Mean-field theory is a widely used approximation for describing phase transitions, particularly effective above the upper critical dimension. Its origins can be traced back to the van der Waals theory of the liquid-gas transition and Weiss's molecular field theory of the paramagnetic-ferromagnetic transition. However, it was Lev D. Landau who provided a unifying and general framework applicable to a broad class of physical systems. The mean-field approach typically involves neglecting thermal fluctuations, which is a reasonable assumption in many classical contexts. However, its application to quantum phase transitions at zero temperature is less common. The aim of this short pedagogical paper is to explore and clarify the use of the mean-field approach in the less familiar domain of quantum phase transitions. We specifically consider the Ising model and the Blume-Capel model.
Mean-field theory is a widely used approximation for describing phase transitions, particularly effective above the upper critical dimension. Its origins can be traced back to the van der Waals theory of the liquid-gas transition and Weiss's molecular field theory of the paramagnetic-ferromagnetic transition. However, it was Lev D. Landau who provided a unifying and general framework applicable to a broad class of physical systems. The mean-field approach typically involves neglecting thermal fluctuations, which is a reasonable assumption in many classical contexts. However, its application to quantum phase transitions at zero temperature is less common. The aim of this short pedagogical paper is to explore and clarify the use of the mean-field approach in the less familiar domain of quantum phase transitions. We specifically consider the Ising model and the Blume-Capel model.
This and the four next chapters are devoted to the study of several aspects of the theory of phase transition. This has been for more than one century, and still remains, a subject of intense experimental and theoretical activity, with important breakthroughs having impacts on different fields in physics but also on other disciplines such as mathematics, economics, sociology, biology In the first section of this chapter, the transition between the ferromagnetic and paramagnetic phases of the Ising system will be studied in the framework of a mean field approximation. The problem will first be addressed by means of the intuitive Weiss molecular field approximation ( Section 9.1.2 ) and then by means of the more detailed Bragg-Williams approximation ( Section 9.1.3 ) which will serve as a base to develop, in Section 9.2 , a general theory of continuous phase transitions: the Landau mean field theory for which the concept of order parameter will first be introduced. Other types of phase transitions will then be studied using the mean field approximation. Phase transitions in liquid crystals will be studied in Section 9.3 . These are systems with a tensor order parameter which exhibit a rich phenomenology. Finally, in Section 9.4 , a transition of a fairly more elaborate nature than a simple first or second order phase transition will be discussed.
Chapter 17 presented one example of a phase transition, the van der Waals gas. This chapter provides another, the Ising model, a widely studied model of phase transitions. We first give the solution for the Ising chain (one-dimensional model), including the introduction of the transfer matrix method. Higher dimensions are treated in the Mean Field Approximation (MFA), which is also extended to Landau theory. The Ising model is deceptively simple. It can be defined in a few words, but it displays astonishingly rich behavior. It originated as a model of ferromagnetism in which the magnetic moments were localized on lattice sites and had only two allowed values.
Mean-field theory, presented in the preceding chapter, correctly describes the qualitative features of most phase transitions and, in some cases, the quantitative features. Since mean-field theory replaces the actual configurations of the local variables (e.g. spins) by their average value, it neglects the effects of fluctuations about this mean. These fluctuations may or may not be important. The more spins that interact with a particular test spin, the more the test spin sees an effective average or mean field. If the test spin interacts with two neighbors, the averaging is minimal and the fluctuations are large and important. The number of spins producing the effective field increases with the range of the interaction and with the dimension. Thus we will find that mean-field theory is a good approximation in high dimensions but fails to provide a quantitatively correct description of second-order critical points in low dimensions. This chapter will be devoted to the study of second-order phase transitions when mean-field theory is not a good approximation. We will begin by considering fluctuations of the order parameter about its spatially uniform mean-field value. We will find that for spatial dimensions below an upper critical dimension d c (typically d c = 4), fluctuations always become important and invalidate mean-field theory for temperatures sufficiently close to T c . This will motivate a generalization of Landau theory that incorporates spatial fluctuations about a mean-field free energy minimum.
Abstract This chapter is devoted to a brief review of general properties of phase transitions in macroscopic physics and, in particular in lattice models. Some of these lattice models actually appear as lattice regularizations of Euclidean (imaginary time) quantum physics theory (QFT). Most of the transitions considered in this work have the following character: spins on the lattice, or macroscopic particles in the continuum, interact through short-range forces, assumed, for simplicity, to decay exponentially. For simple systems, it is possible to find a local observable, called order parameter, whose expectation values depend on the phase in the several phase region, for example, the spin in ferromagnetic systems. In the disordered phase, the connected two-point function decreases exponentially at large distance, at a rate characterized by the correlation length (the inverse of the smallest physical mass in particle physics). In continuous transitions, the correlation length diverges at the critical temperature. Within the mean-field approximation (consistent with Landau's theory of critical phenomena), it can be shown that the singular behaviour of thermodynamic quantities at the critical temperature is universal. These properties can also be reproduced by calculating correlation functions with a perturbed Gaussian measure. It is then shown that the leading corrections to the mean-field approximation, in Ising-like systems, diverge at the critical temperature for dimensions smaller than or equal to 4.
The article provides a tutorial review on how to treat Ising models within mean-field (MF), effective-field (EF) and exact methods. MF solutions of the spin-1 Blume-Capel (BC) model and the mixed-spin Ising model demonstrate a change of continuous phase transitions to discontinuous ones at a tricritical point. A quantum phase transition of the spin-S Ising model driven by a transverse field is explored within MF method. EF theory is elaborated within a single- and two-spin cluster approach to demonstrate an efficiency of this approximate method. The long-standing problem of this method concerned with a self-consistent determination of the free energy is addressed. EF theory is adapted for the spin-1/2 Ising model, the spin-S BC model and the transverse Ising model. The particular attention is paid to continuous and discontinuous transitions. Exact results for the spin-1/2 Ising chain, spin-1 BC chain and mixed-spin Ising chain are obtained using the transfer-matrix method, the crucial steps of which are reviewed for a spin-1/2 Ising square lattice. Critical points of the spin-1/2 Ising model on several lattices are rigorously obtained with the help of dual, star-triangle and decoration-iteration transformations. Mapping transformations are adapted to obtain exact results for the mixed-spin Ising model on planar lattices. An increase in the coordination number of the mixed-spin Ising model on decorated planar lattices gives rise to reentrant transitions, while the critical temperature of the mixed-spin Ising model on a regular honeycomb lattice is always greater than that of two semi-regular archimedean lattices. The effect of selective site dilution of the mixed-spin Ising model on a honeycomb lattice upon phase diagrams is examined. The review affords a brief account of the Ising models solved within MF, EF and exact methods along with a few comments on their future applicability.
These lectures describe the physics of phase transitions and critical phenomena. After introducing the thermodynamics of phase transitions, these general considerations are made explicit by presenting statistical mechanical calculations on a lattice gas model in the mean-field approximation. Then the Landau theory of phase transitions is presented. The form of free energy in the Landau theory is motivated by an explicit mean field calculation for the Ising model. This is followed by a discussion of spatial correlations and the breakdown of the mean field theory due to increase of spatial fluctuations near the critical point. This calculation also brings out the role of dimension of the system for the critical behaviour. The basic ideas of Renormalization Group (RG) are then introduced and illustrated by a simple RG calculation for the one-dimensional Ising model. Real-space RG calculations are then applied to the two-dimensional Ising model on the triangular lattice, which, in fact, brings forth several key features of the RG technique. A discussion of more general aspects of the RG formalism, such as scaling for spatial correlation functions, relevant and irrelevant couplings, universality, upper critical dimension, etc. are introduced.