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Physical Review A

Irreversible evolution of isolated quantum systems and a discreteness of time

Sidney Golden

Published Dec 1, 1992• 7 citations
Publisher

Abstract

The statistical operators of those isolated nonrelativistic quantum systems that are presumed to exhibit intrinsically irreversible evolutionary behavior are shown to be capable of undergoing only discontinuous changes that occur at successive instants of time that are suggestive of possible temporal discreteness and that result in ``mixed-state'' conditions of the systems. Presuming such discrete temporal structure, a temporally asymmetric difference equation is derived for these statistical operators that suffices to imply their irreversible discontinuous evolution and from which both predictability and retrodictability of their temporal behavior are possible, but the latter cannot be extended indefinitely into the past.

DOI
10.1103/physreva.46.6805

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The statistical operators of those isolated nonrelativistic quantum systems that are presumed to exhibit intrinsically irreversible evolutionary behavior are shown to be capable of undergoing only discontinuous changes that occur at successive instants of time that are suggestive of possible temporal discreteness and that result in ``mixed-state'' conditions of the systems. Presuming such discrete temporal structure, a temporally asymmetric difference equation is derived for these statistical operators that suffices to imply their irreversible discontinuous evolution and from which both predictability and retrodictability of their temporal behavior are possible, but the latter cannot be extended indefinitely into the past.
It is shown that the usual proofs of the quasiperiodicity of isolated, finite quantum-statistical systems, previously thought to be general proofs, are in reality based on the special case of a discrete array. Quasiperiodicity is demonstrated for the analogous special case (the discrete distribution) in classical statistical mechanics. The density-operator formalism is set up for the case of a continuous array. The question of the possibly irreversible behavior of isolated, finite quantum-statistical systems with continuous arrays is investigated. An argument is given indicating that such systems generally behave irreversibly. The situations in classical and quantum statistics then appear to be entirely analogous, since it is well known that isolated, finite classical-statistical systems may, in the case of a continuous distribution (the analog of a continuous quantum-statistical array), behave irreversibly.
We present a theory of discontinuous motion of particles in continuous space-time. We show that the simplest nonrelativistic evolution equation of such motion is just the Schrodinger equation in quantum mechanics. This strongly implies what quantum mechanics describes is discontinuous motion of particles. Considering the fact that space-time may be essentially discrete when considering gravity, we further present a theory of discontinuous motion of particles in discrete space-time. We show that its evolution will naturally result in the dynamical collapse process of the wave function, and this collapse will bring about the appearance of continuous motion of objects in the macroscopic world.
The concept of irreversibility is necessary to justify the statistical description of many-body systems. Here, the authors study the dynamics of observable echoes in quantum many-body systems occurring when the time-evolution is effectively inverted. For nonintegrable systems they find that small imperfections in the time-reversal procedure that alter the state of the system lead to exponentially decaying echoes. As the corresponding decay rate is largely independent of the strength of the perturbation, an intrinsic sensitivity to the perturbation is revealed. This implies irreversibility of the dynamics for all practical purposes, similar to the situation in chaotic classical systems.
We present a theory of discontinuous motion of particles in continuous space-time. We show that the simplest nonrelativistic evolution equation of such motion is just the Schroedinger equation in quantum mechanics. This strongly implies what quantum mechanics describes is discontinuous motion of particles. Considering the fact that space-time may be essentially discrete when considering gravity, we further present a theory of discontinuous motion of particles in discrete space-time. We show that its evolution may naturally result in the dynamical collapse process of the wave function, and this collapse will bring about the appearance of continuous motion of objects in the macroscopic world.
We propose a new approach concerning the introduction of time-irreversibility in statistical mechanics. It is based on a transition function defined in terms of path integral and verifying a time-irreversible equation. We show first how dynamic processes may enter in the description of equilibrium states. In order to do that a characteristic time is associated with closed paths. For large isolated systems at equilibrium or for systems in contact with a thermostat our results are identical with those obtained with the Gibbs ensemble methods. For a model used in the microscopic approaches of the brownian motion no new basic assumption is required to predict a transition from a quantum state to a classical one exhibiting a time-irreversible behavior. This demonstration is sufficient to show that very well accepted approximations can lead to time-irreversible behaviors for a large class of systems. The difference between our work and the system+reservoir approaches is underlined. Here equilibrium states and irreversible processes are described on the same footing representing a progress in the question of time-irreversibility in statistical physics. The transition function is also used for describing a small system for which there is no thermodynamics. By adding to the transition function a second one characterizing the reverse motion we may describe time-reversible systems. In a simple case we replace two real valued transition functions by a complex function verifying a Schrodinger like equation. From this we see how to break the time-reversibility of this equation and how to investigate the connection quantum mechanics-thermodynamics from a very fundamental point of view.
We consider the temporal evolution of an isolated system of particles from a non-equilibrium state of entropy S = S′ to the equilibrium state of maximum entropy S = S max, S′ ≤ S max. The application of usual density matrix theory to the temporal development of S leads us to the unexpected result P = dS/dt = 0. The entropy does not change in time. This result is valid in case of the equilibrium state. However it is wrong for a non-equilibrium state, which could not irreversibly change from S′ to S max by entropy production P > 0. This contradicts the second law of thermodynamics. The paradoxial result can be traced back to the Liouville theorem. To overcome this difficulty, we introduce the t–P space. The time t and the entropy production P are observables in quantum thermodynamics. They are defined by the eigenvalue equations t|t〉 = t|t〉 and P|P〉 = P|P〉. The operators t and P do not commute. We have a non-vanishing commutator, [t,P] = ik, and consequently a t–P uncertainty relation, ΔtΔP ≥ k/2. The Boltzmann constant k is characteristic of quantum thermodynamics and represents the atomic entropy unit. — The time evolution operator U(τ) = exp[−(i/k)τP] shifts the time t by τ, U(τ)|t〉 = |t + τ〉. The generator of τ is the operator P of entropy production. Then the eigenvector |P〉 is also an eigenket of U(t), and it follows with progressing time τ ≥ 0 that τP ≥ 0 and hence P = dS/dt ≥ 0. This is the second law of thermodynamics, which is correctly reproduced in quantum thermodynamics. — Exchanging −τ for +τ replaces the equations of forward time +τ by the equations of backward time −τ. Independent of the direction of the arrow of time, the entropy of the system always increases or remains constant in the limit of the equilibrium state, dS ≥ 0. This is characteristic of irreversibility, for the system does not return to its initial state on time reversal. — The t–P uncertainty relation allows to discuss the temporal evolution of the expectation value 〈P〉 of entropy production and the lifetime Δt of the transient states, the system passes through on approaching the equilibrium state. In case of a non-equilibrium state 〈P〉, ΔP, and Δt are finite. On approaching the equilibrium state, 〈P〉 and ΔP decrease, consequently Δt increases. Finally, in the case of equilibrium (eq), we have 〈P〉eq = 0, ΔP eq = 0, and Δt eq → ∞. The lifetime of the equilibrium state is unlimited, because the entropy production 〈P〉 and the uncertainty of entropy production ΔP exactly vanish. The temporal evolution of the system can be described by means of a phenomenological equation.