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arXiv:2610.00603

Late-Time Power Laws in Fluorescence Decays: Quantum Decay or Alternative Mechanisms?

Francesco Giacosa, Anna Kolbus, Krzysztof Kyziol, Magdalena Plodowska, Milena Piotrowska, Karol Szary, Arthur Vereijken

quant-phnucl-thSubmitted Sep 30, 2026• Announced Oct 2, 2026
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Abstract

In quantum mechanics, the properties of an unstable system are closely related to its corresponding energy distribution. One of the predictions of the theory is the emergence of a late-time power law in the survival probability $P(t)$ of the unstable state. However, in complex systems, similar effects may emerge due to other phenomena. This is the case for nonextensive statistical models, for some continuous lifetime distribution models, and also for certain energy-migration models applied to fluorescence. In this work, these alternative interpretations are confronted with data from time-resolved fluorescence spectroscopy experiments with erythrosine B and eosine Y as fluorophores. It turns out that some of the features expected within the quantum-mechanical description, such as the sharp transition from the exponential to the power-law regime, cannot be reproduced by the specific statistical and energy-migration parametrizations fitted in the analysis.

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9 pages, 2 figures

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In quantum mechanics, the properties of an unstable system are closely related to its corresponding energy distribution. One of the predictions of the theory is the emergence of a late-time power law in the survival probability P(t)P(t)P(t) of the unstable state. However, in complex systems, similar effects may emerge due to other phenomena. This is the case for nonextensive statistical models, for some continuous lifetime distribution models, and also for certain energy-migration models applied to fluorescence. In this work, these alternative interpretations are confronted with data from time-resolved fluorescence spectroscopy experiments with erythrosine B and eosine Y as fluorophores. It turns out that some of the features expected within the quantum-mechanical description, such as the sharp transition from the exponential to the power-law regime, cannot be reproduced by the specific statistical and energy-migration parametrizations fitted in the analysis.
Quantum mechanics predicts deviations from exponential decay at short and long times, yet experimental evidence is limited. We report a power-law tail after $\sim$10 lifetimes in two fluorescent compounds (erythrosine~B and eosine Y), confirmed by two detectors probing distinct bands but yielding different power coefficients. The data match a divergent but normalizable spectral density, and theory predicts oscillations as a future test. A novel and general result is that in multichannel QM (and QFT) decay, the lifetime is universal, but the late-time deviations are channel- (or band-) dependent, a feature consistent with our data.
Results of theoretical studies of the quantum unstable systems caused that there are rather widespread belief that a universal feature of the quantum decay process is the presence of three time regimes of the decay process: the early time (initial) leading to the Quantum Zeno (or Anti Zeno) Effects, “exponential” (or “canonical”) described by the decay law of the exponential form, and late time characterized by the decay law having inverse-power law form. Based on the fundamental principles of the quantum theory we give the proof that there is no time interval in which the survival probability (decay law) could be a decreasing function of time of the purely exponential form but even at the “exponential” regime the decay curve is oscillatory modulated with a smaller or a large amplitude of oscillations depending on parameters of the model considered.
Results of theoretical studies and numerical calculations presented in the literature suggest that the survival probability P0(t) has the exponential form starting from times much smaller than the lifetime τ up to times t ⪢τ and that P0(t) exhibits inverse power–law behavior at the late time region for times longer than the so–called crossover time T ⪢ τ (The crossover time T is the time when the late time deviations of P0(t) from the exponential form begin to dominate). More detailed analysis of the problem shows that in fact the survival probability P0(t) can not take the pure exponential form at any time interval including times smaller than the lifetime τ or of the order of τ and it has has an oscillating form. We also study the survival probability of moving relativistic unstable particles with definite momentum . These studies show that late time deviations of the survival probability of these particles from the exponential–like form of the decay law, that is the transition times region between exponential–like and non-exponential form of the survival probability, should occur much earlier than it follows from the classical standard considerations.
A detailed analysis of the quantum decay processes shows the survival probability ( t ) can not take that exponential form at any time interval including times smaller than the lifetime τ . We show that for times t ∼ τ and for the times later than τ the form of ( t ) looks as a composition of an oscillating and exponential functions. The amplitude of these oscillations is very small for t ≪ τ and grows with increasing time and depends on the model considered. We also study the survival probability of moving relativistic unstable particles with definite momentum : It turns out that late time deviations of the survival probability of these particles from the exponential-like form of the decay law should occur much earlier than it follows from the classical standard approach resolving itself into replacing time t by t / γ (where γ is the relativistic Lorentz factor) in the formula for the survival probability ( t ).
Late time properties of moving relativistic particles are studied. Within the proper relativistic treatment of the problem we find decay curves of such particles and we show that late time deviations of the survival probability of these particles from the exponential form of the decay law, that is the transition times region between exponential and non-exponential form of the survival amplitude, occur much earlier than it follows from the classical standard approach boiled down to replace time t by t/γL (where γL is the relativistic Lorentz factor) in the formula for the survival probability. The consequence is that fluctuations of the corresponding decay curves can appear much earlier and much more unstable particles have a chance to survive up to these times or later. It is also shown that fluctuations of the instantaneous energy of the moving unstable particles have a similar form as the fluctuations in the particle rest frame but they are seen by the observer in his rest system much earlier than one could expect replacing t by t/γL in the corresponding expressions for this energy and that the amplitude of these fluctuations can be even larger than it follows from the standard approach. All these effects seem to be important when interpreting some accelerator experiments with high energy unstable particles and the like (possible connections of these effects with GSI anomaly are analyzed) and some results of astrophysical observations.
Possible consequences of non-exponential behavior of the survival amplitude of an unstable particle at very late times are considered. We describe a new quantum phenomenon: Analyzing the transition time region between exponential and post-exponential form of the survival amplitude we find that the instantaneous energy of the considered unstable state can take large values, much larger than the energy of this state for from the exponential time region. We find also that the instantaneous energy of the unstable state tends to the minimal energy of the system as which is much smaller than the energy of this state for of the order of the lifetime of the considered state. Taking into account the results obtained for the model considered, it is hypothesized that this purely quantum mechanical effect may be responsible for the properties of broad resonances such as meson as well as having astrophysical consequences.