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arXiv:2603.25512

Nonperturbative Resummation of Divergent Time-Local Generators: Disentangling Non-Markovian Dynamics

Dragomir Davidovic

quant-phhep-thmath-phSubmitted Mar 26, 2026• Announced Mar 27, 2026• 0 citations• Revised Sep 27, 2026 (v3)

v1 · Mar 26, 2026 v2 · Jun 30, 2026 v3 · Sep 27, 2026

Abstract

Perturbative van Kampen cumulant expansions of time-local generators of open quantum systems generically diverge at long times, but the reduced dynamics is regular. We show that the divergent cumulants nevertheless contain information sufficient to reconstruct the nonperturbative dynamical map. The map reveals that the divergence does not signal a breakdown of the reduced dynamics, but the approach to isolated times at which it becomes noninvertible. Singular time-local generators thus arise naturally from microscopic open-system Hamiltonians, without requiring special Lindblad-type constructions. For the weak-coupling spin--boson model, the reconstructed non-Markovian dynamics takes the explicit disentangled form \begin{equation*} Φ=Φ_{\mathrm{GAD}}+Φ_{\mathrm{NS}}+Φ_{\mathrm{Khal}}, \end{equation*} separating generalized amplitude damping, exponentially damped nonsecular coherence mixing, and a projective, phase-selective Khalfin map. The onset of recurrent noninvertibility is the reduced-dynamical-map manifestation of the Khalfin transition from exponential to algebraic relaxation. Although the coherences acquire algebraic Khalfin tails, the distinguishability of quantum superposition states remains governed by an exponential decay law after the Khalfin transition. Comparison with numerically exact TEMPO dynamics validates the disentanglement and shows that apparently complex non-Markovian dynamics can resolve into a small number of physically transparent and distinct dynamical processes.

Comments: 28 pages 7 figures

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Perturbative van Kampen cumulant expansions of time-local generators of open quantum systems generically diverge at long times, but the reduced dynamics is regular. We show that the divergent cumulants nevertheless contain information sufficient to reconstruct the nonperturbative dynamical map. The map reveals that the divergence does not signal a breakdown of the reduced dynamics, but the approach to isolated times at which it becomes noninvertible. Singular time-local generators thus arise naturally from microscopic open-system Hamiltonians, without requiring special Lindblad-type constructions. For the weak-coupling spin--boson model, the reconstructed non-Markovian dynamics takes the explicit disentangled form \begin{equation*} Φ=Φ_{\mathrm{GAD}}+Φ_{\mathrm{NS}}+Φ_{\mathrm{Khal}}, \end{equation*} separating generalized amplitude damping, exponentially damped nonsecular coherence mixing, and a projective, phase-selective Khalfin map. The onset of recurrent noninvertibility is the reduced-dynamical-map manifestation of the Khalfin transition from exponential to algebraic relaxation. Although the coherences acquire algebraic Khalfin tails, the distinguishability of quantum superposition states remains governed by an exponential decay law after the Khalfin transition. Comparison with numerically exact TEMPO dynamics validates the disentanglement and shows that apparently complex non-Markovian dynamics can resolve into a small number of physically transparent and distinct dynamical processes.

Master equations describing open quantum dynamics are typically first-order differential equations. When such dynamics brings the trajectories in state space of more than one initial state to the same point at finite instants in time, the generator of the corresponding master equation becomes singular while the dynamical map becomes noninvertible. The first-order, time-local, homogeneous master equations then fail to describe the dynamics beyond the singular point. Retaining time locality in the master equation necessitates a reformulation in terms of higher-order differential equations. We formulate a method to eliminate the divergent behavior of the generator by using a combination of higher-order derivatives of the generator with suitable weights and illustrate it with several examples. We also present a detailed study of the central spin model and we propose the average rate of information inflow in non-Markovian processes as a quantity that captures a different aspect of non-Markovian dynamics.

Perturbative master equations are essential for modeling open quantum systems but often exhibit late-time divergences when environmental correlations decay algebraically. In this work, we analyze the time-convolutionless (TCL) master equation expanded to order

{\mathrm{TCL}}_{2n}

and demonstrate that, while van Kampen's cumulants suppress early-time secular growth, they ultimately diverge at long times. To overcome this, we introduce a resummation technique based on the Hadamard trick, which incorporates time integrals directly into the bath's spectral density via elementwise multiplication. This approach establishes a maximum expansion order, ${n}_{\text{max}}=\ensuremath{\lceil}s+1\ensuremath{\rceil}$, and defines a precision limit of the asymptotic states of $O({\ensuremath{\lambda}}^{2\ensuremath{\lceil}s\ensuremath{\rceil}})$, where

s

is the power-law exponent and $\ensuremath{\lambda}$ is the weak-coupling constant. The resummed master equation features renormalized Bohr frequencies that capture decoherence and spectral overlap effects. In the unbiased spin-boson model, this results in an inflation of the generator at a temperature-independent rate equal to the decoherence rate ${\ensuremath{\nu}}_{2}$ and a finite validity time ${t}_{L}\ensuremath{\approx}(s+1)/{\ensuremath{\nu}}_{2}$. For exponentially decaying correlations, the method recovers a proper Markovian limit below a critical coupling threshold.

The time-convolutionless master equation provides a general framework to model the non-Markovian dynamics of an open quantum system with a time-local generator. A diagrammatic representation is developed and proven for the perturbative expansion of the exact time-local generator for an open quantum system interacting with arbitrary environments. A truncation of the perturbation expansion leads to perturbative time-convolutionless quantum master equations. We further introduce a general iterative approach to construct nonperturbative approximations for the time-local generator as nested time-ordered exponential operators.

We introduce a systematic framework to derive the effective Hamiltonian governing the coherent dynamics of non-Markovian open quantum systems. By applying the minimal dissipation principle, we uniquely isolate the coherent contribution to the time-local generator of the reduced dynamics. We derive a general expression for the effective Hamiltonian and develop a recursive perturbative expansion that expresses it in terms of system-bath interaction terms and bath correlation functions. This expansion provides a systematic tool for analyzing energy renormalization effects across different coupling regimes. Applying our framework to paradigmatic spin systems, we reveal how environmental correlations influence energy shifts and eigenbasis rotations, offering insights into strong-coupling effects and non-Markovian quantum thermodynamics.

The time-convolutionless master equation provides a general framework to model non-Markovian dynamics of an open quantum system with a time-local generator. A diagrammatic representation is developed and proven for the perturbative expansion of the exact time-local generator for an open quantum system interacting with arbitrary environments. A truncation of the perturbation expansion leads to the perturbative time-convolutionless quantum master equations. We further introduce a nonperturbative approach that approximates the time-convolutionless generator as a nested time-ordered exponential function.

Embedding non-Markovian open quantum dynamics into an enlarged Markovian space offers a powerful route to nonperturbative simulations, where the dynamics of the extended space can be governed by multiple distinct Markovian equations. We show that these distinct embeddings arise from different unravelings of Gaussian bath self-energies, generating a family of deterministic, time-local equations for the extended system. Using the Brownian-oscillator spectral density as an illustrative example, we clarify the relationships among existing approaches, including the Hierarchical Equations of Motion (HEOM) and the Lindblad--pseudomode formalism, and demonstrate how this framework enables numerically stable and efficient simulations. This work provides both a transparent theoretical foundation for embedding techniques and a flexible platform for developing new methods to simulate non-Markovian quantum dynamics.