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arXiv:2603.25829 · SciPost Physics Core

Quantum thermalization beyond non-integrability and quantum scars in a multispecies Bose-Josephson junction

Francesco Di Menna, Sergio Ciuchi, Simone Paganelli

Published Sep 24, 2026• 0 citations
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Abstract

The modern framework for quantum thermalization is grounded in the Eigenstate Thermalization Hypothesis (ETH), in which non-integrability and chaos are historically assumed as prerequisites. This work investigates this relationship in a three-species Bose-Josephson Junction (BJJ) with mutual interactions, experimentally achievable in current ultracold-atom platforms. After a thorough characterization of quantum chaos in this system, we examine the occurrence of thermal behavior expected when ETH holds. We identify three distinct regimes: chaotic, integrable, and separable. Remarkably, quantum thermalization occurs in both the chaotic and integrable regimes, while it breaks down in and near the separable limit — supporting that non-integrability is not a necessary condition for thermalization. Furthermore, since the system exhibits collective phenomena in the semiclassical limit, we identify ergodicity breaking phenomena such as athermal states in the chaotic regime classifiable as quantum scars, which show no signs of thermalization, consistently with a weak form of ETH.

DOI
10.21468/scipostphyscore.9.3.060

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The modern framework for quantum thermalization is grounded in the Eigenstate Thermalization Hypothesis (ETH), in which non-integrability and chaos are historically assumed as prerequisites. This work investigates this relationship in a three-species Bose-Josephson Junction (BJJ) with mutual interactions, experimentally achievable in current ultracold-atom platforms. After a thorough characterization of quantum chaos in this system, we examine the occurrence of thermal behavior expected when ETH holds. We identify three distinct regimes: chaotic, integrable, and separable. Remarkably, quantum thermalization occurs in both the chaotic and integrable regimes, while it breaks down in and near the separable limit — supporting that non-integrability is not a necessary condition for thermalization. Furthermore, since the system exhibits collective phenomena in the semiclassical limit, we identify ergodicity breaking phenomena such as athermal states in the chaotic regime classifiable as quantum scars, which show no signs of thermalization, consistently with a weak form of ETH.
We consider a Bose-Josephson junction (BJJ) formed by a binary mixture of ultracold atoms to investigate the manifestation of coherent collective dynamics on ergodicity and quantum scars, unfolding the connection between them. By tuning the inter- and intraspecies interaction, we demonstrate a rich variety of Josephson dynamics and transitions between them, which plays a crucial role in controlling the overall ergodic behavior. The signature of underlying classicality is revealed from the entanglement spectrum, which also elucidates the formation of quantum scars of unstable steady states and of periodic orbits leading to athermal behavior. The degree of ergodicity across the energy band and scarring phenomena can be probed from the autocorrelation function as well from the phase fluctuation of the condensates, which has relevance in cold atom experiments.
Quantum many-body scars consist of a few low-entropy eigenstates in an otherwise chaotic many-body spectrum, and can weakly break ergodicity resulting in robust oscillatory dynamics. The notion of quantum many-body scars follows the original single-particle scars introduced within the context of quantum billiards, where scarring manifests in the form of a quantum eigenstate concentrating around an underlying classical unstable periodic orbit. A direct connection between these notions remains an outstanding problem. Here, we study a many-body spinor condensate that, owing to its collective interactions, is amenable to the diagnostics of scars. We characterize the system's rich dynamics, spectrum, and phase space, consisting of both regular and chaotic states. The former are low in entropy, violate the eigenstate thermalization hypothesis, and can be traced back to integrable effective Hamiltonians, whereas most of the latter are scarred by the underlying semiclassical unstable periodic orbits, while satisfying the eigenstate thermalization hypothesis. We outline an experimental proposal to probe our theory in trapped spin-1 Bose-Einstein condensates.
We consider a model describing Bose-Josephson junction (BJJ) coupled to a single bosonic mode exhibiting a quantum phase transition (QPT). Onset of chaos close to QPT is observed from semiclassical dynamics of collective modes and from spectral statistics. A detailed analysis of entanglement entropy and multifractal nature of states reveals a non-ergodic to weakly ergodic crossover at a critical energy. We identify the imprint of collective π\piπ-oscillation as many body quantum scar (MBQS), which leads to the deviation from ergodicity. Persistence of phase coherence in non-equilibrium dynamics of such initial state corresponding to the π\piπ-mode is an observable signature of MBQS which can be relevant for experiments on BJJ.
Quantum chaos and the eigenstate thermalization hypothesis are based on the assumption of the validity of random matrix theory description on the spectrum and eigenstates. They provide the foundation and descriptions for the typical dynamics and thermalization in generic closed quantum systems. In this thesis, we investigate situations where the systems show atypical dynamics or anomalous thermalization, conflicting with the usual expectations from quantum chaos and eigenstate thermalization hypothesis. We first examine weak thermalization in a nonintegrable spin chain. The system shows long-lived strong oscillations and relaxes to the thermal equilibrium weakly. We identify the dynamics describable by quasiparticles and recognize the oscillation frequency to be the quasiparticle mass gap. We also estimate the damping time for the oscillations. Next, we study prethermalization, a phenomenon where a system relaxes to an intermediate almost-equilibrium stage before reaching the true thermal equilibrium. We study a nonintegrable spin chain in the strong coupling limit, where an almost-conserved quantity emerges and gives rise to the prethermalization. We also study a newly proposed diagnostic for quantum chaos: out-of-time-ordered correlators. Contrasting to the chaotic systems, we inspect their behaviors in various noninteracting integrable models. Finally, we dig into the quantum many-body scar states in the PXP model which describes a Rydberg atom chain. These special states do not satisfy the random matrix theory description nor the eigenstate thermalization hypothesis, therefore defying quantum chaos.
This work investigates the emergent thermalization regimes in a chaotic Tavis-Cummings (TC) model and their implications in quantum spectroscopy. While the TC model is a cornerstone of cavity quantum electrodynamics, traditional treatments often overlook many-body effects that arise in the thermodynamic limit. We utilize the Eigenstate Thermalization Hypothesis to demonstrate that a non-integrable excitonic Hamiltonian within the material manifold drives local thermalization. By tuning the polariton splitting ggg, we observe two dynamical regimes: a thermalizing regime at low interactions driven by quantum chaos and ergodicity, and a non-thermalizing regime at high interactions where strong coupling suppresses ergodicity. We further show that these regimes have direct implications on output photon statistics, specifically influencing the correlation times τcτ_cτc​ of the cavity population and the second-order correlation function g(2)(t+τ)g^{(2)}(t+τ)g(2)(t+τ). We propose that entangled-biphoton spectroscopy serves as an ideal experimental platform to probe these effects and to allow the characterization of the underlying many-body exciton-coupling disorder σσσ through coincidence measurements of the output. Taken together, these results exploit a naturally occurring many-body phenomenon to bridge theoretical predictions with experimental observables.
We consider a model describing Bose-Josephson junction (BJJ) coupled to a single bosonic mode exhibiting quantum phase transition (QPT). Onset of chaos above QPT is observed from semiclassical dynamics as well from spectral statistics. Based on entanglement entropy, we analyze the ergodic behavior of eigenstates with increasing energy density which also reveals the influence of dynamical steady state known as π-mode on it. We identify the imprint of unstable π-oscillation as many body quantum scar (MBQS), which leads to the deviation from ergodicity and quantify the degree of scarring. Persistence of phase coherence in nonequilibrium dynamics of such initial state corresponding to the π-mode is an observable signature of MBQS which has relevance in experiments on BJJ.