The effects of system-environment correlations on the dynamics of an open quantum system are investigated for the standard model of a set of quantum harmonic oscillators interacting with a heat bath of oscillators. By definition, a subdynamics is described by transformations of the open system observables. It is shown that such a construction can reproduce the observable properties of the exact dynamics only when the states of system and environment are uncorrelated, while for classical systems there is always a subdynamics. A quantum subdynamics cannot have the properties we associate with thermal fluctuations; the KMS relation at a finite temperature for the open system implies that the system must be closed. The conditions for having a subdynamics as a good approximation to the exact closed dynamics are investigated, and so are the similar but stronger conditions for a Markovian dynamics. It is also shown that a subdynamics defines the response of the open system to some types of time dependent external forces.
The effects of system-environment correlations on the dynamics of an open quantum system are investigated for the standard model of a set of quantum harmonic oscillators interacting with a heat bath of oscillators. By definition, a subdynamics is described by transformations of the open system observables. It is shown that such a construction can reproduce the observable properties of the exact dynamics only when the states of system and environment are uncorrelated, while for classical systems there is always a subdynamics. A quantum subdynamics cannot have the properties we associate with thermal fluctuations; the KMS relation at a finite temperature for the open system implies that the system must be closed. The conditions for having a subdynamics as a good approximation to the exact closed dynamics are investigated, and so are the similar but stronger conditions for a Markovian dynamics. It is also shown that a subdynamics defines the response of the open system to some types of time dependent external forces.
We generalize the classical theory of Brownian motion so as to reckon with non-Markovian effects on both Klein-Kramers and Smoluchowski equations. For a free particle and a harmonic oscillator, it is shown that such non-Markovian effects account for the differentiability of the Brownian trajectories as well as the breakdown of the energy equipartition of statistical mechanics at short times in some physical situations. This non-Markovian approach is also extended to look at anomalous diffusion. Next, we bring in the dynamical-quantization method for investigating open quantum systems, which does consist in quantizing the classical Brownian motion starting directly from our non-Markovian Klein-Kramers and Smoluchowski equations, without alluding to any model Hamiltonian. Accordingly, quantizing our non-Markovian Klein-Kramers in phase space gives rise to a non-Markovian quantum master equation in configuration space, whereas quantizing our non-Markovian Smoluchowski equation in configuration space leads to a non-Markovian quantum Smoluchowski equation in phase space. In addition, it is worth noticing that non-Markovian quantum Brownian motion takes place in presence of a generic environment (e.g. a non-thermal quantum fluid). As far as the special case of a heat bath comprising of quantum harmonic oscillators is concerned, a non-Markovian Caldeira-Leggett master equation and a thermal quantum Smoluchowski equation are derived and extended to bosonic and fermionic heat baths valid for all temperatures.
We derive an exact Markovian kinetic equation for an oscillator linearly coupled to a heat bath, describing quantum Brownian motion. Our work is based on the subdynamics formulation developed by Prigogine and collaborators. The space of distribution functions is decomposed into independent subspaces that remain invariant under Liouville dynamics. For integrable systems in Poincaré's sense the invariant subspaces follow the dynamics of uncoupled, renormalized particles. In contrast, for nonintegrable systems, the invariant subspaces follow a dynamics with broken time symmetry, involving generalized functions. This result indicates that irreversibility and stochasticity are exact properties of dynamics in generalized function spaces. We comment on the relation between our Markovian kinetic equation and the Hu-Paz-Zhang equation.
The dynamical aspects of quantum Brownian motion at low temperatures are investigated. Exact calculations of quantum entanglement among two Brownian oscillators are given without invoking the Born-Markov or Born approximation widely used for the study of open systems. Nonlocality due to finite oscillator separation is studied. Our approach is applicable for arbitrary time scale, in particular suitable to probe the short-time regime at cold temperatures where many experiments on quantum information processing are performed. We study separability criteria based on the uncertainty relation, negativity, and entanglement of formation. We found a crossover behavior in a disentanglement process between quantum- and thermal-fluctuation-dominated regimes. The fluctuation-dissipation theorem is violated for two Brownian particles interacting with a common environment. The deviation from the relation originates in the interaction mediated by the environment, which drives two particles into a steady oscillatory state, preventing the system from thermalizing. Consequently there is a residual entanglement at low temperatures for arbitrary coupling strength. This entanglement is generated from the environment nonperturbatively even when two modes are not entangled initially. When the distance between two oscillators is varied, competition between entanglement induced from the environment and modified decoherence due to finite separation leads to the characteristic distance where entanglement is minimized.
We study quantum non-Markovian dynamics of the Caldeira-Leggett model, a prototypical model for quantum Brownian motion describing a harmonic oscillator linearly coupled to a reservoir of harmonic oscillators. Employing the exact analytical solution of this model one can determine the size of memory effects for arbitrary couplings, temperatures, and frequency cutoffs. Here, quantum non-Markovianity is defined in terms of the flow of information between the open system and its environment, which is quantified through the Bures metric as distance measure for quantum states. This approach allows us to discuss quantum memory effects in the whole range from weak to strong dissipation for arbitrary Gaussian initial states. A comparison of our results with the corresponding results for the spin-boson problem show a remarkable similarity in the structure of non-Markovian behavior of the two paradigmatic models.
We explore some aspects of nonequilibrium statistical mechanics of classical and quantum systems. Two chapters are devoted to fluctuation theorems which were originally derived for classical systems. The main challenge in formulating them in quantum mechanics is the fact that fundamental quantities of interest, like work, are defined via the classical concept of a phase space trajectory. We utilize the decoherent histories conceptual framework, in which classical trajectories emerge in quantum mechanics as a result of coarse graining, and provide a first-principles analysis of the nonequilibrium work relation of Jarzynski and Crooks's fluctuation theorem for a quantum system interacting with a general environment based on the quantum Brownian motion (QBM) model. We indicate a parameter range at low temperatures where the theorems might fail in their original form. Fluctuation theorems of Jarzynski and Crooks for systems obeying classical Hamiltonian dynamics are derived under the assumption that the initial conditions are sampled from a canonical ensemble, even though the equilibrium state of an isolated system is typically associated with the microcanonical ensemble. We address this issue through an exact analysis of the classical Brownian motion model. We argue that a stronger form of ensemble equivalence than usually discussed in equilibrium statistical mechanics is required for these theorems to hold in the infinite environment limit irrespective of the ensemble used, and proceed to prove it for this model. An exact expression for the probability distribution of work is obtained for finite environments. Intuitively one expects a system to relax to an equilibrium state when brought into contact with a thermal environment. Yet it is important to have rigorous results that provide conditions for equilibration and characterize the equilibrium state. We consider the dynamics of open quantum systems using the Langevin and master equations and rigorously show that under fairly general conditions quantum systems interacting with a heat bath relax to the equilibrium state defined as the reduced thermal state of the system plus environment, even in the strong coupling regime. Our proof is valid to second-order in interaction strength for general systems and exact for the linear QBM model, for which we also show the equivalence of multi-time correlations. In the final chapter we give a sampling of our investigations into macroscopic quantum phenomena. We work out in detail a specific example of how and under what conditions the center of mass (CoM) coordinate of a macroscopic object emerges as the relevant degree of freedom. Interaction patterns are studied in terms of the couplings they induce between the CoM and relative coordinates of two macroscopic objects. We discuss the implications of these interaction patterns on macroscopic entanglement.
The quantum fluctuation-dissipation theorem is a central ingredient in the construction of quantum dynamics of Brownian motion which necessarily is non-Markovian. Yet, often Markovian approximations to quantum dynamics are studied in the literature. In this work, we investigate the limitations of the Markovian approximation within two paradigmatic models describing a single damped harmonic oscillator. These models are governed by distinct quantum Langevin equations, although both are constructed to satisfy the same set of phenomenological criteria: the canonical commutation relations between position and momentum, the Kubo response relation, the virial theorem, and the equilibrium quantum variance. The limitations of the Markovian approximation are underscored by the classical limit, violations of the Ehrenfest theorem, the breakdown of complete and simple positivity in the reconstructed master equations, and anomalies in thermalisation behaviour. Further phenomenological differences between the two models are illustrated through their quantum relaxation dynamics and phase diagrams, derived from their reinterpretation as mean-field approximations of a many-body interacting magnet. Our analysis explicitly reveals intrinsic inconsistencies introduced by the Markovian approximation, emphasising the need for non-Markovian frameworks for a consistent description of open quantum dynamics.