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Journal of Applied Physics

Thermodynamics of alternate Ising chains of spins 1 and 3/2 with dipolar, biquadratic, and single ion interactions

Elton Casado Fireman, Roberto J. V. dos Santos

Published Apr 15, 1997• 4 citations
Publisher

Abstract

Within a recently developed extended decoration-transformation formalism we study the thermodynamic properties of a linear chain of alternate Ising σ=1 and S=3/2 spins. We allow for different anisotropy fields on each subchain of different spins. For some range of the parameter space we show the existence of a crossover from a ferromagnetic to an antiferromagnetic-like behavior of the model, as explicitly captured in the susceptibility results.

DOI
10.1063/1.365119

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Within a recently developed extended decoration-transformation formalism we study the thermodynamic properties of a linear chain of alternate Ising σ=1 and S=3/2 spins. We allow for different anisotropy fields on each subchain of different spins. For some range of the parameter space we show the existence of a crossover from a ferromagnetic to an antiferromagnetic-like behavior of the model, as explicitly captured in the susceptibility results.
The linear real space renormalization group is applied to study alternating spin (1/2,1) chains. The temperature dependences of the specific heat and spin–spin correlation functions for the quantum easy-axis mixed-spin chain are found. The role of single-ion anisotropy is discussed. The phase diagram of Ising spin chains with antiferromagnetic intrachain interactions and weak ferromagnetic interchain interactions is presented. As one expects, the weak interchain coupling leads to antiferrimagnetic long-range order in several chains. The threshold value of single-ion anisotropy below which the system does not exhibit a phase transition is found.
The "star-triangle" and "decoration" transformations are generalized so as to apply to arbitrary mechanical systems coupled to the spins of a standard Ising net. This leads to exact solutions for further plane Ising nets and also for lattices in which the spins on alternate sites have a magnitude greater than S=12S=\frac{1}{2}S=21​. A general class of antiferromagnetic Ising models is constructed; exact closed expressions can be derived for all the thermodynamic and magnetic properties of these models in an arbitrary magnetic field.The magnetizations and susceptibilities of Ising nets in which different spins have different magnetic moments are investigated and a valuable relation between the susceptibilities of the honeycomb and triangular lattices is derived. It is shown how correlation functions involving a given spin can be expressed in terms of correlations involving the nearest-neighbor spins instead.
The thermodynamic properties of a spin S=1/2S=1/2S=1/2 tetrameric Heisenberg antiferromagnetic chain with alternating interactions AF1-AF2-AF1-F{\text{AF}}_{1}{\text{-AF}}_{2}{\text{-AF}}_{1}\text{-F}AF1​-AF2​-AF1​-F (AF and F denote the antiferromagnetic and ferromagnetic couplings, respectively) are studied by means of the transfer-matrix renormalization-group method and Jordan-Wigner transformation. It is found that in the absence of magnetic field, the thermodynamic behaviors are closely related to the gapped low-lying excitations, and a novel structure with three peaks in the temperature dependence of specific heat is unveiled. In a magnetic field, a phase diagram in the temperature-field plane for the couplings satisfying JAF1=JAF2=JF{J}_{{\text{AF}}_{1}}={J}_{{\text{AF}}_{2}}={J}_{\text{F}}JAF1​​=JAF2​​=JF​ is obtained, in which various phases are identified. The temperature dependence of thermodynamic quantities including the magnetization, susceptibility, and specific heat are studied to characterize the corresponding phases. It is disclosed that the magnetization has a crossover behavior at low temperature in the Luttinger liquid phase, which is shown falling into the same class as that in the S=1S=1S=1 Haldane chain. In the plateau regime, the thermodynamic behaviors alter at a certain field, which results from the crossing of two excitation spectra. By means of the fermion mapping, it is uncovered that the system has four spectra from fermion and hole excitations that are responsible for the observed thermodynamic behaviors.
Within a new type of correlated-effective-field theory we calculate the effective-field parameters (including their response to external field), critical temperatures, susceptibility, short-range order parameters, and specific heat associated with an anisotropic, square-lattice, spin-\textonehalf{} Ising ferromagnet. The present formalism, which is shown to recover the Bethe-Peierls thermodynamics for the pure ZZZ-coordinated-lattice, spin-\textonehalf{} Ising model, yields satisfactory results; in particular, the crossover from a pure Ising ferromagnet on a square lattice to that on a linear chain is reasonably exhibited in the behavior of the susceptibility and the specific heat.
Using the Jordan-Wigner transformation and continued fractions we calculate rigorously the thermodynamic quantities for the spin-1/2 transverse Ising chain with periodically varying intersite interactions and/or on-site fields. We consider in detail the properties of the chains having a period of the transverse field modulation equal to 3. The regularly alternating transverse Ising chain exhibits several quantum phase transition points, where the number of transition points for a given period of alternation strongly depends on the specific set of the Hamiltonian parameters. The critical behavior in most cases is the same as for the uniform chain. However, for certain sets of the Hamiltonian parameters the critical behavior may be changed and weak singularities in the ground-state quantities appear. Due to the regular alternation of the Hamiltonian parameters the transverse Ising chain may exhibit plateaulike steps in the zero-temperature dependence of the transverse magnetization vs transverse field and many-peak temperature profiles of the specific heat. We compare the ground-state properties of regularly alternating transverse Ising and transverse XX chains and of regularly alternating quantum and classical chains. Making use of the corresponding unitary transformations we extend the elaborated approach to the study of thermodynamics of regularly alternating spin-1/2 anisotropic XY chains without field. We use the exact expression for the ground-state energy of such a chain of period 2 to discuss how the exchange interaction anisotropy destroys the spin-Peierls dimerized phase.
Thermodynamic properties of a tetrameric bond-alternating Heisenberg spin chain with ferromagnetic-ferromagnetic-antiferromagnetic-antiferromagnetic exchange interactions are studied using the transfer-matrix renormalization group and compared to experimental measurements. The temperature dependence of the uniform susceptibility exhibits typical ferrimagnetic features. Both the uniform and staggered magnetic susceptibilities diverge in the limit $T\ensuremath{\rightarrow}0$, indicating that the ground state has both ferromagnetic and antiferromagnetic long-range orders. A double-peak structure appears in the temperature dependence of the specific heat. Our numerical calculation gives a good account for the temperature and field dependence of the susceptibility, the magnetization, and the specific heat for $\mathrm{Cu}{(3\text{\ensuremath{-}}\mathrm{Clpy})}_{2}{({\mathrm{N}}_{3})}_{2}$ $(3\text{\ensuremath{-}}\mathrm{Clpy}=3\text{\ensuremath{-}}\text{Chloroyridine})$.