The emergence of classical behavior and the origin of thermal equilibrium are two central problems in the foundations of physics. In the standard accounts, both phenomena are typically explained through interactions with an external environment: decoherence suppresses quantum interference, while coupling to a thermal bath drives relaxation toward equilibrium. Over the last decades, however, it has become clear that equilibration and thermalization can arise even in fully isolated quantum systems, in the operational sense that the expectation values of relevant observables remain close to equilibrium values for most of the time. Here, we ask whether the same intrinsic equilibration mechanism can also account for the emergence of classical behavior. Using rigorous bounds on equilibration in closed systems, we derive sufficient conditions under which a time-evolved pure state becomes, for most times, operationally indistinguishable from a classical mixture associated with a chosen physical property. We identify two complementary routes to such operational classicality: either the chosen property almost commutes with the system Hamiltonian or the observables used to probe the system lose access to the remaining coherence after equilibration. Our results show that classical behavior need not be confined to the energy basis and may emerge even when substantial coherence remains present in the equilibrium state. This establishes a direct connection between two foundational questions: the origin of thermalization in isolated quantum systems and the quantum-to-classical transition
The emergence of classical behavior and the origin of thermal equilibrium are two central problems in the foundations of physics. In the standard accounts, both phenomena are typically explained through interactions with an external environment: decoherence suppresses quantum interference, while coupling to a thermal bath drives relaxation toward equilibrium. Over the last decades, however, it has become clear that equilibration and thermalization can arise even in fully isolated quantum systems, in the operational sense that the expectation values of relevant observables remain close to equilibrium values for most of the time. Here, we ask whether the same intrinsic equilibration mechanism can also account for the emergence of classical behavior. Using rigorous bounds on equilibration in closed systems, we derive sufficient conditions under which a time-evolved pure state becomes, for most times, operationally indistinguishable from a classical mixture associated with a chosen physical property. We identify two complementary routes to such operational classicality: either the chosen property almost commutes with the system Hamiltonian or the observables used to probe the system lose access to the remaining coherence after equilibration. Our results show that classical behavior need not be confined to the energy basis and may emerge even when substantial coherence remains present in the equilibrium state. This establishes a direct connection between two foundational questions: the origin of thermalization in isolated quantum systems and the quantum-to-classical transition
Understanding how macroscopic thermodynamic behavior emerges from microscopic quantum dynamics remains an open problem. While equilibration of quantum observables is well established, thermodynamics also relies on variables not directly associated with linear operators, but which are defined instead as functions of expectation values. Whether and how such derived quantities inherit equilibration properties is an open question. Here, we establish that any continuously differentiable function of equilibrating expectation values also equilibrates. We apply this result to a bipartite isolated system, showing that the entropy and conjugate variables of each subsystem -- defined through Jaynes' maximum entropy principle -- equilibrate. Moreover, with the assumption that their equilibrium properties depend solely on local conserved quantities, we show the dynamical maximization of the total entropy, enforcing equality of conjugate variables across subsystems. These results provide a direct dynamical justification for entropy maximization and the emergence of thermodynamic equilibrium conditions, showing that fundamental principles of thermodynamics follow from the unitary evolution of quantum systems.
Macroscopic quantum superpositions are widely believed to be unobservable because large systems cannot be perfectly isolated from their environments. Here, we show that even under perfect isolation, intrinsic unitary dynamics in generic many-body systems, as analyzed through the eigenstate thermalization hypothesis and random matrix theory, can suppress the observable signatures of macroscopic coherence. Using the Greenberger-Horne-Zeilinger (GHZ) state as a representative example, we demonstrate that while fully correlated measurements can initially distinguish a macroscopic superposition from its corresponding classical mixture, generic many-body evolution renders them operationally indistinguishable for most times. By analyzing both distinguishability measures and established quantifiers of macroscopic quantumness, we find that equilibration not only hides coherence from accessible observables but also suppresses the corresponding signatures of macroscopic quantumness, in particular within the additive-local framework considered here. These results identify unitary thermalization, independent of environmental decoherence, as a fundamental mechanism that limits the observation of macroscopic quantum effects.
The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schrödinger equation, which preserves the von Neumann entropy. Nonetheless, one finds that with respect to many observables, expectation values approach a fixed value—their equilibrium value. This ultimately raises the question: ? For classical systems, one introduces the assumption of a low-entropy initial state along with the concept of ignorance about the microscopic details of the physical system, leading to a statistical interpretation of the second law. By considering the observables through which we examine quantum systems, both these assumptions can be incorporated, building upon recent studies of the of observables. While the statistical behavior of observable expectation values is well established, a quantitative connection to entropy increase has been lacking so far. In deriving novel bounds for the equilibration of observables, and considering the entropy of the system relative to observables, we recover a variant of the second law: the entropy with respect to a given observable tends toward its equilibrium value in the course of the system’s unitary evolution. These results also support recent findings that question the necessity of nonintegrability for equilibration in quantum systems. We further illustrate our bounds using numerical results from the paradigmatic example of a quantum Ising model on a chain of spins. There, we observe entropy increasing up to equilibrium values, as well as fluctuations, which expose the underlying reversible evolution in accordance with the derived bounds.
A single mechanism, endemic to the standard model of physics, is proposed to explain wavefunction collapse, classical motion, dissipation, equilibration, and the transition from pure quantum mechanics through open system decoherence to the natural regime. Spontaneous events in the neighborhood of a particle disrupts correlation such that large many-particle states do not persist and each particle collapses to a stable mode of motion established by its neighbors. These events are the source of thermal fluctuation and drive diffusion. Consequently, evolution is not deterministic, unitary or classically conservative; diffusion toward a steady state occurs incessantly in every system of particles, though slowed under unnatural experimental conditions that suppress these events. Mean properties of a system evolve as particles jump between single-particle modes, producing observed transport laws and equilibrium properties without additional postulate or empirical factors. These modes are localized in dense material, yielding classical characteristics. Boltzmann's equal probability postulate is valid only when comparing results of nonrelativistic observers.
We introduce energy-space quantum walks as a minimal framework to investigate equilibration, thermalization, and irreversibility from an effective-dynamics perspective. By mapping the configuration space of a walk onto a ladder of energy eigenlevels, we reinterpret thermalization as transport in energy space, independently of microscopic system--bath details. At the classical level, the resulting birth--death--lazy dynamics leads to equilibration of the energy distribution and, under suitable conditions, to a Gibbs stationary state. We then embed this dynamics into a unitary, collision-assisted model in which coherence is controlled by a single parameter. A central result is a structural decoupling between population dynamics and coherence generation: while the populations evolve according to the classical process and relax to the Gibbs distribution, the full quantum state exhibits a persistent coherence-induced deviation from the thermal manifold. This establishes a minimal scenario of thermalization without state convergence, where equilibration occurs at the level of populations but not at the level of the full density operator. We quantify this effect using the thermal distance to the Gibbs state and derive perturbative bounds that relate the long-time deviation to classical transport properties. Our results show that coherence acts as a controllable and quantitatively bounded source of nonthermal behavior, providing a clear separation between classical equilibration and genuinely quantum corrections.
Understanding how macroscopic systems exhibit irreversible thermal behavior has been a longstanding challenge, first brought to prominence by Boltzmann. Recent advances have established rigorous conditions for isolated quantum systems to equilibrate to a maximum entropy state, contingent upon weak assumptions. These theorems, while powerful, applied for a sudden quench. However, natural processes involve finite-time perturbations or quenches, which raises a crucial question: Can these systems still equilibrate under more realistic, finite-time dynamics? In this work, we extend the established results to account for finite-time quenches, demonstrating that, even under finite-time perturbations, the system will equilibrate provided it populates many significant energy levels. While the mathematical proof is more intricate than in the instantaneous case, the physical conclusion remains the same: sufficient perturbation leads to equilibration. Our results provide a broader and more physically realistic framework for understanding thermalization in isolated quantum systems.