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arXiv:2606.03226

Perturbative results for fractional quantum mechanics

Claude Semay, Clara Tourbez, Loïc Keszeli

quant-phSubmitted Jun 2, 2026• Announced Jun 3, 2026
v1 · Jun 2, 2026v2 · Jun 8, 2026v3 · Sep 30, 2026
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Abstract

The fractional Schrödinger equation is studied with a kinetic energy that slightly deviates from the usual nonrelativistic form. The harmonic oscillator and the Kepler problem are both treated in the context of small perturbations. The usual perturbation theory is used and compared with the envelope theory. The analytical results show good agreement between both methods, indicating possible future developments for many-body systems. A possible connection with experimental observations is briefly discussed.

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The fractional Schrödinger equation is studied with a kinetic energy that slightly deviates from the usual nonrelativistic form. The harmonic oscillator and the Kepler problem are both treated in the context of small perturbations. The usual perturbation theory is used and compared with the envelope theory. The analytical results show good agreement between both methods, indicating possible future developments for many-body systems. A possible connection with experimental observations is briefly discussed.
The Klein Gordon equation for the harmonic oscillator may be written as (E-.5kx2)2=p2+mo2 ((1)) where mo is the rest mass and p the relativistic momentum. In the literature, it is argued that the resulting x4 term dominates for large x and prevents the Klein Gordon equation from being solved for bound states. As a result, it is replaced with an equation of the form: (E2-mo2) = (p-imwx)(p+imw) ((2)) where p=-ihbar d/dx in one dimension which may be solved exactly. Recently, the authors of (1) have used perturbation theory to calculate energy changes to ((1)) by using -.5V2 - e2 +2eV as a perturbative potential where V=.5kx2 and E=e+mo. They utilise the unperturbed wavefunction exp(-ax2) so large x4 values are damped. Their results are close to the exact calculations of ((2)) for the case of k=1 and m=1. In this note, we argue that for an oscillator there are classical turning points at which the quantum average kinetic energy -1/2m d/dx d/dx W should be zero and small nearby even if the average kinetic energy near x=0 corresponds to relativistic momenta. Thus, it is argued there are different spatial regions, each with its own quantum equation. The Schrodinger equation may be applied to regions near the classical turning point moving to infinite. In such a case, there is no issue with an x4 term. Near x=0, the full Klein Gordon equation ((1)) may be applied. There are questions of then matching the two sets of solutions. In this note, we attempt to investigate this scenario and compare results with those of (1) and (2). (1) and (2) suggest similar relativistic corrections to the nonrelativistic ground state oscillator energy of more than 20%. In this note, we suggest a smaller value.
The authors develop a simple alternative approach to perturbation theory in one-dimensional nonrelativistic quantum mechanics. The formulae for the energy shifts and wavefunctions do not involve cumbersome sums over intermediate states which appear in the usual Rayleigh-Schrodinger expansion. Unlike standard logarithmic perturbation theory, the approach does not utilize taking the logarithm of the wavefunction, and is therefore applicable in the same form to both the ground state and excited bound states.
The subject of perturbation theory in non-relativistic quantum mechanics is introduced. First, perturbation theory for stationary states in the absence of degeneracy is studied. The case of nearby levels, perturbations of a one-dimensional harmonic oscillator, the occurrence of degeneracy, Stark and Zeeman effects are then described in detail. After a brief outline of the variational method, the Dyson series for time-dependent perturbation theory is derived, with application to harmonic perturbations. The Fermi golden rule is also presented. The chapter ends with an assessment of four branches of the subject: regular perturbation theory, asymptotic perturbation theory, and summability methods, spectral concentration and singular perturbations. Approximate methods for stationary states It is frequently the case, in physical problems, that the full Hamiltonian operator H consists of an operator H 0 whose eigenvalues and eigenfunctions are known exactly, and a second term V resulting from a variety of sources (e.g. the interaction with an electric field, or a magnetic field, or the relativistic corrections to the kinetic energy, or the effects of spin). The problems and aims of perturbation theory for stationary states can be therefore summarized as follows. (i) Once the domain of (essential) self-adjointness of the ‘unperturbed’ Hamiltonian H 0 is determined, find on which domain the ‘sum’ H = H 0 + V represents an (essentially) self-adjoint operator (the reader should remember from appendix 4. A that in general, once some operators A and B are given, the intersection of their domains, on which their sum is defined, might be the empty set). […]
We discuss an alternative method of performing coupling constant perturbation expansions in nonrelativistic quantum mechanics. This method, called logarithmic perturbation theory, yields new expressions for any-order corrections En to an unperturbed bound-state energy which do not involve cumbersome sums over intermediate unperturbed states. In one dimension, these corrections En can be evaluated using a simple explicit form containing a small number of integrals. In more than one dimension the approach is systematic but computations require the solution of well-defined partial differential equations. For order n=2 this equation is identical to that appearing in the method of Dalgarno and Lewis. Numerous illustrative examples are presented.
This report discusses two new ideas for using perturbation methods to solve the time-independent Schrödinger equation. The first concept begins with rewriting the perturbation equations in a form that is closely related to matrix diagonalization methods. That allows a simple, compact derivation of the standard (Rayleigh-Schrödinger) equations. But it also leads to a new iterative solution method that is not based on the usual power series expansion. The iterative method can also be used when the unperturbed system is two-fold degenerate. The second concept is quite different from the first but compatible with it. It is based on the fact that one can replace the true Hamiltonian with a synthetic Hamiltonian having the same eigenvalues. This approach allows one to cancel part of the perturbation and to reduce the size of the off-diagonal matrix elements, giving better convergence of the series. These methods are illustrated by application to three perturbed harmonic oscillator problems--a 1-D oscillator with a linear perturbation, a 1-D oscillator with a quartic perturbation, and a perturbed 2-D oscillator, which involves degenerate states. The iterative method and the synthetic Hamiltonian method are shown to give significantly better results than the standard method.