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Theoretical and Mathematical Physics

Dynamical structure factor of a fluid in nonequilibrium steady states

V. G. Morozov

Published Feb 1, 1986• 1 citation
Publisher
DOI
10.1007/bf01017768

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There is no simple fluctuation-dissipation theorem (FDT) for nonequilibrium systems. We show that for a fluid in a nonequilibrium steady state (NESS) characterized by a constant temperature gradient there is a generalized FDT that relates commutator correlation functions to the bilinear response of products of observables. This allows for experimental probes of the long-range correlations in such a system, quantum or classical, via response experiments. We also show that the correlations are not tied to thermal fluctuations but are intrinsic to the NESS and reflect a generalized rigidity.
The concept of thermal machines has evolved from the canonical steam engine to the recently proposed nanoscopic quantum systems as working fluids. The latter obey quantum open system dynamics and frequently operate in nonequilibrium conditions. However, the role of this dynamics in the overall performance of quantum heat engines remains an open problem. Here we analyze and optimize the efficiency and power output of two-stage quantum heat engines fueled by nonequilibrium steady states. In a charging first stage, the quantum working fluid consisting of a qutrit or two coupled qubits is connected to two reservoirs at different temperatures, which establish a heat current that stores ergotropy in the system; the second stage comprises a coherent driving force that extracts work from the machine in finite a amount of time; finally, the external drive is switched off and the machine enters a new cycle.