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arXiv:2605.15339

Energy-space quantum walks: Thermalization without state convergence

Alana Spak dos Santos, Renato Moreira Angelo

quant-phSubmitted May 14, 2026• Announced May 18, 2026• 0 citations
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Abstract

We introduce energy-space quantum walks as a minimal framework to investigate equilibration, thermalization, and irreversibility from an effective-dynamics perspective. By mapping the configuration space of a walk onto a ladder of energy eigenlevels, we reinterpret thermalization as transport in energy space, independently of microscopic system--bath details. At the classical level, the resulting birth--death--lazy dynamics leads to equilibration of the energy distribution and, under suitable conditions, to a Gibbs stationary state. We then embed this dynamics into a unitary, collision-assisted model in which coherence is controlled by a single parameter. A central result is a structural decoupling between population dynamics and coherence generation: while the populations evolve according to the classical process and relax to the Gibbs distribution, the full quantum state exhibits a persistent coherence-induced deviation from the thermal manifold. This establishes a minimal scenario of thermalization without state convergence, where equilibration occurs at the level of populations but not at the level of the full density operator. We quantify this effect using the thermal distance to the Gibbs state and derive perturbative bounds that relate the long-time deviation to classical transport properties. Our results show that coherence acts as a controllable and quantitatively bounded source of nonthermal behavior, providing a clear separation between classical equilibration and genuinely quantum corrections.

Comments
13 pages, 4 figures

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We introduce energy-space quantum walks as a minimal framework to investigate equilibration, thermalization, and irreversibility from an effective-dynamics perspective. By mapping the configuration space of a walk onto a ladder of energy eigenlevels, we reinterpret thermalization as transport in energy space, independently of microscopic system--bath details. At the classical level, the resulting birth--death--lazy dynamics leads to equilibration of the energy distribution and, under suitable conditions, to a Gibbs stationary state. We then embed this dynamics into a unitary, collision-assisted model in which coherence is controlled by a single parameter. A central result is a structural decoupling between population dynamics and coherence generation: while the populations evolve according to the classical process and relax to the Gibbs distribution, the full quantum state exhibits a persistent coherence-induced deviation from the thermal manifold. This establishes a minimal scenario of thermalization without state convergence, where equilibration occurs at the level of populations but not at the level of the full density operator. We quantify this effect using the thermal distance to the Gibbs state and derive perturbative bounds that relate the long-time deviation to classical transport properties. Our results show that coherence acts as a controllable and quantitatively bounded source of nonthermal behavior, providing a clear separation between classical equilibration and genuinely quantum corrections.
We develop a perturbative technique for solving Markovian quantum dissipative dynamics, with the perturbation parameter being a small gap in the eigenspectrum. As an example, we apply the technique and straightforwardly obtain analytically the dynamics of a three-level system with quasidegenerate excited states, where quantum coherences persist for very long times, proportional to the inverse of the energy splitting squared. We then show how to bypass this long-lived coherent dynamics and accelerate the relaxation to thermal equilibration in a hyper-exponential manner, a Markovian quantum-assisted Mpemba-like effect. This hyperacceleration of the equilibration process manifests if the initial state is carefully prepared, such that its coherences precisely store the amount of population relaxing from the initial condition to the equilibrium state. Our analytical method for solving quantum dissipative dynamics readily provides equilibration timescales, and as such it reveals how coherent and incoherent effects interlace in the dynamics. It further advises on how to accelerate relaxation processes, which is desirable when long-lived quantum coherences stagnate dynamics.
The emergence of classical behavior and the origin of thermal equilibrium are two central problems in the foundations of physics. In the standard accounts, both phenomena are typically explained through interactions with an external environment: decoherence suppresses quantum interference, while coupling to a thermal bath drives relaxation toward equilibrium. Over the last decades, however, it has become clear that equilibration and thermalization can arise even in fully isolated quantum systems, in the operational sense that the expectation values of relevant observables remain close to equilibrium values for most of the time. Here, we ask whether the same intrinsic equilibration mechanism can also account for the emergence of classical behavior. Using rigorous bounds on equilibration in closed systems, we derive sufficient conditions under which a time-evolved pure state becomes, for most times, operationally indistinguishable from a classical mixture associated with a chosen physical property. We identify two complementary routes to such operational classicality: either the chosen property almost commutes with the system Hamiltonian or the observables used to probe the system lose access to the remaining coherence after equilibration. Our results show that classical behavior need not be confined to the energy basis and may emerge even when substantial coherence remains present in the equilibrium state. This establishes a direct connection between two foundational questions: the origin of thermalization in isolated quantum systems and the quantum-to-classical transition
Two-level systems (TLS) are widely recognized as a dominant source of energy relaxation in superconducting qubits, limiting coherence times and device performance. While TLS-induced dissipation is often modeled as independent channels, interacting TLS can form finite many-body environments whose dynamical role in qubit relaxation remains insufficiently understood. Building on the information-erasure-based framework for irreversible thermalization developed in our previous work, we present a microscopic model and numerical simulations of a superconducting qubit coupled to a finite interacting many-body TLS environment as a concrete physical realization of this mechanism. We show that effective irreversible energy relaxation can emerge from intrinsic many-body dynamics without invoking external baths or phenomenological dissipation. The introduction of information erasure drives a transition from coherent oscillatory energy exchange to nonoscillatory exponential relaxation of the qubit. The relaxation times exhibit the scaling T1,T2∝Jq,τ−2T_1, T_2 \propto J_{q,τ}^{-2}T1​,T2​∝Jq,τ−2​ with respect to the qubit-TLS coupling strength, consistent with Fermi's golden rule and Lindblad-type descriptions. Importantly, both exponential decay and its scaling behavior arise directly from microscopic many-body dynamics. These results provide quantitative insight into TLS-induced decoherence mechanisms and establish a microscopic link between information erasure, many-body thermalization, and irreversible relaxation in superconducting quantum systems.
Understanding how macroscopic systems exhibit irreversible thermal behavior has been a longstanding challenge, first brought to prominence by Boltzmann. Recent advances have established rigorous conditions for isolated quantum systems to equilibrate to a maximum entropy state, contingent upon weak assumptions. These theorems, while powerful, applied for a sudden quench. However, natural processes involve finite-time perturbations or quenches, which raises a crucial question: Can these systems still equilibrate under more realistic, finite-time dynamics? In this work, we extend the established results to account for finite-time quenches, demonstrating that, even under finite-time perturbations, the system will equilibrate provided it populates many significant energy levels. While the mathematical proof is more intricate than in the instantaneous case, the physical conclusion remains the same: sufficient perturbation leads to equilibration. Our results provide a broader and more physically realistic framework for understanding thermalization in isolated quantum systems.
We introduce a wide class of quantum maps that arise in collisional reservoirs and are able to thermalize a system if they operate in conjunction with an additional dephasing mechanism. These maps describe the effect of collisions and induce transitions between populations that obey detailed balance, but also create coherences that prevent the system from thermalizing. We combine these maps with a unitary evolution acting during random Poissonian times between collisions and causing dephasing. We find that, at a low collision rate, the nontrivial combination of these two effects causes thermalization in the system. This scenario is suitable for modeling collisional reservoirs at equilibrium. We justify this claim by identifying the conditions for such maps to arise within a scattering theory approach and provide a thorough characterization of the resulting thermalization process.
Quantum systems governed by unitary and reversible microscopic dynamics may nevertheless exhibit equilibration, in the sense that some effective description becomes time-independent. Standard equilibration results usually consider two separate situations: system-environment structures, in which the composite system evolves unitarily while the system of interest equilibrates, and restricted measurements, such as coarse-grained POVMs and observables, in which the measurement statistics equilibrate. Here, we bring these descriptions into a common state-level framework using the concept of generalized subsystems, where the accessible effective state appears as the output of a quantum channel acting on the microscopic state. We derive bounds showing that generalized subsystems equilibrate when their dimension is small compared with the effective dimension of the discarded microscopic information. We further show that this condition is met for typical initial states in large subspaces and that the resulting equilibrium description is largely insensitive to microscopic initial details. The framework recovers the usual equilibration bounds for ordinary subsystems and finite families of POVMs. As an example, we also introduce a finite-resolution energy channel that maps unresolved microscopic energy levels into effective energy levels, thereby making residual effective coherences explicit and showing how spectral multiplicities constrain those coherences while strengthening equilibration. Our results provide a unified state-level formulation of quantum equilibration under general forms of limited accessible information.