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Brazilian Journal of Physics

The time-dependent Schrödinger equation: the need for the Hamiltonian to be self-adjoint

Vanilse S. Araujo, Francisco Antônio Bezerra Coutinho, F. Masafumi Toyama

Published Mar 1, 2008• 13 citations
Publisher

Abstract

We present some simple arguments to show that quantum mechanics operators are required to be self-adjoint. We emphasize that the very definition of a self-adjoint operator includes the prescription of a certain domain of the operator. We then use these concepts to revisit the solutions of the time-dependent Schroedinger equation of some well-known simple problems - the infinite square well, the finite square well, and the harmonic oscillator. We show that these elementary illustrations can be enriched by using more general boundary conditions, which are still compatible with self-adjointness. In particular, we show that a puzzling problem associated with the Hydrogen atom in one dimension can be clarified by applying the correct requirements of self-adjointness. We then come to Stone\'s theorem, which is the main topic of this paper, and which is shown to relate the usual definitions of a self-adjoint operator to the possibility of constructing well-defined solutions of the time-dependent Schrödinger equation.

DOI
10.1590/s0103-97332008000100030

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We present some simple arguments to show that quantum mechanics operators are required to be self-adjoint. We emphasize that the very definition of a self-adjoint operator includes the prescription of a certain domain of the operator. We then use these concepts to revisit the solutions of the time-dependent Schroedinger equation of some well-known simple problems - the infinite square well, the finite square well, and the harmonic oscillator. We show that these elementary illustrations can be enriched by using more general boundary conditions, which are still compatible with self-adjointness. In particular, we show that a puzzling problem associated with the Hydrogen atom in one dimension can be clarified by applying the correct requirements of self-adjointness. We then come to Stone's theorem, which is the main topic of this paper, and which is shown to relate the usual definitions of a self-adjoint operator to the possibility of constructing well-defined solutions of the time-dependent Schrödinger equation.
W Pauli pointed out that the existence of a self-adjoint time operator is incompatible with the semi-bounded character of the Hamiltonian spectrum. As a result, there has been much argument about the time–energy uncertainty relation and other related issues. In this paper, we show a way to overcome Pauli's argument. In order to define a time operator, by treating time and space on an equal footing and extending the usual Hamiltonian Ĥ to the generalized Hamiltonian Ĥ μ (with Ĥ 0 = Ĥ), we reconstruct the analytical mechanics and the corresponding quantum (field) theories, which are equivalent to the traditional ones. The generalized Schrödinger equation i∂ μ ψ = Ĥ μ ψ and Heisenberg equation d /d x μ = ∂ μ + i[Ĥ μ , ] are obtained, from which we have: (1) t is to Ĥ 0 as x j is to Ĥ j ( j = 1, 2, 3); likewise, t is to i∂ 0 as x j is to i∂ j ; (2) the proposed time operator is canonically conjugate to i∂ 0 rather than to Ĥ 0 , therefore Pauli's theorem no longer applies; (3) two types of uncertainty relations, the usual Δ x μ Δ p μ ≥ 1/2 and the Mandelstam–Tamm treatment Δ x μ Δ H μ ≥ 1/2, have been formulated.
Recently, we constructed an energy-dependent point interaction (EDPI) in its most general form in one-dimensional quantum mechanics. In this paper, we show that stationary solutions of the Schrodinger equation with the EDPI form a complete set. Then any nonstationary solution of the time-dependent Schrodinger equation can be expressed as a linear combination of stationary solutions. This, however, does not necessarily mean that the EDPI is self-adjoint and the time-development of the nonstationary state is unitary. The EDPI is self-adjoint provided that the stationary solutions are all orthogonal to one another. We illustrate situations in which this orthogonality condition is not satisfied.PACS Nos.: 03.65.–w, 03.65.Nk, 03.65.Ge
The quantum wave mechanics proposed in 1926 by Erwin Schrödinger for the hydrogen atom was a mixture of success and failure. Astonishing and extraordinary success resulted from Schrödinger self adjoint Hamiltonian energy linear operator H. This mathematical object allows the calculation of stationary energies and stationary electron configurations. On the other hand the Schrödinger time dependent equation was such a dramatic failure that it led to the establishment of the current Quantism, or Quantum doctrine, or Copenhagen interpretation of quantum mechanics based on the postulates listed below, or variations of these. This paper discusses the implications that the deterministic time dependent equation has for Quantism.