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International Journal of Quantum Chemistry

Usage de l'algebre de lie su(n) dans l'etude des systems à n etats. VI. Equations linéaires d'evolution positive

A. Van Groenendael

Published Jul 1, 1986• 1 citation
Publisher

Abstract

Abstract The n‐level quantum system density‐operators evolution is not usually given by the Liouville equation, but by a more general one. This equation must keep density‐operators trace, hermiticity, and positiveness. These three conditions restrict the available kinds of evolution equations. In this paper we investigate linear equations for systems without memory effects. By using the first two conditions and the formalism we introduced in earlier papers, the evolution equation takes the form of a first order differential equation concerning the n2 – 1 dimension “coherence‐vector.” The third one is the essential object of this paper. Moreover, we obtain a cononical splitting of this equation into four parts that may be separately studied.

DOI
10.1002/qua.560300115

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Abstract The n‐level quantum system density‐operators evolution is not usually given by the Liouville equation, but by a more general one. This equation must keep density‐operators trace, hermiticity, and positiveness. These three conditions restrict the available kinds of evolution equations. In this paper we investigate linear equations for systems without memory effects. By using the first two conditions and the formalism we introduced in earlier papers, the evolution equation takes the form of a first order differential equation concerning the n2 – 1 dimension “coherence‐vector.” The third one is the essential object of this paper. Moreover, we obtain a cononical splitting of this equation into four parts that may be separately studied.
Abstract The density operator of an n level quantum system is known to be a positive semidefinite, hermitian operator of trace one. In a previous article we have established, through su(n) algebras, a formalism where density operators are built from coherence vectors in a n2 − 1 dimension, real, Euclidean space. The last two conditions are then automatically satisfied. Being positive semidefinite means a restriction to the domain of coherence vectors. In this article we clarify this domain and obtain several equivalent tests to know if a given vector is part of it.
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Abstract In an n level quantum system there is a relation between each density operator and an element of su (n) Lie algebra. This relation is also established between Cartan's subalgebras and the complete sets of compatible observables. A scalar product is then defined in this algebra in order to introduce orthonormal bases and to simplify many calculations about expectation values of observables. Therefore simple general rules were established which show how to determine (completely or partly), from linearly independent observables, the density operator of the system.
Abstract A partir de I'opérateur‐densité d'un système quantique à n états, sont définies et calcultes des constantes du mouvement pour lesquelles est proposée I'appellation nouvelle de conjoncturelles. On établit qu'il en existe au maximum n − 1 linéairement indépendantes. A I'aide des sous‐algèbres su(m) (m < n ), on montre comment il est possible d'introduire, suivant la forme de I'hamiltonien, des constantes du mouvement conjoncturelles reliées aux composantes du vecteur de cohérence.