Under non-equilibrium conditions, energy/particle currents flow through a quantum system coupled to multiple baths. Although the fluxes increase in the weak coupling regime as the coupling strengthens, the reason why they decrease to zero for large coupling remains unknown. This counterintuitive behavior of energy exchange or transport phenomena is called the turnover effect. It has been predicted in several quantum systems such as photosynthetic complexes, mesoscopic junctions, quantum heat machines, and chemical networks without a single counterexample, and it results in constrained performance due to limited currents. Here, we use scattering theory to study the turnover effect produced by low-zdensity reservoirs of free particles scattered by a quantum system through localized potentials. We find that the turnover effect is a consequence of total reflection that impedes the reservoir particle from reaching the interaction region and exchanging energy with the quantum system. Moreover, we design a protocol based on quantum tunneling to avoid the turnover and to increase the maximum current. This strategy could be used to unleash the full potential of devices based on temperature/chemical potential gradients.
Under non-equilibrium conditions, energy/particle currents flow through a quantum system coupled to multiple baths. Although the fluxes increase in the weak coupling regime as the coupling strengthens, the reason why they decrease to zero for large coupling remains unknown. This counterintuitive behavior of energy exchange or transport phenomena is called the turnover effect. It has been predicted in several quantum systems such as photosynthetic complexes, mesoscopic junctions, quantum heat machines, and chemical networks without a single counterexample, and it results in constrained performance due to limited currents. Here, we use scattering theory to study the turnover effect produced by low-zdensity reservoirs of free particles scattered by a quantum system through localized potentials. We find that the turnover effect is a consequence of total reflection that impedes the reservoir particle from reaching the interaction region and exchanging energy with the quantum system. Moreover, we design a protocol based on quantum tunneling to avoid the turnover and to increase the maximum current. This strategy could be used to unleash the full potential of devices based on temperature/chemical potential gradients.
Quantum heat transport for non-equilibrium steady state (NESS) exhibits a characteristic turnover effect, where the heat current reaches a maximum and subsequently declines as system-bath coupling increases. Although numerically exact methods can simulate this non-monotonic behavior, they offer limited information on the thermal state of the heat baths. Here, we introduce a frequency-selective thermometric protocol to probe the baths sustaining an NESS. By extracting a frequency-resolved effective temperature spectrum using a tunable two-level probe, we demonstrate that spectral dispersion serves as a direct witness for the non-equilibrium state of the heat baths. To demonstrate the protocol, we applied the hierarchical equations of motion to spin-boson and two-qubit models, though any exact method can be used. For both models, the turnover effect can be explained by how the thermal state of the heat baths evolves as the system-bath coupling strength increases.
Quantum heat transport governs energy exchange processes and statistical laws in non-equilibrium quantum systems, and plays a pivotal role in quantum thermodynamics. We investigate the steady-state thermal transport of a noncommuting coupled spin system. We employ the quantum dressed master equation approach within the framework of open quantum system theory to accurately analyze the non-equilibrium dynamics, ensuring the validity of transport results in the strong coupling regime. Our results demonstrate that noncommuting spin coupling serves as a significant resource for modulating the nonlinearity of the heat current. Specifically, in the weak spin-coupling regime, the system exhibits robust negative differential thermal conductance (NDTC) across various spin numbers. By deriving analytical expressions for the heat current in both the single-spin and large-spin limits, we reveal that this NDTC behavior is governed by microscopic cycle fluxes. Physically, this arises because spin excitation channels induced by the cold reservoir are suppressed under a large temperature bias, thereby blocking energy exchange cycles. Conversely, in the strong spin-coupling and large temperature bias regime, the quantum system demonstrates pronounced thermal rectification. This high rectification efficiency originates from the unidirectional saturation of the heat current, rendering the system a promising candidate for high-performance thermal diodes. Furthermore, we extend the model to a three-terminal configuration to construct a quantum thermal transistor. By manipulating the temperature of the gate reservoir, we achieve efficient modulation and amplification of heat flow between the source and drain. The heat amplification factor is shown to far exceed unity in specific operating regions, confirming significant thermal amplification.
We consider a system consisting of two interacting qubits that are individually coupled to separate heat baths at different temperatures. The quantum effects in heat transport are investigated in a numerically rigorous manner with a hierarchial equations of motion (HEOM) approach for non-perturbative and non-Markovian system-bath coupling cases under non-equilibrium steady-state conditions. For a weak interqubit interaction, the total system is regarded as two individually thermostatted systems, whereas for a strong interqubit interaction, the two-qubit system is regarded as a single system coupled to two baths. The roles of quantum coherence (or entanglement) between the two qubits (q-q coherence) and between the qubit and bath (q-b coherence) are studied through the heat current calculated for various strengths of the system-bath coupling and interqubit coupling for high and low temperatures. The same current is also studied using the time convolutionless (TCL) Redfield equation and using an expression derived from the Fermi golden rule (FGR). We find that the HEOM results exhibit turnover behavior of the heat current as a function of the system-bath coupling strength for all values of the interqubit coupling strength, while the results obtained with the TCL and FGR approaches do not exhibit such behavior, because they do not possess the capability of treating the q-b and q-q coherences. The maximum current is obtained in the case that the q-q coherence and q-b coherence are balanced in such a manner that coherence of the entire heat transport process is realized. We also find that the heat current does not follow Fourier's law when the temperature difference is very large, due to the non-perturbative system-bath interactions.
The challenge of harnessing entanglement during the non-equilibrium dynamics of open quantum systems, especially at high temperatures, is highly prominent within recent scientific researches. Due to the ongoing trend of miniaturization of quantum devices that exploit quantum correlations, proposing novel schemes to overcome this challenge is itself a crucial task within current quantum technological research. We contribute to this research by proposing a new scheme to control entanglement dynamics of a non-equilibrium two-qubit Heisenberg XXZ spin chain model in an external magnetic field. The design of the scheme is based on a coupling asymmetry in the model induced by the asymmetrical connection of qubits to two independent thermal reservoirs. While in the absence of the coupling asymmetry, non-equilibrium effects generally suppress the dynamical generation of thermal entanglement, making entanglement production impossible at high mean temperatures of reservoirs, it is shown that this asymmetry in the coupling potentially enables us to generate a maximal non-equilibrium entanglement even in the high mean temperature regime. We show that the coupling asymmetry can also lead to a complete protection of the maximum initial entanglement between the qubits at high mean temperatures of the reservoirs thanks to the non-equilibrium conditions. Depending on the initial state of the two qubits, this can be achieved either by accessing a coherence-free subspace or by fully reviving the initial qubit-qubit entanglement. Furthermore, we investigate the quantum heat transport of the chain, and find that by turning on the asymmetry in the qubit-reservoir coupling, although the chain loses its initial thermal rectification property over time, it regains this property and maintain it until the non-equilibrium steady state is reached. Our results show that, at higher temperature gradients, the chain leverages the steady-state entanglement to completely block the heat released from the hot reservoir. Our findings can be significant for heat management in quantum computing devices such as solid-state thermal circuits.
Quantum transport simulations are rapidly evolving and now encompass well-controlled tensor network techniques for many-body limits. One powerful approach combines matrix product states with extended reservoirs. In this method, continuous reservoirs are represented by explicit, discretized counterparts and a chemical potential or temperature drop is maintained by external relaxation. Currents are strongly influenced by relaxation when it is very weak or strong, resulting in a simulation analog of Kramers turnover for solution-phase chemical reactions. At intermediate relaxation, the intrinsic conductance, that given by the Landauer or Meir-Wingreen expressions, moderates the current. We demonstrate that strong impurity scattering (i.e., a small steady-state current) reveals anomalous transport regimes within this methodology at weak-to-moderate and moderate-to-strong relaxation. The former is due to virtual transitions and the latter to unphysical broadening of the populated density of states. Thus, the turnover analog has five standard transport regimes, further constraining the parameters that lead to recovery of the intrinsic conductance. In the worst case, the common strategy of choosing a relaxation strength proportional to the reservoir level spacing can prevent convergence to the continuum limit. This advocates a simulation strategy where one utilizes the current versus relaxation turnover profiles to identify simulation parameters that most efficiently reproduce the intrinsic physical behavior.
This review presents a thermodynamic perspective on quantum coupled transport processes in nanoscale systems. Our analysis is formulated within the framework of entropy production rate, the central quantity governing non-equilibrium processes and expressed through conjugate force-flux pairs. Although thermodynamic laws are universal across classical and quantum domains, the discussion is developed within a microscopic open quantum system framework, focusing on quantum dots (QDs) coupled to electronic reservoirs. We first examine elementary single transport processes and highlight their strong thermodynamic constraints in the near-equilibrium regime. This motivates the study of coupled transport, where multiple force-flux pairs coexist and interact, leading to richer thermodynamic behaviour. Using entropy production as the guiding principle, we analyse coupled energy and particle transport in a minimal two-terminal single-QD setup and show how conventional thermoelectric phenomena, including Seebeck and Peltier effects as well as thermoelectric heat engines and refrigerators, naturally emerge as thermodynamic cross-effects. We then extend the framework to a three-terminal coupled quantum dot (CQD) geometry, which provides a versatile platform for studying coupled transport and reduces, under suitable constraints, to the well-known Sánchez-Büttiker configuration. Beyond standard cross-effects, we discuss the phenomenon of inverse currents in coupled transport (ICC), where a current flows against mutually parallel thermodynamic forces without violating the second law. We show that ICC requires breaking the symmetry between energy and particle transport and identify the conditions for its realization in coupled quantum-dot systems with attractive interdot interactions.