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arXiv:2604.11872

Quantum Chaos and Eigenstate Thermalization

Rohit Patil, Marcos Rigol

quant-phcond-mat.stat-mechSubmitted Apr 13, 2026• Announced Apr 15, 2026• 0 citations• Revised Oct 6, 2026 (v4)
v1 · Apr 13, 2026v2 · Apr 27, 2026v3 · Jun 8, 2026v4 · Oct 6, 2026
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Abstract

We provide a pedagogical introduction to eigenstate thermalization. This phenomenon, which occurs in generic quantum many-body systems, allows one to understand why thermalization takes place in isolated systems under unitary dynamics. We motivate eigenstate thermalization using random matrix theory and discuss recent complementary results for the volume-law entanglement entropy of Haar-random states. We discuss numerical results that highlight the corresponding behaviors in quantum many-body systems.

Comments
24 pages, 9 figures; Chapter for the Quantum Chaos volume in 'Comprehensive Quantum Mechanics', to be published by Elsevier (Main editor: R.B. Mann; volume editors: S. Gnutzmann and K. Życzkowski)

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We provide a pedagogical introduction to eigenstate thermalization. This phenomenon, which occurs in generic quantum many-body systems, allows one to understand why thermalization takes place in isolated systems under unitary dynamics. We motivate eigenstate thermalization using random matrix theory and discuss recent complementary results for the volume-law entanglement entropy of Haar-random states. We discuss numerical results that highlight the corresponding behaviors in quantum many-body systems.
This review gives a pedagogical introduction to the eigenstate thermalization hypothesis (ETH), its basis, and its implications to statistical mechanics and thermodynamics. In the first part, ETH is introduced as a natural extension of ideas from quantum chaos and random matrix theory (RMT). To this end, we present a brief overview of classical and quantum chaos, as well as RMT and some of its most important predictions. The latter include the statistics of energy levels, eigenstate components, and matrix elements of observables. Building on these, we introduce the ETH and show that it allows one to describe thermalization in isolated chaotic systems without invoking the notion of an external bath. We examine numerical evidence of eigenstate thermalization from studies of many-body lattice systems. We also introduce the concept of a quench as a means of taking isolated systems out of equilibrium, and discuss results of numerical experiments on quantum quenches. The second part of the review explores the implications of quantum chaos and ETH to thermodynamics. Basic thermodynamic relations are derived, including the second law of thermodynamics, the fundamental thermodynamic relation, fluctuation theorems, the fluctuation–dissipation relation, and the Einstein and Onsager relations. In particular, it is shown that quantum chaos allows one to prove these relations for individual Hamiltonian eigenstates and thus extend them to arbitrary stationary statistical ensembles. In some cases, it is possible to extend their regimes of applicability beyond the standard thermal equilibrium domain. We then show how one can use these relations to obtain nontrivial universal energy distributions in continuously driven systems. At the end of the review, we briefly discuss the relaxation dynamics and description after relaxation of integrable quantum systems, for which ETH is violated. We present results from numerical experiments and analytical studies of quantum quenches at integrability. We introduce the concept of the generalized Gibbs ensemble and discuss its connection with ideas of prethermalization in weakly interacting systems.
The emergence of statistical mechanics for isolated classical systems comes about through chaotic dynamics and ergodicity. Here we review how similar questions can be answered in quantum systems. The crucial point is that individual energy eigenstates behave in many ways like a statistical ensemble. A more detailed statement of this is named the eigenstate thermalization hypothesis (ETH). The reasons for why it works in so many cases are rooted in the early work of Wigner on random matrix theory and our understanding of quantum chaos. The ETH has now been studied extensively by both analytic and numerical means, and applied to a number of physical situations ranging from black hole physics to condensed matter systems. It has recently become the focus of a number of experiments in highly isolated systems. Current theoretical work also focuses on where the ETH breaks down leading to new interesting phenomena. This review of the ETH takes a somewhat intuitive approach as to why it works and how this informs our understanding of many body quantum states.
We study the static and dynamical properties of isolated many-body quantum systems and compare them with the results for full random matrices. In doing so, we link concepts from quantum information theory with those from quantum chaos. In particular, we relate the von Neumann entanglement entropy with the Shannon information entropy and discuss their relevance for the analysis of the degree of complexity of the eigenstates, the behavior of the system at different time scales and the conditions for thermalization. A main advantage of full random matrices is that they enable the derivation of analytical expressions that agree extremely well with the numerics and provide bounds for realistic many-body quantum systems.
Eigenstate thermalization has been numerically shown to occur for few-body observables in a wide range of nonintegrable models. For intensive sums of few-body observables, a weaker version of eigenstate thermalization known as weak eigenstate thermalization has been proved to occur in general. Here, we unveil a stricter weak eigenstate thermalization phenomenon that occurs in quadratic models exhibiting quantum chaos in the single-particle sector (quantum-chaotic quadratic models) and in integrable interacting models. In such models, we argue that few-body observables that have a properly defined system-size independent norm are guaranteed to exhibit at least a polynomially vanishing variance (over the entire many-body energy spectrum) of the diagonal matrix elements, a phenomenon we dub normal weak eigenstate thermalization. We prove that normal weak eigenstate thermalization is a consequence of single-particle eigenstate thermalization, i.e., it can be viewed as a manifestation of quantum chaos at the single-particle level. We report numerical evidence of normal weak eigenstate thermalization for quantum-chaotic quadratic models such as the three-dimensional Anderson model in the delocalized regime and the power-law random banded matrix model, as well as for the integrable interacting spin-12\frac{1}{2}21​ XYZ and XXZ models.
These notes accompany lectures given in June 2025 at the summer school \emph{Fundamental Problems in Statistical Physics XVI}. They offer a short introduction to random quantum circuits as simple models for generic many-body quantum systems. They give an outline of the motivation for introducing these models, starting from ideas of random matrix theory. They also provide a sketch of calculations of some of the quantities of most physical interest, based on an average over an ensemble of systems. These quantities give insights into operator spreading, entanglement dynamics and spectral correlations.
A profound quest of statistical mechanics is the origin of irreversibility - the arrow of time. New stimulants have been provided, thanks to unprecedented degree of control reached in experiments with isolated quantum systems and rapid theoretical developments of manybody localization in disordered interacting systems. The proposal of (many-body) eigenstate thermalization (ET) for these systems reinforces the common belief that either interaction or extrinsic randomness is required for thermalization. Here, we unveil a quantum thermalization mechanism challenging this belief. We find that, provided one-body quantum chaos is present, as a pure many-body state evolves the arrow of time can emerge, even without interaction or randomness. In times much larger than the Ehrenfest time that signals the breakdown of quantum-classical correspondence, quantum chaotic motion leads to thermal [Fermi-Dirac (FD) or Bose-Einstein (BE)] distributions and thermodynamics in individual eigenstates. Our findings lay dynamical foundation of statistical mechanics and thermodynamics of isolated quantum systems.