Master equations describing open quantum dynamics are typically first-order differential equations. When such dynamics brings the trajectories in state space of more than one initial state to the same point at finite instants in time, the generator of the corresponding master equation becomes singular while the dynamical map becomes noninvertible. The first-order, time-local, homogeneous master equations then fail to describe the dynamics beyond the singular point. Retaining time locality in the master equation necessitates a reformulation in terms of higher-order differential equations. We formulate a method to eliminate the divergent behavior of the generator by using a combination of higher-order derivatives of the generator with suitable weights and illustrate it with several examples. We also present a detailed study of the central spin model and we propose the average rate of information inflow in non-Markovian processes as a quantity that captures a different aspect of non-Markovian dynamics.
Master equations describing open quantum dynamics are typically first-order differential equations. When such dynamics brings the trajectories in state space of more than one initial state to the same point at finite instants in time, the generator of the corresponding master equation becomes singular while the dynamical map becomes noninvertible. The first-order, time-local, homogeneous master equations then fail to describe the dynamics beyond the singular point. Retaining time locality in the master equation necessitates a reformulation in terms of higher-order differential equations. We formulate a method to eliminate the divergent behavior of the generator by using a combination of higher-order derivatives of the generator with suitable weights and illustrate it with several examples. We also present a detailed study of the central spin model and we propose the average rate of information inflow in non-Markovian processes as a quantity that captures a different aspect of non-Markovian dynamics.
The precise characterization of dynamics in open quantum systems often presents significant challenges, leading to the introduction of various approximations to simplify a model. One commonly used strategy involves Markovian approximations, assuming a memoryless environment. In this study, such approximations are not used and an analytical dynamical depiction of an open quantum system is provided. The system under consideration is an oscillator that is surrounded by a bath of oscillators. The resulting dynamics are characterized by a second-order complex coefficient linear differential equation, which may be either homogeneous or inhomogeneous. Moreover, distinct dynamical regions emerge, depending on certain parameter values. Notably, the steady-state average excitation number (AEN) of the system shows rapid escalation with increasing non-Markovianity, reflecting the intricacies of real-world dynamics. In cases where there is detuning between the system frequency and the environmental central frequency within a non-Markovian regime, the AEN maintains its initial value for an extended period. Furthermore, the application of pulse control can effectively protect the quantum system from decoherence effects without using approximations. The pulse control can not only prolong the relaxation time of the oscillator, but can also be used to speed up the relaxation process, depending on the specifications of the pulse. By employing a kick pulse, the Mpemba effect can be observed in the non-Markovian regime in a surprisingly super-cooling-like effect.
We propose a novel formulation of master equations for open systems wherein the evolution of a state is determined solely by its local behaviour at any point of time. Specifically, our formulation allows for a local interpretation of the workings of beyond-Markovian dynamics as opposed to the more common conception that non-Markovian state evolution is affected by its cumulative past history. Quite interestingly, local determinacy is found prevalent in quantum dynamics. We illustrate the advantages of our coordinate-free formulation with exact analyses on two physically relevant models.
The theory of open quantum systems represents one of the major developments of quantum mechanics over the last 50 years. Its central object of study is constituted by quantum systems that cannot be regarded as fully isolated, but instead interact with additional degrees of freedom, giving rise to irreversible phenomena such as dissipation and decoherence. The tools provided by this framework are nowadays of paramount importance across many active areas of research, including quantum computation, thermodynamics, metrology and biology. In this thesis, we investigate three main topics within the field. The first contribution concerns the microscopic derivation of the evolution equations, socalled quantum master equations, for open systems which are also subject to external driving fields. Standard techniques developed for time-independent Hamiltonians encounter several difficulties in the time-dependent case, largely restricting their applicability to specific instances, such as periodic or adiabatic drivings. In contrast, a core result of the derivation presented in the thesis is that, when the environment is sufficiently Markovian (essentially, memoryless), the non-adiabatic contributions to the driving field can be neglected in a controlled fashion, yielding an accurate master equation with time-dependent generator, capable of correctly reproducing the open dynamics even for strong drivings. This result is further supported by benchmarks against numerically exact simulations. The second contribution addresses the long-time behavior of general types of (Markovian) quantum master equations, including those of the form introduced above. While this problem has been extensively analyzed in the time-independent setting, virtually no results are known for time-dependent generators. In particular, we establish the foundations of a general theory of relaxation, that is, convergence towards an asymptotic trajectory in the long-time limit, independently of the initial state. The main results include a theorem guaranteeing sufficient conditions for relaxation and the derivation of a rate function governing the convergence to the asymptotic trajectory. The analysis is further extended to a simple non-Markovian case. Moreover, we treat in detail the specific master equation derived in the first part, connecting the aforementioned relaxation property directly to the underlying microscopic dynamics. The third contribution investigates chirality-induced spin selectivity (CISS) effects from the perspective of open quantum systems. Although the majority of theoretical studies aiming to model CISS are based on a coherent description of the spin dynamics, such effects have been observed also for electrons subject to incoherent transport across molecular networks. In this regard, we provide a rigorous ab initio derivation of the microscopic Hamiltonian describing the electronic transport, incorporating electron spin effects and contributions stemming from the nuclear vibrations. Within this result, we critically revise a master equation approach aiming to explain the origin of CISS effects observed in photosynthetic complexes. Taken together, these contributions offer fresh insights and original results on the interplay between driving fields and dissipation, relaxation phenomena, and electronic spin transport in the presence of incoherent dynamics. More broadly, these results provide new theoretical tools with several potential applications in quantum technologies, from modeling of control pulses in noisy environments to quantum reservoir engineering, and contribute to a deeper understanding of the role of quantum effects in biological systems.
Perturbative van Kampen cumulant expansions of time-local generators of open quantum systems generically diverge at long times, but the reduced dynamics is regular. We show that the divergent cumulants nevertheless contain information sufficient to reconstruct the nonperturbative dynamical map. The map reveals that the divergence does not signal a breakdown of the reduced dynamics, but the approach to isolated times at which it becomes noninvertible. Singular time-local generators thus arise naturally from microscopic open-system Hamiltonians, without requiring special Lindblad-type constructions. For the weak-coupling spin--boson model, the reconstructed non-Markovian dynamics takes the explicit disentangled form \begin{equation*} Φ=Φ_{\mathrm{GAD}}+Φ_{\mathrm{NS}}+Φ_{\mathrm{Khal}}, \end{equation*} separating generalized amplitude damping, exponentially damped nonsecular coherence mixing, and a projective, phase-selective Khalfin map. The onset of recurrent noninvertibility is the reduced-dynamical-map manifestation of the Khalfin transition from exponential to algebraic relaxation. Although the coherences acquire algebraic Khalfin tails, the distinguishability of quantum superposition states remains governed by an exponential decay law after the Khalfin transition. Comparison with numerically exact TEMPO dynamics validates the disentanglement and shows that apparently complex non-Markovian dynamics can resolve into a small number of physically transparent and distinct dynamical processes.
It is well known that the state operator of an open quantum system can be generically represented as the solution of a time-local equation — a quantum master equation. Unraveling in quantum trajectories offers a picture of open system dynamics dual to solving master equations. In the unraveling picture, physical indicators are computed as Monte Carlo averages over a stochastic process valued in the Hilbert space of the system. This approach is particularly adapted to simulate systems in large Hilbert spaces. We show that the dynamics of an open quantum system generically admits an unraveling in the Hilbert space of the system described by a Markov process generated by ordinary stochastic differential equations for which rigorous concentration estimates are available. The unraveling can be equivalently formulated in terms of norm-preserving state vectors or in terms of linear “ostensible” processes trace preserving only on average. We illustrate the results in the case of a two level system in a simple boson environment. Next, we derive the state-of-the-art form of the Diósi-Gisin-Strunz Gaussian random ostensible state equation in the context of a model problem. This equation provides an exact unraveling of open systems in Gaussian environments. We compare and contrast the two unravelings and their potential for applications to quantum error mitigation.
Abstract We investigate the dynamics of open quantum systems which are initially correlated with their environment. The strategy of our approach is to analyze how given, fixed initial correlations modify the evolution of the open system with respect to the corresponding uncorrelated dynamical behavior with the same fixed initial environmental state, described by a completely positive dynamical map. We show that, for any predetermined initial correlations, one can introduce a linear dynamical map on the space of operators of the open system which acts like the proper dynamical map on the set of physical states and represents its unique linear extension. Furthermore, we demonstrate that this construction leads to a linear, time-local quantum master equation with generalized Lindblad structure involving time-dependent, possibly negative transition rates. Thus, the general non-Markovian dynamics of an open quantum system can be described by means of a time-local master equation even in the case of arbitrary, fixed initial system–environment correlations. We present some illustrative examples and explain the relation of our approach to several other approaches proposed in the literature.