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arXiv:2602.03714 · Journal of High Energy Physics

Thermodynamics of the Heisenberg XXX chain with negative spin

Rong Zhong, Yang-Yang Chen, Kun Hao, Wen-li Yang, Vladimir Korepin

hep-thcond-mat.stat-mechquant-phSubmitted Feb 3, 2026• Announced Feb 4, 2026• 0 citations
v1 · Feb 3, 2026v2 · Feb 12, 2026v3 · Aug 13, 2026
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Abstract

We study the thermodynamics of the isotropic Heisenberg XXX spin chain with negative spin, focusing on the case $s=-1$. The model is equivalent to the quantum lattice nonlinear Schrödinger (NLS) model and appears as an effective theory in deep inelastic scattering in high-energy quantum chromodynamics. Owing to its integrability, it admits a consistent Bethe Ansatz description and a well-defined thermodynamic limit. Using the thermodynamic Bethe Ansatz, we analyze the ground state, elementary excitations, and finite-temperature properties. In contrast to the conventional positive spin XXX chain, the negative spin model exhibits a distinct vacuum structure and excitation spectrum, leading to modified TBA equations and unconventional low-temperature behavior. Although the integral equations resemble those of the Lieb-Liniger Bose gas, the thermodynamics and scaling properties are qualitatively different and cannot be continuously connected. We derive the free energy, entropy, and specific heat, and identify a quantum phase transition separating different thermodynamic regimes. At zero temperature, the excitation spectrum becomes linear in the continuum limit and can be described by a conformal field theory. The low-temperature regime realizes a Luttinger-liquid like phase with features unique to the negative spin XXX chain.

Journal reference
JHEP 08 (2026) 101
DOI
10.1007/JHEP08(2026)101
Comments
26 pages, 10 figures

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We study the thermodynamics of the isotropic Heisenberg XXX spin chain with negative spin, focusing on the case s=−1s=-1s=−1. The model is equivalent to the quantum lattice nonlinear Schrödinger (NLS) model and appears as an effective theory in deep inelastic scattering in high-energy quantum chromodynamics. Owing to its integrability, it admits a consistent Bethe Ansatz description and a well-defined thermodynamic limit. Using the thermodynamic Bethe Ansatz, we analyze the ground state, elementary excitations, and finite-temperature properties.
In contrast to the conventional positive spin XXX chain, the negative spin model exhibits a distinct vacuum structure and excitation spectrum, leading to modified TBA equations and unconventional low-temperature behavior. Although the integral equations resemble those of the Lieb-Liniger Bose gas, the thermodynamics and scaling properties are qualitatively different and cannot be continuously connected.
We derive the free energy, entropy, and specific heat, and identify a quantum phase transition separating different thermodynamic regimes. At zero temperature, the excitation spectrum becomes linear in the continuum limit and can be described by a conformal field theory. The low-temperature regime realizes a Luttinger-liquid like phase with features unique to the negative spin XXX chain.
[Formula: see text] spin chain with spin [Formula: see text] appears as an effective theory of Quantum Chromodynamics. It is equivalent to lattice nonlinear Schroediger’s equation: interacting chain of harmonic oscillators [bosonic]. In thermodynamic limit each energy level is a scattering state of several elementary excitations [lipatons]. Lipaton is a fermion: it can be represented as a topological excitation [soliton] of original [bosonic] degrees of freedom, described by the group [Formula: see text]. We also provide the CFT description (including local quenches) and Yang–Yang thermodynamics of the model.
Abstract This chapter presents the extension of the Bethe ansatz to finite temperature, the thermodynamic Bethe ansatz, for the antiferromagnetic isotropic Heisenberg quantum spin chain, the XXX quantum spin chain. It discusses how the added complications of this model arise from the more complicated structure of excitations of the quantum spin chain, the complex string excitations, which have to be included in the Bethe ansatz thermodynamics. It derives the integral equations of the thermodynamic Bethe ansatz for the XXX quantum spin chain and mentions explicit formulas for the free energy of the quantum spin chain and some interesting physical quantities, especially making contact with predictions of conformal symmetry.
This chapter reviews the various techniques developed for the study of the thermodynamics of integrable systems at the example of the simplest one, namely the spin-12 Heisenberg chain. As a matter of fact, the strict ground state is inaccessible due to the very fundamentals of thermodynamics. The minimization of the free energy functional yields what is known as the thermodynamical Bethe ansatz. Application of thermodynamical data of quantum spin chains is the microscopic modelling of magnetic systems such as spin-Peierls compounds and ladder systems. The microscopic interactions of a given substance are determined by a comparative analysis of the experimental results for the susceptibility and the theoretical data obtained for a model. Lowering the temperature, the systems enter a large regime with non-universal correlations and finally approach the quantum critical point at exactly zero temperature showing again universal yet nontrivial properties with divergent correlation lengths governed by conformal field theory.
The free energy per lattice site of a quantum spin chain in the thermodynamic limit is determined by a single `dominant' Eigenvalue of an associated quantum transfer matrix in the infinite Trotter number limit. For integrable quantum spin chains, related with solutions of the Yang-Baxter equation, an appropriate choice of the quantum transfer matrix enables to study its spectrum, e.g.\ by means of the algebraic Bethe Ansatz. In its turn, the knowledge of the full spectrum allows one to study its universality properties such as the appearance of a conformal spectrum in the low-temperature regime. More generally, accessing the full spectrum is a necessary step for deriving thermal form factor series representations of the correlation functions of local operators for the spin chain under consideration. These are statements that have been established by physicists on a heuristic level and that are calling for a rigorous mathematical justification. In this work we implement certain aspects of this programme with the example of the XXZ quantum spin chain in the antiferromagnetic massless regime and in the low-temperature limit. We rigorously establish the existence, uniqueness and characterise the form of the solutions to the non-linear integral equations that are equivalent to the Bethe Ansatz equations for the quantum transfer matrix of this model. This allows us to describe that part of the quantum transfer matrix spectrum that is related to the Bethe Ansatz and that does not collapse to zero in the infinite Trotter number limit. Within the considered part of the spectrum we rigorously identify the dominant Eigenvalue and show that those correlations lengths that diverge in the low-temperature limit are given, to the leading order, by the spectrum of the free Boson c=1c=1c=1 conformal field theory. This rigorously establishes a long-standing conjecture present in the physics literature.
We study the thermodynamic behaviour of Inozemtsev's long-range elliptic spin chain using the Bethe ansatz equations describing the spectrum of the model in the infinite-length limit. We classify all solutions of these equations in that limit and argue which of these solutions determine the spectrum in the thermodynamic limit. Interestingly, some of the solutions are not selfconjugate, which puts the model in sharp contrast to one of the model's limiting cases, the Heisenberg xxx spin chain. Invoking the string hypothesis we derive the thermodynamic Bethe ansatz equations (TBA-equations) from which we determine the Helmholtz free energy in thermodynamic equilibrium and derive the associated Y-system. We corroborate our results by comparing numerical solutions of the TBA-equations to a direct computation of the free energy for the finite-length hamiltonian. In addition we confirm numerically the interesting conjecture put forward by Finkel and González-López that the original and supersymmetric versions of Inozemtsev's elliptic spin chain are equivalent in the thermodynamic limit.
Introduction to Integrable Many-Body Systems II This is the second part of a three-volume introductory course about integrable systems of interacting bodies. The models of interest are quantum spin chains with nearest-neighbor interactions between spin operators, in particular Heisenberg spin-1/2 models. The Ising model in a transverse field, expressible as a quadratic fermion form by using the Jordan-Wigner transformation, is the subject of Sect. 12. The derivation of the coordinate Bethe ansatz for the XXZ Heisenberg chain and the determination of its absolute ground state in various regions of the anisotropy parameter are presented in Sect. 13. The magnetic properties of the ground state are explained in Sect. 14. Sect. 15 concerns excited states and the zero-temperature thermodynamics of the XXZ model. The thermodynamics of the XXZ Heisenberg chain is derived on the basis of the string hypothesis in Sect. 16; the thermodynamic Bethe ansatz equations are analyzed in high-temperature and low-temperature limits. An alternative derivation of the thermodynamics without using strings, leading to a non-linear integral equation determining the free energy, is the subject of Sect. 17. A nontrivial application of the Quantum Inverse Scattering method to the fully anisotropic XYZ Heisenberg chain is described in Sect. 18. Sect. 19 deals with integrable cases of isotropic spin chains with an arbitrary spin.