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arXiv:2607.03845

Quantum tunneling Mpemba effect

Hisao Hayakawa, Satoshi Takada

cond-mat.stat-mechquant-phSubmitted Jul 4, 2026• Announced Jul 7, 2026• 0 citations
v1 · Jul 4, 2026v2 · Sep 14, 2026
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Abstract

The quantum tunneling Mpemba effect is investigated within a continuous one-dimensional symmetric double-well potential open to external environmental sinks at the boundaries ($x=\pm L$). Using a non-Hermitian spectral decomposition of the effective Hamiltonian, we characterize the open-system relaxation dynamics without relying on abstract state-space quenches. We mathematically prove that the non-monotonic behavior of the first non-trivial even-parity spectral coefficient, $a_{2}(T_{i})$, with respect to the initial preparation temperature $T_{i}$ is a universal topological property born from quantum statistical mechanics. Crucially, we demonstrate that this intermediate thermal peak is governed by the Sturm-Liouville oscillation theorem and remains completely invariant with respect to the global system size $L$, contrasting sharply with the boundary-driven classical Mpemba effect. This universal peak arises from the geometric and nodal alignment between highly localized unperturbed states and extended non-Hermitian decay channels. Furthermore, we clarify that while this mechanism is robust, the actual observation of anomalous crossings in the total survival probability trace $S(t,T_{i})$ and the trace distance $\mathcal{D}(t,T_i)$ demand a strict separation of timescales, requiring the over-barrier escape rate to vastly exceed the decay rate of the deep-well tunneling doublet ($Γ_{2}\gg Γ_{0}$ and $Γ_2\gg Γ_1$). Our continuous formulation successfully bridges real-space classical boundary-driven dissipation with open quantum dynamics, providing novel insights for engineering non-equilibrium states via tailored boundary loss.

Comments
25 pages, 6 figures

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The quantum Mpemba effect refers to the counterintuitive phenomenon in which a system initially farther from equilibrium relaxes faster than one prepared closer to it. Several mechanisms have been identified in open quantum systems to explain this behavior, including the strong Mpemba effect, non-Markovian memory, and initial system-reservoir entanglement. Here, we unveil a distinct mechanism rooted in the non-normal nature of the Liouvillian superoperator in Markovian dynamics. When the Liouvillian's eigenmodes are non-orthogonal, transient interference between decaying modes can induce anomalous early-time behavior-such as delayed thermalization or transient freezing-even though asymptotic decay rates remain unchanged. This differs fundamentally from strong Mpemba effects, which hinge on suppressed overlap with slow-decaying modes. We demonstrate this mechanism using a waveguide quantum electrodynamics model, where quantum emitters interact with the photonic modes of a one-dimensional waveguide. The directional and radiative nature of these couplings naturally introduces non-normality into the system's dynamics. As a result, certain initial states-despite being closer to equilibrium-can exhibit slower relaxation at short times. This work reveals a previously unexplored and universal source of Mpemba-like behavior in memoryless quantum systems, expanding the theoretical framework for anomalous relaxation and opening new avenues for control in engineered quantum platforms.
Quantum Mpemba effect occurs when a quantum system, residing far away from the steady state, relaxes faster than a relatively nearer state. We look for the presence of this highly counterintuitive effect in the relaxation dynamics of the operators within the open quantum system setting. Since the operators evolve under a non-trace preserving map, the trace distance of an operator is not a monotonically decaying function of time, unlike its quantum state counterpart. Consequently, the trace distance can not serve as a reliable measure for detecting the Mpemba effect in operator dynamics. We circumvent this problem by defining a \textit{dressed} distance between operators that decays monotonically with time, enabling a generalized framework to explore the Mpemba-like effect for operators. Applying the formalism to various open quantum system settings, we find that, interestingly, in the single qubit case, only accelerated relaxation of operators is possible, while genuine Mpemba-like effects emerge in higher-dimensional systems such as qutrits and beyond. Furthermore, we demonstrate the existence of Mpemba-like effects in nonlocal, non-equilibrium operators, such as current, in a double-quantum-dot setup. Our results, besides offering fundamental insight about the occurrence of the Mpemba-like effect under non-trace preserving dynamics, open avenues for new experimental studies where quicker relaxation of observables could be of significant interest.
The behavior of systems far from equilibrium is often complex and unpredictable, challenging and sometimes overturning the physical intuition derived from equilibrium scenarios. One striking example of this is the Mpemba effect, which implies that non-equilibrium states can sometimes relax more rapidly when they are further from equilibrium. Despite a rich historical background, the precise conditions and mechanisms behind this phenomenon remain unclear. Recently, there has been growing interest in investigating accelerated relaxation and Mpemba-like effects within quantum systems. In this work, we explore a quantum manifestation of the Mpemba effect in a simple and paradigmatic model of open quantum systems: the damped quantum harmonic oscillator, which describes the relaxation of a bosonic mode in contact with a thermal bath at finite temperature T . By means of an exact analytical analysis of the relaxation dynamics based on the method of moments in both population and coherence subspaces, we demonstrate that any initial distribution of populations with the first r moments exactly matching those of the equilibrium distribution shows a super-accelerated relaxation to equilibrium at a rate linearly increasing with r , leading to a pronounced Mpemba effect. In particular, one can find a broad class of far-from-equilibrium distributions that relax to equilibrium faster than any other initial thermal state with a temperature T ′ arbitrarily close to T . The super-accelerated relaxation effect is shown to persist even for a broad class of initial states with non-vanishing coherences, and a general criterion for the observation of super-accelerated thermalization is presented.
The Unruh effect links acceleration to thermalization, providing a relativistic setting for anomalous quantum relaxation. We demonstrate a {\it relativistic} strong quantum Mpemba effect in the Unruh thermalization of a two-level detector coupled to a massless scalar field. For a fixed pair of isospectral initial states, relaxation curves that never cross in inertial motion exhibit a Mpemba crossing above a threshold acceleration. At a higher, precisely tuned acceleration, the initially farther state has zero overlap with the slowest decay mode and relaxes with a faster asymptotic exponential rate. We identify how competition between transition and dephasing channels governs the relaxation spectrum, where sufficiently strong longitudinal coupling enables acceleration to switch the relaxation bottleneck between population and coherence modes. We derive the spectral-switching condition and construct isospectral preparation protocols that eliminate slow-mode contributions within their physical domains. Our results establish acceleration as a control parameter for anomalous quantum relaxation, connecting relativistic quantum dynamics with nonequilibrium thermodynamics.
An ancient and counterintuitive phenomenon known as the Mpemba effect (water can cool faster when initially heated up) showcases the critical role of initial conditions in relaxation processes. How to realize and utilize this effect for speeding up relaxation is an important but challenging task in purely quantum system till now. Here, we experimentally study the strong Mpemba effect in a single trapped ion system in which an exponentially accelerated relaxation in time is observed by preparing an optimal quantum initial state with no excitation of the slowest decaying mode. Also, we demonstrate that the condition of realizing such effect coincides with the Liouvillian exceptional point, featuring the coalescence of both the eigenvalues and the eigenmodes of the systems. Our work provides an efficient strategy to engineer the dynamics of open quantum system, and suggests a link unexplored yet between the Mpemba effect and the non-Hermitian physics. The Mpemba effect is an archetype for various anomalous relaxation phenomena. Here, the authors experimentally study a quantum version of the Mpemba effect in a single trapped ion system, where relaxation is exponentially accelerated by removing the excitation of the slowest decaying mode. This phenomenon, seen in Markovian open quantum systems containing Liouvillian exceptional points, indicates a link between the Mpemba effect and non-Hermitian physics.
Understanding relaxation dynamics in open quantum systems is a central problem in nonequilibrium quantum physics. Here we investigate the quantum Mpemba effect in the spin boson model. In the weak coupling Markovian regime we show that the occurrence of the effect strongly depends on the choice of distance measure at low temperature: while it appears in the trace distance, it can disappear in the quantum relative entropy. Going beyond the weak-coupling approximation, numerically exact simulations of the full system bath dynamics reveal that increasing coupling enhances the effect in the trace distance and restores it in the quantum relative entropy. We uncover a simple Bloch sphere picture of the effect: within the excited-state hemisphere, pairs of states related by rotations and having the same Bloch-vector modulus generically exhibit an inversion of their relaxation ordering. This behavior is robust across sub Ohmic, Ohmic, and super Ohmic bath spectra. In the Ohmic and sub Ohmic regimes, the crossing time becomes strongly suppressed upon approaching the critical region, whereas in the super Ohmic regime the effect remains enhanced despite the absence of a finite-coupling localization transition. These results highlight the interplay between geometry, distance measures, system--environment coupling, and bath spectral properties in anomalous quantum relaxation.