To construct a self-adjoint operator the domain of the operator has to be specified by imposing an appropriate boundary condition or conditions on the wave functions on which the operator acts. We illustrate situations for which different boundary conditions lead to different operators and hence to different physics.
We present some simple arguments to show that quantum mechanics operators are required to be self-adjoint. We emphasize that the very definition of a self-adjoint operator includes the prescription of a certain domain of the operator. We then use these concepts to revisit the solutions of the time-dependent Schroedinger equation of some well-known simple problems - the infinite square well, the finite square well, and the harmonic oscillator. We show that these elementary illustrations can be enriched by using more general boundary conditions, which are still compatible with self-adjointness. In particular, we show that a puzzling problem associated with the Hydrogen atom in one dimension can be clarified by applying the correct requirements of self-adjointness. We then come to Stone\'s theorem, which is the main topic of this paper, and which is shown to relate the usual definitions of a self-adjoint operator to the possibility of constructing well-defined solutions of the time-dependent Schrödinger equation.
Conditions on wave functions that are eigenvectors often have a mathematical rather than a physical basis; they are required simply because an eigenvector of an operator must be in the domain of that operator. This is illustrated with derivations of the conditions at the origin on eigenvectors of a nonrelativistic Hamiltonian, for example, for the hydrogen atom or harmonic oscillator, and the condition that eigenfunctions of the angular momentum Lz must be single valued or continuous around a complete circle.
We are focused on the idea that observables in quantum physics are a bit more then just hermitian operators and that this is, in general, a “tricky business”. The origin of this idea comes from the fact that there is a subtle difference between symmetric, hermitian, and self-adjoint operators which are of immense importance in formulating Quantum Mechanics. The theory of self-adjoint extensions is presented through several physical examples and some emphasis is given on the physical implications and applications.