A general thermal machine is characterized by distinct time or energy scales: temperature, coupling to the heat baths, internal free dynamics and interactions, and external driving. We address the question: what parameters determine the speed of a given engine, and how can they be used to reliably compare different types of engine? Specifically, we consider four realizations of the Otto engine, each operating with the same Otto efficiency, and aim to characterize and compare their power outputs. The main insight of this paper is that, irrespective of their very different dynamical implementations, the power of each engine can be factorized into a common characteristic work and an implementation-specific characteristic time. The characteristic work depends only on the internal frequencies of the machine and the temperatures, whereas the characteristic time depends on the coupling strength to the baths and on the implementation-specific driving. This observation allows us to compare the power of different engines through their characteristic times and thereby reduce the relevant parameter space to parameters that capture the dynamical aspects of engine performance. Despite different dynamical implementations, this framework reveals simple common features. In all cases, the maximum operating speed is limited by a common timescale given by the sum of the characteristic thermalization times of the hot and cold baths. Moreover, the four engines fall into two distinct asymptotic classes: implementations in which driving and thermalization occur simultaneously exhibit quadratic scaling, whereas those in which work extraction and thermalization alternate exhibit linear scaling. These results expose general dynamical features that determine the operational speed of quantum Otto engines.
A general thermal machine is characterized by distinct time or energy scales: temperature, coupling to the heat baths, internal free dynamics and interactions, and external driving. We address the question: what parameters determine the speed of a given engine, and how can they be used to reliably compare different types of engine? Specifically, we consider four realizations of the Otto engine, each operating with the same Otto efficiency, and aim to characterize and compare their power outputs. The main insight of this paper is that, irrespective of their very different dynamical implementations, the power of each engine can be factorized into a common characteristic work and an implementation-specific characteristic time. The characteristic work depends only on the internal frequencies of the machine and the temperatures, whereas the characteristic time depends on the coupling strength to the baths and on the implementation-specific driving. This observation allows us to compare the power of different engines through their characteristic times and thereby reduce the relevant parameter space to parameters that capture the dynamical aspects of engine performance. Despite different dynamical implementations, this framework reveals simple common features. In all cases, the maximum operating speed is limited by a common timescale given by the sum of the characteristic thermalization times of the hot and cold baths. Moreover, the four engines fall into two distinct asymptotic classes: implementations in which driving and thermalization occur simultaneously exhibit quadratic scaling, whereas those in which work extraction and thermalization alternate exhibit linear scaling. These results expose general dynamical features that determine the operational speed of quantum Otto engines.
We consider the finite-time performance of a quantum Otto engine working between a hot squeezed and a cold thermal bath at inverse temperatures ${\ensuremath{\beta}}_{h}$ and ${\ensuremath{\beta}}_{c}(>{\ensuremath{\beta}}_{h})$ with $({k}_{B}\ensuremath{\equiv}1)\ensuremath{\beta}=1/T$. We derive the analytical expressions for work, efficiency, power, and power fluctuations, in which the squeezing parameter is involved. By optimizing the power output with respect to two frequencies, we derive the efficiency at maximum power as ${\ensuremath{\eta}}_{mp}={({\ensuremath{\eta}}_{C}^{\mathrm{gen}})}^{2}/[{\ensuremath{\eta}}_{C}^{\mathrm{gen}}\ensuremath{-}(1\ensuremath{-}{\ensuremath{\eta}}_{C}^{\mathrm{gen}})ln(1\ensuremath{-}{\ensuremath{\eta}}_{C}^{\mathrm{gen}})]$, where the generalized Carnot efficiency ${\ensuremath{\eta}}_{C}^{\mathrm{gen}}$ in the high-temperature or small squeezing limit simplifies to an analytic function of squeezing parameter $\ensuremath{\gamma}$: ${\ensuremath{\eta}}_{C}^{\mathrm{gen}}=1\ensuremath{-}{\ensuremath{\beta}}_{h}/[{\ensuremath{\beta}}_{c}cosh(2\ensuremath{\gamma})]$. Within the context of irreversible thermodynamics, we demonstrate that the expression of efficiency at maximum power satisfies a general form derived from nonlinear steady state heat engines. We show that, the power fluctuations are considerably increased, although the engine efficiency is enhanced by squeezing.
We put forward four schemes of a coupled-qubit quantum Otto machine, a generalization of the single-qubit quantum Otto machine, based on work and heat transfer between an internal system consisting of a coupled pair of qubits and an external environment consisting of two heat baths and two work storages. The four schemes of our model are defined by the positions of attaching the heat baths, which play a key role in the power of the coupled-qubit engine. First, for the single-qubit heat engine, we find a maximum-power relation, and the fact that its efficiency at the maximum power is equal to the Otto efficiency, which is greater than the Curzon-Ahlborn efficiency. Second, we compare the coupled-qubit engines to the single-qubit engine from the point of view of achieving the maximum power based on the same energy-level change for work production and find that the coupling between the two qubits can lead to greater powers but the system efficiency at the maximum power is lower than the single-qubit system's efficiency and the Curzon-Ahlborn efficiency. Published by the American Physical Society 2024
Abstract This paper presents an analysis of quantum Otto heat engines operating in non-equilibrium. It explores the fundamental thermodynamic principles that govern these engines, focusing on efficiency, work output, and the impact of environmental factors such as thermal gradients, external fields, noise, and decoherence. The study investigates the effects of non-equilibrium conditions on engine performance, highlighting challenges and opportunities in practical realizations. Through numerical simulations, the article examines the power, efficiency, and performance coefficients, revealing trade-offs between these metrics and the influence of temperature differences and internal coupling strength. The results demonstrate that non-equilibrium effects can significantly reduce efficiency compared to ideal scenarios, emphasizing the importance of considering both quantum effects and real-world limitations in the design and optimization of quantum heat engines. This work contributes to the growing body of knowledge in quantum thermodynamics, offering insights for quantum computing, sustainable energy technologies, and thermodynamic cycles at the quantum scale.
Algebraic methods for solving time-dependent Hamiltonians are used to investigate the performance of quantum thermal machines. We investigate the thermodynamic properties of an engine formed by two coupled qubits, performing an Otto cycle. The thermal interaction occurs with two baths at different temperatures, while work is associated with the interaction with an arbitrary time-dependent magnetic field that varies in intensity and direction. For the coupling, we consider the 1D isotropic Heisenberg model, which allows us to describe the system by means of the irreducible representation of the su(2) Lie algebra within the triplet subspace. We also inspect different settings of the temperatures and frequencies of the cycle, and investigate the corresponding operation regimes. We describe how these regimes can change with the speed of the protocol. Finally, we compare the weak and strong coupling regimes, and conclude that for the weak case the efficiency is optimal and can surpass the value of the classical Otto cycle. For low temperatures of the heat baths, we show that losses due to quantum friction are reduced in the strong coupling limit.
We study the optimization of the performance of arbitrary periodically driven thermal machines. Within the assumption of fast modulation of the driving parameters, we derive the optimal cycle that universally maximizes the extracted power of heat engines, the cooling power of refrigerators, and in general any linear combination of the heat currents. We denote this optimal solution as ``generalized Otto cycle'' since it shares the basic structure with the standard Otto cycle, but it is characterized by a greater number of fast strokes. We bound this number in terms of the dimension of the Hilbert space of the system used as working fluid. The generality of these results allows for a widespread range of applications, such as reducing the computational complexity for numerical approaches, or obtaining the explicit form of the optimal protocols when the system-baths interactions are characterized by a single thermalization scale. In this case, we compare the thermodynamic performance of a collection of optimally driven noninteracting and interacting qubits. Remarkably, for refrigerators the noninteracting qubits perform almost as well as the interacting ones, while in the heat engine case there is a many-body advantage both in the maximum power, and in the efficiency at maximum power. Additionally, we illustrate our general results studying the paradigmatic model of a qutrit-based heat engine. Our results strictly hold in the semiclassical case in which no coherence is generated by the driving, and finally we discuss the noncommuting case.
This paper presents an analysis of quantum Otto heat engines operating out of equilibrium. It explores the fundamental thermodynamic principles governing these engines, focusing on efficiency, work output, and the impact of environmental factors, including thermal gradients, external fields, noise, and decoherence. The study investigates the effects of non-equilibrium conditions on engine performance, highlighting challenges and opportunities in practical realizations. Through numerical simulations, the article examines the power, efficiency, and performance coefficients, revealing trade-offs between these metrics and the influence of temperature differences and internal coupling strength. The results demonstrate that non-equilibrium effects can significantly reduce efficiency compared to idealized scenarios, underscoring the importance of accounting for both quantum effects and real-world constraints in the design and optimization of quantum heat engines. This work contributes to the growing body of knowledge in quantum thermodynamics, offering insights for quantum computing, sustainable energy technologies, and thermodynamic cycles at the quantum scale.