Absorption spectroscopy is a widely used technique that permits the detection and characterization of gas species at low concentrations. We propose a sensing strategy combining the advantages of frequency modulation spectroscopy with the reduced noise properties accessible by squeezing the probe state. A homodyne detection scheme allows the simultaneous measurement of the absorption at multiple frequencies and is robust against dispersion across the absorption profile. We predict a significant enhancement of the signal-to-noise ratio that scales exponentially with the squeezing factor. An order of magnitude improvement beyond the standard quantum limit is possible with state-of-the-art squeezing levels facilitating high precision gas sensing.
In this article, we present a novel spectroscopy technique that improves the signal-to-shot-noise ratio without the need to increase the laser power. Detrimental effects by technical noise sources are avoided by frequency-modulation techniques (frequency up-shifting). Superimposing the signal on non-classical states of light leads to a reduced quantum noise floor. Our method reveals in a proof-of-concept experiment small signals at Hz to kHz frequencies even below the shot noise limit. Our theoretical calculations fully support our experimental findings. The proposed technique is interesting for applications such as high-precision cavity spectroscopy, e.g., for explosive trace gas detection where the specific gas might set an upper limit for the laser power employed.
Quantum noise is one of the limiting factors in laser-interferometric gravitational-wave (GW) detectors. The application of squeezed states in these interferometers allows the reduction of quantum noise in one quadrature. Due to opto-mechanical coupling in a GW detector the squeezed quadrature needs to be rotated within the spectrum to achieve a broadband noise reduction. So far, the implementation of additional filter cavities is considered that allow for the optimal, frequency-dependent rotation of the squeezed quadrature. However, these cavities need to have low loss, a length in the order of \unit[100]{m} and must be situated in the vacuum system, making them cost-intensive. In 2017, Ma and coworkers proposed a scheme for the broadband quantum-noise reduction without the need of additional filter cavities. It was shown by Brown et al. that a similar scheme can be used to broadband-enhance interferometers with a detuned signal-recycling cavity. Here, we performed a proof-of-principle experiment of the proposal on a table-top-scale. Squeezed states were produced detuned to the carrier field of a \unit[2.5]{m}-linear cavity and read out in a bichromatic homodyne detection. The frequencies of the lower and upper local oscillator were at entangled sidebands of the squeezed field. Depending on the relations between the involved frequencies, we can address both variants of the proposal. We show, that the frequency-dependences of the resulting noise spectra fit to a theoretical model we derived from the theory used by Ma et al. With this work we set the path towards an implementation of these schemes in a GW-detector prototype, where the compatibility of the approach with a low-frequency suspended interferometer can be tested. Moreover, we used the same setup to show nonclassical interferometer enhancement at low frequencies by high-frequency squeezed states. Here, a heterodyne readout scheme was implemented to avoid limiting noises at low frequencies. The application of squeezed states centered around the local oscillator frequency yielded an improvement in signal-to-noise ratio of $\unit[3.4]{dB}\pm\unit[0.3]{dB}$. Additionally, I designed, built and characterized a compact source of squeezed vacuum-states at \unit[1064]{nm} with a footprint of just $\unit[0.8]{m^2}$. I show measurements of squeezed states from this source with a reduction of quantum noise of $\unit[10.7]{dB}\pm\unit[0.2]{dB}$ below the vacuum noise and present a noise reduction in the frequency range from \unit[70]{kHz} to \unit[65]{MHz}.
High sensitivity detection of quantum absorption is demonstrated at a sensitivity of
1times1011 integrated absorption, in 1 sec, using 10 mTorr total gas pressure. Achieving highly sensitive detection relies on simple basic principles: 1) The molecule-generated electric field in the forward direction (the "darkness wave") is most precious, and contains the maximum available information. It is the physical manifestation of the -
alpha∗L term appearing when beer#### absorption law is expanded for low opacity, 2) After generating the molecular signal, the detected unabsorbed light sets the "shotnoise" measurement floor. We use an optical transmission cavity for the gas cell, since the high internal "build-up" field will elicit a strong molecular "darkness wave", for a given transmitted de light on the detector, A more conventional explanation of Gavity Enhancement would be the extension of the effective cell length by the factor finesse
∗2/pi.3) To avoid excess low-frequency noise, such small signals should be measured by ac methods, comparing on-resonant and off-resonant cases in quick succession. 4) By SIMULTANEOUSLY obtaining and subtracting these cases, one provides a siginal channel with NO OUTPUT unless there is a resonance. This is conveniently accomplished by using the FM detection method with the optical heterodyne sidebands and carrier being transmitted through the cavity via adjacent axial orders 5). A remarkable property of this configuration, when the modulation frequency= cavity mode spacing, is the suppression of ANY detection of laser frequency noise with the transmitted light. We can refer to this property as (laser FM-) noise-Immune detection. This enables profitable use of cavity finesse in the range above 10,000, without a nois penalty, Altogether, we refer to this new spectroscopy as Noise-Immune, Cavity-Enhanced, Optical Heterodyne Molecular spectroscopy, i.e. "NICE OHMS". We have measured excellent saturated dispersion signals from HCCH in the band near 790 mm (
nu1+3nu3), and recently, using a Nd:YAG source, from the HCCD P(5) line (
nu2+3nu3) at 1064 mm. The saturation peaks broaden from the transit limit of 270 kHz near zero pressure at the rate 34.7 kHz/m Torr. We observe interesting narrow linwidths 8-fold below the transit limit, basically using optical selection of slow molecules by low power and pressure (2 mW and 2 m Torr). The absolute frequency is measurred to be 281, 635,363,960 MHz
pm45 kHz.
A frequency tunable source of squeezed light has been developed for application to a variety of problems in atomic physics. The basic experimental arrangement consists of a subthreshold optical parametric oscillator (OPO) that is pumped by the frequency-doubled output of a titanium-sapphire laser. Squeezed light with continuous tunability of 2 GHz has been generated with a directly observed nonclassical noise reduction of 5.0 dB relative to the vacuumstate limit in a balanced homodyne detector (5.2 dB when corrected for detector noise). Although our source is potentially broadly tunable over the noncritical phase-matching bandwidth of potassium niobate, current research has concentrated on operation at 852 nm for excitation of the D2 line of atomic cesium. Relative to the usual quantum limit associated with vacuumstate fluctuations, enhanced sensitivity is demonstrated for the detection of Doppler-free resonances in FM saturation spectroscopy, with an improvement of 3.1 dB directly observed and 3.8 dB after correction for detector noise.