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arXiv:2603.22470

Multivariable Painleve'-II equation: connection formulas for asymptotic solutions

N. A. Sinitsyn

math-phgr-qcnlin.SIquant-phSubmitted Mar 23, 2026• Announced Mar 25, 2026• Revised Sep 28, 2026 (v5)
v1 · Mar 23, 2026v2 · Mar 27, 2026v3 · Jun 30, 2026v4 · Aug 24, 2026v5 · Sep 28, 2026
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Abstract

For an integrable generalization of the Painleve'-II equation (P-II) to a system of coupled equations with symmetry breaking terms, an asymptotically exact WKB analysis is applied to obtain connection formulas for solutions at different infinities. The analysis relies on an exact solution of the quantum mechanical Demkov--Osherov model (DOM), revealing a possible deeper relation between classical integrable systems and solvable multistate Landau--Zener models. An application of the connection formulas to the problem of unstable vacuum decay during a second-order phase transition provides precise scaling of the number of excitations, including subdominant contributions.

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9 pages, 4 figures

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For an integrable generalization of the Painleve'-II equation (P-II) to a system of coupled equations with symmetry breaking terms, an asymptotically exact WKB analysis is applied to obtain connection formulas for solutions at different infinities. The analysis relies on an exact solution of the quantum mechanical Demkov--Osherov model (DOM), revealing a possible deeper relation between classical integrable systems and solvable multistate Landau--Zener models. An application of the connection formulas to the problem of unstable vacuum decay during a second-order phase transition provides precise scaling of the number of excitations, including subdominant contributions.
Abstract The concept of quantum integrability has been introduced recently for quantum systems with explicitly time-dependent Hamiltonians (Sinitsyn et al 2018 Phys. Rev. Lett . 120 190402). Within the multistate Landau–Zener (MLZ) theory, however, there has been a successful alternative approach to identify and solve complex time-dependent models (Sinitsyn and Chernyak 2017 J. Phys. A: Math. Theor . 50 255203). Here we compare both methods by applying them to a new class of exactly solvable MLZ models. This class contains systems with an arbitrary number of interacting states and shows quick growth with N number of exact adiabatic energy crossing points, which appear at different moments of time. At each N , transition probabilities in these systems can be found analytically and exactly but complexity and variety of solutions in this class also grow with N quickly. We illustrate how common features of solvable MLZ systems appear from quantum integrability and develop an approach to further classification of solvable MLZ problems.
The WKB analysis for higher order differential equations had not been developed until recent progress of the so-called exact WKB method, so it was difficult to find WKB solutions for multistate nonadiabatic models in general, whereas enormous efforts were made especially for the study of generalized Landau-Zener models. Under such circumstances Aoki-Kawai-Takei provided a closed expression for the SSS matrix of a time-dependent multistate nonadiabatic system, in which diabatic potential curves are given as polynomial functions of time and they all intersect with each other. Their result is completely explicit, and the model covers much wider classes of systems than multistate nonadiabatic models studied so far. Here we numerically show how their exact WKB formula works as long as crossing points of diabatic potential curves are well separated. The model studied includes the cases where diabatic potential functions are nonlinear, not like generalized Landau-Zener models. We also discuss the situations where virtual turning points and new Stokes curves, new components in the Stokes geometry appearing only for higher order differential equations, come into play. In particular, we examine how the presence of new Stokes curves affects final transition probabilities using a couple of concrete examples.
The control of nonadiabatic quantum transitions is a requirement for the development of modern quantum technologies. The paradigm to understand these dynamics is the Landau-Zener model. However, for nearly a century, the exact transition probability of this model has been derived using special functions or semiclassical approximations. These conventional methods obscure the underlying physical mechanisms and transition dynamics near the avoided crossing. This cumulative thesis, resulting from the author's research activities at the Intitute of Quantum Physics at Ulm University under the supervision of Prof. Dr. Wolfgang P. Schleich, establishes an analytical framework to study the underlying structure of two-level crossing dynamics. In contrast to the standard techniques, the framework developed in this thesis is based on elementary concepts combined with complex analysis. First, we map the Landau-Zener equations onto an integro-differential equation to decouple them and formulate the Markov approximation which reduces the complicated integrals to the evaluation of Fresnel integrals. This technique reproduces in the asymptotic limit the exact probability amplitude of the Landau-Zener model. Next, to uncover the origin behind the success of the Markov approximation, we analyze the Landau-Zener equations in terms of their underlying nonlinear dynamics. First, we introduce an amplitude-and-phase approach, which explains in a clear way the emergence of the Stueckelberg oscillations through the dynamics of the phase velocity. Second, we map the two-level dynamics onto a nonlinear Riccati differential equation and show that the Markov approximation is equivalent to a linearization of the derived Riccati equation. Moreover, our approach helps to identify the nonlinear term as the reason for the breakdown of the Markov approximation close to the avoided crossing. Finally, we derive exact asymptotic expressions for the transition amplitudes using elementary functions for both negative and positive times. Connecting these two regimes via the analytical continuation of the logarithmic phase reveals that the Landau-Zener transition is mainly governed by a logarithmic phase singularity. Based on this logarithmic phase singularity, we introduce a new time scale to map the system dynamics as a path via a logarithmic phase ansatz in the complex plane. Evaluating this path via the Cauchy’s integral formula yields the exact transition probability which demonstrates that the exact solution emerges from the underlying phase singularity rather than properties of special functions.
The search for exactly solvable models is an evergreen topic in theoretical physics. In the context of multistate Landau-Zener models -- NNN-state quantum systems with linearly time-dependent Hamiltonians -- the theory of integrability provides a framework for identifying new solvable cases. In particular, it was proved that the integrability of a specific class known as the multitime Landau-Zener (MTLZ) models guarantees their exact solvability. A key finding was that an NNN-state MTLZ model can be represented by data defined on an NNN-vertex graph. While known host graphs for MTLZ models include hypercubes, fans, and their Cartesian products, no other families have been discovered, leading to the conjecture that these are the only possibilities. In this work, we conduct a systematic graph-theoretical search for integrable models within the MTLZ class. By first identifying minimal structures that a graph must contain to host an MTLZ model, we formulate an efficient algorithm to systematically search for candidate graphs for MTLZ models. Implementing this algorithm using computational software, we enumerate all candidate graphs with up to N=13N = 13N=13 vertices and perform an in-depth analysis of those with N≤11N \le 11N≤11. Our results corroborate the aforementioned conjecture for graphs up to 111111 vertices. For even larger graphs, we propose a specific family, termed descendants of ``(0,2)(0,2)(0,2)-graphs'', as promising candidates that may violate the conjecture above. Our work can serve as a guideline to identify new exactly solvable multistate Landau-Zener models in the future.
Abstract All currently known exactly solvable multistate Landau–Zener (MLZ) models are associated with families of operators that commute with the MLZ Hamiltonians and depend on time linearly. There can also be operators that satisfy the integrability conditions with the MLZ Hamiltonians but depend on time quadratically. We show that, among the MLZ systems, such time-quadratic operators are much more common. We demonstrate then that such operators generally lead to constraints on the independent variables that parametrize the scattering matrix. Such constraints lead to asymptotically exact expressions for the transition probabilities in the adiabatic limit of a three-level MLZ model. New more complex fully solvable MLZ systems are also found.