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The Journal of Chemical Physics

Irreversibility in Finite Quantum-Statistical-Mechanical Systems

Arthur Hobson

Published Feb 15, 1967• 2 citations
Publisher

Abstract

It is shown that the usual proofs of the quasiperiodicity of isolated, finite quantum-statistical systems, previously thought to be general proofs, are in reality based on the special case of a discrete array. Quasiperiodicity is demonstrated for the analogous special case (the discrete distribution) in classical statistical mechanics. The density-operator formalism is set up for the case of a continuous array. The question of the possibly irreversible behavior of isolated, finite quantum-statistical systems with continuous arrays is investigated. An argument is given indicating that such systems generally behave irreversibly. The situations in classical and quantum statistics then appear to be entirely analogous, since it is well known that isolated, finite classical-statistical systems may, in the case of a continuous distribution (the analog of a continuous quantum-statistical array), behave irreversibly.

DOI
10.1063/1.1840858

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It is shown that the usual proofs of the quasiperiodicity of isolated, finite quantum-statistical systems, previously thought to be general proofs, are in reality based on the special case of a discrete array. Quasiperiodicity is demonstrated for the analogous special case (the discrete distribution) in classical statistical mechanics. The density-operator formalism is set up for the case of a continuous array. The question of the possibly irreversible behavior of isolated, finite quantum-statistical systems with continuous arrays is investigated. An argument is given indicating that such systems generally behave irreversibly. The situations in classical and quantum statistics then appear to be entirely analogous, since it is well known that isolated, finite classical-statistical systems may, in the case of a continuous distribution (the analog of a continuous quantum-statistical array), behave irreversibly.
The statistical operators of those isolated nonrelativistic quantum systems that are presumed to exhibit intrinsically irreversible evolutionary behavior are shown to be capable of undergoing only discontinuous changes that occur at successive instants of time that are suggestive of possible temporal discreteness and that result in ``mixed-state'' conditions of the systems. Presuming such discrete temporal structure, a temporally asymmetric difference equation is derived for these statistical operators that suffices to imply their irreversible discontinuous evolution and from which both predictability and retrodictability of their temporal behavior are possible, but the latter cannot be extended indefinitely into the past.
Weyl's formulation of quantum mechanics opened the possibility of studying the dynamics of quantum systems both in infinite-dimensional and finite-dimensional systems. Based on Weyl's approach, generalized by Schwinger, a self-consistent theoretical framework describing physical systems characterised by a finite-dimensional space of states has been created. The used mathematical formalism is further developed by adding finite-dimensional versions of some notions and results from the continuous case. Discrete versions of the continuous Gaussian functions have been defined by using the Jacobi theta functions. We continue the investigation of the properties of these finite Gaussians by following the analogy with the continuous case. We study the uncertainty relation of finite Gaussian states, the form of the associated Wigner quasi-distribution and the evolution under free-particle and quantum harmonic oscillator Hamiltonians. In all cases, a particular emphasis is put on the recovery of the known continuous-limit results when the dimension ddd of the system increases.
Weyl's formulation of quantum mechanics opened the possibility of studying the dynamics of quantum systems both in infinite-dimensional and finite-dimensional systems. Based on Weyl's approach, generalized by Schwinger, a self-consistent theoretical framework describing physical systems characterized by a finite-dimensional space of states has been created. The used mathematical formalism is further developed by adding finite-dimensional versions of some notions and results from the continuous case. Discrete versions of the continuous Gaussian functions have been defined by using the Jacobi theta functions. We continue the investigation of the properties of these finite Gaussians by following the analogy with the continuous case. We study the uncertainty relation of finite Gaussian states, the form of the associated Wigner quasi-distribution and the evolution under free-particle and quantum harmonic oscillator Hamiltonians. In all cases, a particular emphasis is put on the recovery of the known continuous-limit results when the dimension d of the system increases.
In statistical mechanics, it is well known that finite-state classical lattice models can be recast as quantum models, with distinct classical configurations identified with orthogonal basis states. This mapping makes classical statistical mechanics on a lattice a special case of quantum statistical mechanics, and classical combinatorial entropy a special case of quantum entropy. In a similar manner, finite-state classical dynamics can be recast as finite-energy quantum dynamics. This mapping translates continuous quantities, concepts and machinery of quantum mechanics into a simplified finite-state context in which they have a purely classical and combinatorial interpretation. For example, in this mapping quantum average energy becomes the classical update rate. Interpolation theory and communication theory help explain the truce achieved here between perfect classical determinism and quantum uncertainty, and between discrete and continuous dynamics.
Abstract Nonintegrable Poincaré systems with a continuous spectrum (so‐called large Poincaré systems, LPS) lead to the appearance of diffusive terms in the frame of classical or quantum dynamics. These terms break time symmetry. They lead, therefore, to limitations to classical trajectory theory and of wave‐function formalism (Schrödinger's equation). These diffusive terms correspond to well‐defined classes of dynamical processes (i.e., so‐called vacuum‐vacuum transitions). The diffusive effects are amplified in situations corresponding to persistent interactions. As a result, we have to include, already, in the fundamental dynamical description the two basic aspects, probability and irreversibility, which are so conspicuous on the macroscopic level. We have to formulate both classical and quantum mechanics on the Liouville level of probability distributions (or density matrices). For integrable systems, we recover the usual formulation of classical or quantum mechanics. Instead of being primitive concepts, which cannot be further analyzed, trajectories and wave functions appear as special solutions of the Liouville–von Neumann equations. This extension of classical and quantum dynamics permits us to unify the two concepts of nature that we inherited from the nineteenth century, based, on the one hand, on dynamical time‐reversible laws and, on the other, on an evolutionary view associated to entropy. It leads also to a unified formulation of quantum theory, avoiding the conventional dual structure based on Schrödinger's equation, on the one hand, and on the “collapse” of the wave function, on the other. A dynamical interpretation is given to processes such as decoherence or approach to equilibrium without any appeal to extra dynamic considerations (such as many‐world theory, coarse graining, or averaging over the environment). There is a striking parallelism between classical and quantum theory. For large Poincaré systems (LPS), we have, in general, both a “collapse” of trajectories and of wave functions. In both cases, we need a generalized formulation of dynamics in terms of probability distributions or density matrices. Since the beginning of this century, we have known that classical mechanics had to be generalized to take into account the existence of universal constants. We now see that classical as well as quantum mechanics also have to be extended to include unstable dynamical systems such as LPS. As a result, we achieve a new formulation of “laws of physics” dealing no more with certitudes but with probabilities. This formulation is appropriate to describe an open, evolving universe. © 1995 John Wiley & Sons, Inc.
We propose a new approach concerning the introduction of time-irreversibility in statistical mechanics. It is based on a transition function defined in terms of path integral and verifying a time-irreversible equation. We show first how dynamic processes may enter in the description of equilibrium states. In order to do that a characteristic time is associated with closed paths. For large isolated systems at equilibrium or for systems in contact with a thermostat our results are identical with those obtained with the Gibbs ensemble methods. For a model used in the microscopic approaches of the brownian motion no new basic assumption is required to predict a transition from a quantum state to a classical one exhibiting a time-irreversible behavior. This demonstration is sufficient to show that very well accepted approximations can lead to time-irreversible behaviors for a large class of systems. The difference between our work and the system+reservoir approaches is underlined. Here equilibrium states and irreversible processes are described on the same footing representing a progress in the question of time-irreversibility in statistical physics. The transition function is also used for describing a small system for which there is no thermodynamics. By adding to the transition function a second one characterizing the reverse motion we may describe time-reversible systems. In a simple case we replace two real valued transition functions by a complex function verifying a Schrodinger like equation. From this we see how to break the time-reversibility of this equation and how to investigate the connection quantum mechanics-thermodynamics from a very fundamental point of view.