The treatment of the Zeeman effect from the point of view of Schroedinger's theory presents certain difficulties. Let us consider the case of a hydrogen atom in a homogeneous magnetic field of the strength H.
The Bohr formulation—the original one—is now largely a matter of history. The usual career of a theory was its fate. It explained much, but it failed at the first signs of complication, even for the simplest molecules as hydrogen and helium. Some results were either only approximate in a loose or incomplete fashion, e.g. in the application of the correspondence principle to intensities, the only reliable predictions being only for an absence of certain lines, or they quite disagreed with experiment, e.g. in the case of the hydrogen molecule and the hydrogen molecule ion, the normal and excited states of helium, the anomalous Zeeman effect, the Ramsauer effect (the phenomenon of the deflection of electrons at low speeds being less than at higher speeds in atomic collisions), and in the treatment of problems where more than one electron was involved. In the last mentioned cases the perturbation method, so successful in solving “many-body” problems in celestial mechanics, failed completely because systems of several electrons, possessing frequencies of the order of light waves, cannot interact classically. A bit of much forced pragmatism was practiced in treating the many electron atom as a variation of the hydrogen atom. Besides, there were technical oddities, like ½ quantum numbers, and impenetrated anologies between visible and X-ray spectra.
Abstract The aim of this paper is to put forward a theory of the simple Zeeman effect which possesses the same general features as those of the corresponding theory in the case of the Stark effect already developed by Epstein and Schwarzschild. These general features may be briefly described as follows:— (1) The steady states of the atom are governed by classical dynamics subject to certain conditions, the quantum restrictions, which define the atom both in the absence and the 'presence of the field; (2) radiation occurs during the period of transition from one steady state to another according to Bohr’s energy relation hv = Wm-Wn.
The problem of a spinning electron moving round the nudeu.s in the piesence of an external magnetic held ha.sbeen considered from the wave-statistical point of view.The general expressions for energies and wave functions in any held strength have l)een obtained.The problems of no field, weak field (Zeeman effect) and strong field (Paschen-Back effect) are considered as .specialcases.The resnlt.s for the no field case are identical with tho.se obtained in the earlier paper (Kar and Sengnpta.uj'ig).Other results also agree with the well-known spectro,scopic formulae,