Quantum chaos and the eigenstate thermalization hypothesis are based on the assumption of the validity of random matrix theory description on the spectrum and eigenstates. They provide the foundation and descriptions for the typical dynamics and thermalization in generic closed quantum systems. In this thesis, we investigate situations where the systems show atypical dynamics or anomalous thermalization, conflicting with the usual expectations from quantum chaos and eigenstate thermalization hypothesis. We first examine weak thermalization in a nonintegrable spin chain. The system shows long-lived strong oscillations and relaxes to the thermal equilibrium weakly. We identify the dynamics describable by quasiparticles and recognize the oscillation frequency to be the quasiparticle mass gap. We also estimate the damping time for the oscillations. Next, we study prethermalization, a phenomenon where a system relaxes to an intermediate almost-equilibrium stage before reaching the true thermal equilibrium. We study a nonintegrable spin chain in the strong coupling limit, where an almost-conserved quantity emerges and gives rise to the prethermalization. We also study a newly proposed diagnostic for quantum chaos: out-of-time-ordered correlators. Contrasting to the chaotic systems, we inspect their behaviors in various noninteracting integrable models. Finally, we dig into the quantum many-body scar states in the PXP model which describes a Rydberg atom chain. These special states do not satisfy the random matrix theory description nor the eigenstate thermalization hypothesis, therefore defying quantum chaos.
Quantum chaos and the eigenstate thermalization hypothesis are based on the assumption of the validity of random matrix theory description on the spectrum and eigenstates. They provide the foundation and descriptions for the typical dynamics and thermalization in generic closed quantum systems. In this thesis, we investigate situations where the systems show atypical dynamics or anomalous thermalization, conflicting with the usual expectations from quantum chaos and eigenstate thermalization hypothesis. We first examine weak thermalization in a nonintegrable spin chain. The system shows long-lived strong oscillations and relaxes to the thermal equilibrium weakly. We identify the dynamics describable by quasiparticles and recognize the oscillation frequency to be the quasiparticle mass gap. We also estimate the damping time for the oscillations. Next, we study prethermalization, a phenomenon where a system relaxes to an intermediate almost-equilibrium stage before reaching the true thermal equilibrium. We study a nonintegrable spin chain in the strong coupling limit, where an almost-conserved quantity emerges and gives rise to the prethermalization. We also study a newly proposed diagnostic for quantum chaos: out-of-time-ordered correlators. Contrasting to the chaotic systems, we inspect their behaviors in various noninteracting integrable models. Finally, we dig into the quantum many-body scar states in the PXP model which describes a Rydberg atom chain. These special states do not satisfy the random matrix theory description nor the eigenstate thermalization hypothesis, therefore defying quantum chaos.
This thesis investigates the anomalous dynamics observed in a Rydberg atom experiment in the broadest sense: a strongly interacting spin chain, without integrability or disorder, exhibits coherent many-body revivals ensuing only from specific initial states. This non-thermal behavior is attributed to the presence of quantum many-body scars (QMBS), a novel class of ergodicity breaking phenomena. Unlike other non-thermalizing systems such as integrable models and many-body localization, the mechanism of ergodicity breaking in QMBS is quite subtle, relying on a (vanishingly) small subset of anomalous eigenstates, known as scar states: one could observe ergodicity breaking only if initial states have appreciable overlap with these scar states. In other words, systems hosting QMBS are indistinguishable from typical chaotic, thermalizing systems, except for scar states. While the theoretical understanding of QMBS has advanced through the investigation of various toy quantum models, ranging from the Affleck-Kennedy-Lieb-Tasaki (AKLT) model to the Hubbard model, these insights do not fully resolve the mysterious oscillations in the Rydberg experiment: crucially the wavefunction corresponding to the experiment, and its relation to many other toy models in the literature remain open questions. Furthermore, beyond mathematical curiocity, the observability of non-thermal dynamics suggests that QMBS may yield distinct physical effects. the nature of which remains to be determined. This dissertation addresses these issues by solving two concrete problems: (i) the mathematical characterization of scar states in the PXP model, the effective model for the experiment, and (ii) the identification of physical consequences of QMBS in both short- and long-time dynamics. In the first part, we clarify the algebraic structure underlying the scar states of the PXP model and derive analytic ansatz for these wavefunctions. The proposed forms make explicit the hidden algebraic structure of the PXP scars and demonstrate how this structure is shared with many other QMBS Hamiltonians, including the AKLT model. The second part investigates dynamical signatures and robustness. Given the fragility of many-body eigenstates to perturbations, identifying which scar characteristics survive realistic perturbations is crucial. In closed systems, we show that out-of-time-ordered correlators (OTOCs) and the associated Lyapunov exponent can distinguish QMBS from generic chaotic states, at least within a semiclassical regime. Specifically, the OTOC growth associated with scar states is parametrically slower and remains slow under small ``scar-breaking'' perturbations. For open systems governed by non-Hermitian dynamics, we introduce a novel non-equilibrium phase, the QMBS phase, where the long-time wavefunction is localized in a small corner of the Hilbert space. We further identify a first-order transition between the QMBS phase and a thermal phase, where the wavefunction becomes delocalized.
In classical systems, chaos is clearly defined via the behavior of trajectories. In quantum systems with a classical analogue one finds that the transition from regular to chaotic dynamics is signified by a change in the spectral statistics. This has been found to remain true for quantum systems with no classical analogue, including many-body systems. Furthermore, quantum chaotic systems explore all the allowed configurations in the Hilbert space, i.e. they are ergodic, while integrable systems, and systems in the many-body localized phase, are restricted to a certain subspace of the available phase space, and hence strongly break ergodicity. In this dissertation, we study the intermediate behavior between ergodicity and localization, i.e. the weak breaking of ergodicity. The model examined is the PXP spin chain model, where spins are allowed to flip only under certain kinetic constraints. We start by reproducing some already established results. First, we explore the eigenstate thermalization hypothesis (ETH) for this model and demonstrate the existence of a small number of states, throughout the PXP spectrum, that violate the ETH. Then we study the level-spacing statistics of the model, a well-known quantum chaos diagnostic, which turns out to be close to semi-Poisson and approach Wigner--Dyson statistics for large system sizes. Moreover, we examine various aspects of the model that have not been studied before. For example, the eigenvector component statistics, another quantum chaos diagnostic, for the PXP model turn out to be non-Gaussian. Finally, we perform a quench, in order to study how the energy spreads throughout the system, and observe ballistic fronts.
Quantum many-body scars are special eigenstates that violate the eigenstate thermalization hypothesis while residing at finite energy density along with thermalizing eigenstates. The spin-1 XY model is known to host a family of such exceptional states originating from long-lived quasiparticle excitations that exhibit anomalously low entanglement entropy and long-time periodic revivals, resulting in weak ergodicity breaking. We study the stability of these scarred states against typical U(1) symmetry preserving perturbation in the XY chain. While perturbation theory can describe the deformed scar states at small system sizes, finite-size scaling of the perturbation matrix elements indicate that the scars ultimately thermalize in larger chains. Nonetheless, we demonstrate that the long-range order associated with the scars decays under the perturbation, and we estimate the relaxation timescale of oscillatory dynamics in certain local observables to be of order λ−2, where λ is the perturbation strength.
A recent experiment in the Rydberg atom chain observed unusual oscillatory quench dynamics with a charge density wave initial state, and theoretical works identified a set of many-body "scar states" showing nonthermal behavior in the Hamiltonian as potentially responsible for the atypical dynamics. In the same nonintegrable Hamiltonian, we discover several eigenstates at an infinite temperature that can be represented exactly as matrix product states with a finite bond dimension, for both periodic boundary conditions (two exact E=0 states) and open boundary conditions (two E=0 states and one each E=±sqrt[2]). This discovery explicitly demonstrates the violation of the strong eigenstate thermalization hypothesis in this model and uncovers exact quantum many-body scar states. These states show signatures of translational symmetry breaking with a period-2 bond-centered pattern, despite being in one dimension at an infinite temperature. We show that the nearby many-body scar states can be well approximated as "quasiparticle excitations" on top of our exact E=0 scar states and propose a quasiparticle explanation of the strong oscillations observed in experiments.
The eigenstate thermalization hypothesis (ETH) provides a fundamental mechanism for emergent statistical mechanics in isolated chaotic quantum systems, asserting that individual energy eigenstates behave as pseudorandom vectors within an energy window. This enables a complete characterization of nontrivial correlations among matrix elements in the energy eigenbasis, as described by the full ETH ansatz. Nevertheless, this description breaks down in systems exhibiting quantum many-body scars, which host non-thermal eigenstates with extensive energy. In this Letter, we address this problem by formulating the \textit{scar full ETH}, which captures correlations among matrix elements involving scar states. The corresponding scaling forms and factorization properties are established using typicality arguments. Multi-time correlation functions for scar states are then organized in terms of both thermal and scar cumulants, providing a nontrivial reorganization of higher-order correlations. We numerically demonstrate the validity of this framework in the paradigmatic model of quantum scars, the PXP model. Our results pave the way for a systematic understanding of intriguing correlations in systems with quantum many-body scars.
The success of statistical mechanics in describing complex quantum systems rests upon typicality properties such as ergodicity. Both integrable systems and the recently discovered many-body localisation show that these assumptions can be strongly violated in either finely tuned cases, or in the presence of quenched disorder. In this thesis, we uncover a qualitatively different form of ergodicity breaking, wherein a small number of atypical eigenstates are embedded throughout an otherwise thermalising spectrum. We call this a many-body quantum scar, in analogy to quantum scars in single-particle quantum chaos, where quantum scarred eigenfunctions concentrate around associated periodic classical trajectories. \nWe demonstrate that many-body quantum scars can be found in an unusual model recently realised in a 51 Rydberg atom quantum simulator. The observed coherent oscillations following in a certain quench experiment are a consequence of the quantum scar. At the same time, the level statistics rules out conventional explanations such as integrability and many-body localisation. We develop an approximate method to construct scarred eigenstates, in order to describe their structure and physical properties. Additionally, we find a local perturbation which makes these non-equilibrium properties much more pronounced, with near perfect quantum revivals. At the same time the other eigenstates remain thermal. Our results suggest that many-body quantum scars forms a new class of quantum dynamics with unusual properties, which are realisable in current experiments.