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Russian Journal of Mathematical Physics

On the superfluidity of classical liquid in nanotubes, I. Case of even number of neutrons

Виктор Павлович Маслов

Published Sep 1, 2007• 26 citations
Publisher

Abstract

We show that the superfluidity effect in nanotubes arises in a classical liquid (regarded as the limit as h → 0 of the quantum liquid) and involves not only the Bogolyubov “running waves,” but also a “standing wave.” This is obtained from the variational equations in the context of ultrasecondary quantization. It is stressed that the “atomic” size of the nanotube plays a crucial role in the phenomena.

DOI
10.1134/s1061920807030065

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We show that the superfluidity effect in nanotubes arises in a classical liquid (regarded as the limit as h → 0 of the quantum liquid) and involves not only the Bogolyubov “running waves,” but also a “standing wave.” This is obtained from the variational equations in the context of ultrasecondary quantization. We consider cases of Bose and Fermi liquids.

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We conclude our study of superfluidity in Bose liquids with a brief summary of the strengths, and of the inadequacies, of the theory. The cornerstone of our fundamental understanding of superfluidity has been the recognition of the central importance of the condensate, a single quantum state which is macroscopically occupied. For the Bose liquid one has a particle condensate, characterized by a non-vanishing expectation value of ψ (r). The existence of the condensate explains all major aspects of superfluid behavior; in particular, we now possess: A clear understanding of the static and the long wavelength dynamic properties of an equilibrium Bose liquid, including a microscopic basis for the two-fluid model. A precise microscopic theory at T = 0 for a specific model, the dilute Bose gas. Variational calculations of the excitation spectrum of liquid He II (and of the ground state properties as well), which are in good quantitative agreement with experiment. A satisfactory phenomenological treatment of the interactions between elementary excitations which give rise to various irreversible phenomena. A qualitative understanding of the role which is played by quantized vortices in both equilibrium and non-equilibrium phenomena.

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Motivated by recent experiments on alkali gases in atom traps, a largely pedagogical account is given of the implications of the existence of a single-particle Bose-Einstein condensate for the phenomenon of superfluidity. The first conclusion is that, for alkalis in traps at the lowest temperatures, Bose-Einstein condensation coexists with superfluidity. Both experimental evidence and basic microscopic theory are reviewed in this context, with superfluidity in finite systems, quantized vortices and the threshold for breakdown of superfluidity all being referred to. The contrast between liquid 4He below the λ point and the alkali atom gases is then emphasized. Both exhibit superfluidity, but the manifestations of a Bose-Einstein condensate are quite different. For the atomic vapours, near to 100% of the atoms are condensed at the lowest temperatures, whereas from (i) neutron scattering and (ii) computer simulations in liquid 4He present evidence is that 7% is the condensate fraction. This leads finally into a brief discussion of superfluidity without a condensate, with specific reference to the two-dimensional Bose Coulomb gas. The main conclusion is that Bose-Einstein condensation and superfluidity are distinct consequences of deeper topological properties of the many-body wavefunction.

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Vortices are commonly observed in the context of classical hydrodynamics: from whirlpools after stirring the coffee in a cup to a violent atmospheric phenomenon such as a tornado, all classical vortices are characterized by an arbitrary circulation value of the local velocity field. On the other hand the appearance of vortices with quantized circulation represents one of the fundamental signatures of macroscopic quantum phenomena. In two-dimensional superfluids quantized vortices play a key role in determining finite-temperature properties, as the superfluid phase and the normal state are separated by a vortex unbinding transition, the Berezinskii-Kosterlitz-Thouless transition. Very recent experiments with two-dimensional superfluid fermions motivate the present work: we present theoretical results based on the renormalization group showing that the universal jump of the superfluid density and the critical temperature crucially depend on the interaction strength, providing a strong benchmark for forthcoming investigations.

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This book is about a certain class of superfluids, namely the high temperature superconductors. Perhaps the simplest of the superfluids is liquid He4. Since the very early days of quantum mechanics it has been known that the helium atom He4 is a boson; it is built of an even number of particles (two electrons, two neutrons and two protons), so that a wave function ^(ri,F2) must be symmetrical in FI — r? where FI, r-z are the electron's coordinates. This has the result that half the rotational states of the molecule H62 are absent and that the scattering of alpha particles by helium for low energies deviates from the Rutherford scattering law. It also has the remarkable result that this is not so for the light isotope He3, which shows that the number of neutrons in the nucleus affects properties depending otherwise only on the electrons and nuclear charge.

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We show that the superfluidity effect in nanotubes arises in a classical liquid (regarded as the limit as h → 0 of the quantum liquid) and involves not only the Bogolyubov “running waves,” but also a “standing wave.” This is obtained from the variational equations in the context of ultrasecondary quantization. It is stressed that the “atomic” size of the nanotube plays a crucial role in the phenomena.
We conclude our study of superfluidity in Bose liquids with a brief summary of the strengths, and of the inadequacies, of the theory. The cornerstone of our fundamental understanding of superfluidity has been the recognition of the central importance of the condensate, a single quantum state which is macroscopically occupied. For the Bose liquid one has a particle condensate, characterized by a non-vanishing expectation value of ψ (r). The existence of the condensate explains all major aspects of superfluid behavior; in particular, we now possess: A clear understanding of the static and the long wavelength dynamic properties of an equilibrium Bose liquid, including a microscopic basis for the two-fluid model. A precise microscopic theory at T = 0 for a specific model, the dilute Bose gas. Variational calculations of the excitation spectrum of liquid He II (and of the ground state properties as well), which are in good quantitative agreement with experiment. A satisfactory phenomenological treatment of the interactions between elementary excitations which give rise to various irreversible phenomena. A qualitative understanding of the role which is played by quantized vortices in both equilibrium and non-equilibrium phenomena.
We review fundamental problems involved in liquid theory including both classical and quantum liquids. Understanding classical liquids involves exploring details of their microscopic dynamics and its consequences. Here, we apply the same general idea to quantum liquids. We discuss momentum condensation in liquid helium which is consistent with microscopic dynamics in liquids and high mobility of liquid atoms. We propose that mobile transit atoms accumulate in the finite-energy state where the transit speed is close to the speed of sound. In this state, the transit energy is close to the oscillatory zero-point energy. In momentum space, the accumulation operates on a sphere with the radius set by interatomic spacing and corresponds to zero net momentum. We show that this picture is supported by experiments, including the measured kinetic energy of helium atoms below the superfluid transition and sharp peaks of scattered intensity at predicted energy. We discuss the implications of this picture including the macroscopic wave function and superfluidity.
Motivated by recent experiments on alkali gases in atom traps, a largely pedagogical account is given of the implications of the existence of a single-particle Bose-Einstein condensate for the phenomenon of superfluidity. The first conclusion is that, for alkalis in traps at the lowest temperatures, Bose-Einstein condensation coexists with superfluidity. Both experimental evidence and basic microscopic theory are reviewed in this context, with superfluidity in finite systems, quantized vortices and the threshold for breakdown of superfluidity all being referred to. The contrast between liquid 4He below the λ point and the alkali atom gases is then emphasized. Both exhibit superfluidity, but the manifestations of a Bose-Einstein condensate are quite different. For the atomic vapours, near to 100% of the atoms are condensed at the lowest temperatures, whereas from (i) neutron scattering and (ii) computer simulations in liquid 4He present evidence is that 7% is the condensate fraction. This leads finally into a brief discussion of superfluidity without a condensate, with specific reference to the two-dimensional Bose Coulomb gas. The main conclusion is that Bose-Einstein condensation and superfluidity are distinct consequences of deeper topological properties of the many-body wavefunction.
Vortices are commonly observed in the context of classical hydrodynamics: from whirlpools after stirring the coffee in a cup to a violent atmospheric phenomenon such as a tornado, all classical vortices are characterized by an arbitrary circulation value of the local velocity field. On the other hand the appearance of vortices with quantized circulation represents one of the fundamental signatures of macroscopic quantum phenomena. In two-dimensional superfluids quantized vortices play a key role in determining finite-temperature properties, as the superfluid phase and the normal state are separated by a vortex unbinding transition, the Berezinskii-Kosterlitz-Thouless transition. Very recent experiments with two-dimensional superfluid fermions motivate the present work: we present theoretical results based on the renormalization group showing that the universal jump of the superfluid density and the critical temperature crucially depend on the interaction strength, providing a strong benchmark for forthcoming investigations.
This book is about a certain class of superfluids, namely the high temperature superconductors. Perhaps the simplest of the superfluids is liquid He4. Since the very early days of quantum mechanics it has been known that the helium atom He4 is a boson; it is built of an even number of particles (two electrons, two neutrons and two protons), so that a wave function ^(ri,F2) must be symmetrical in FI — r? where FI, r-z are the electron's coordinates. This has the result that half the rotational states of the molecule H62 are absent and that the scattering of alpha particles by helium for low energies deviates from the Rutherford scattering law. It also has the remarkable result that this is not so for the light isotope He3, which shows that the number of neutrons in the nucleus affects properties depending otherwise only on the electrons and nuclear charge.