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Thermodynamics of the Isotropic Heisenberg Quantum Spin Chain

Hans-Peter Eckle

Published Jul 25, 2019• 0 citations
Publisher

Abstract

Abstract This chapter presents the extension of the Bethe ansatz to finite temperature, the thermodynamic Bethe ansatz, for the antiferromagnetic isotropic Heisenberg quantum spin chain, the XXX quantum spin chain. It discusses how the added complications of this model arise from the more complicated structure of excitations of the quantum spin chain, the complex string excitations, which have to be included in the Bethe ansatz thermodynamics. It derives the integral equations of the thermodynamic Bethe ansatz for the XXX quantum spin chain and mentions explicit formulas for the free energy of the quantum spin chain and some interesting physical quantities, especially making contact with predictions of conformal symmetry.

DOI
10.1093/oso/9780199678839.003.0018

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Abstract This chapter presents the extension of the Bethe ansatz to finite temperature, the thermodynamic Bethe ansatz, for the antiferromagnetic isotropic Heisenberg quantum spin chain, the XXX quantum spin chain. It discusses how the added complications of this model arise from the more complicated structure of excitations of the quantum spin chain, the complex string excitations, which have to be included in the Bethe ansatz thermodynamics. It derives the integral equations of the thermodynamic Bethe ansatz for the XXX quantum spin chain and mentions explicit formulas for the free energy of the quantum spin chain and some interesting physical quantities, especially making contact with predictions of conformal symmetry.
We study the thermodynamics of the isotropic Heisenberg XXX spin chain with negative spin, focusing on the case s=−1s=-1s=−1. The model is equivalent to the quantum lattice nonlinear Schrödinger (NLS) model and appears as an effective theory in deep inelastic scattering in high-energy quantum chromodynamics. Owing to its integrability, it admits a consistent Bethe Ansatz description and a well-defined thermodynamic limit. Using the thermodynamic Bethe Ansatz, we analyze the ground state, elementary excitations, and finite-temperature properties. In contrast to the conventional positive spin XXX chain, the negative spin model exhibits a distinct vacuum structure and excitation spectrum, leading to modified TBA equations and unconventional low-temperature behavior. Although the integral equations resemble those of the Lieb-Liniger Bose gas, the thermodynamics and scaling properties are qualitatively different and cannot be continuously connected. We derive the free energy, entropy, and specific heat, and identify a quantum phase transition separating different thermodynamic regimes. At zero temperature, the excitation spectrum becomes linear in the continuum limit and can be described by a conformal field theory. The low-temperature regime realizes a Luttinger-liquid like phase with features unique to the negative spin XXX chain.
Abstract The Bethe ansatz genuinely considers a finite system. The extraction of finite-size results from the Bethe ansatz equations is of genuine interest, especially against the background of the results of finite-size scaling and conformal symmetry in finite geometries. The mathematical techniques introduced in chapter 19 permit a systematic treatment in this chapter of finite-size corrections as corrections to the thermodynamic limit of the system. The application of the Euler-Maclaurin formula transforming finite sums into integrals and finite-size corrections transforms the Bethe ansatz equations into Wiener–Hopf integral equations with inhomogeneities representing the finite-size corrections solvable using the Wiener–Hopf technique. The results can be compared to results for finite systems obtained from other approaches that are independent of the Bethe ansatz method. It briefly discusses higher-order corrections and offers a general assessment of the finite-size method.
Abstract This chapter verifies the conjecture for the wave function, the Bethe ansatz wave function, of the anisotropic Heisenberg quantum spin chain by examining first the cases for one, two, and three spin deviations. The equations determining the quasi- momenta are the Bethe ansatz equations, now obtained from the coordinate Bethe ansatz. The Bethe ansatz equations derive from the eigenvalue equation in combination with boundary conditions, here periodic boundary conditions. These quasi-momenta also determine the energy eigenvalue. However, solving the Bethe ansatz equations to obtain a particular state requires more considerations. New variables, called rapidities, are useful. The consideration of the thermodynamic limit then allows to extract information about the ground state and low-lying excitations of the anisotropic quantum spin chain from the Bethe ansatz equations. Furthermore, complex solutions of the Bethe ansatz equations, called strings, are considered.
Introduction to Integrable Many-Body Systems II This is the second part of a three-volume introductory course about integrable systems of interacting bodies. The models of interest are quantum spin chains with nearest-neighbor interactions between spin operators, in particular Heisenberg spin-1/2 models. The Ising model in a transverse field, expressible as a quadratic fermion form by using the Jordan-Wigner transformation, is the subject of Sect. 12. The derivation of the coordinate Bethe ansatz for the XXZ Heisenberg chain and the determination of its absolute ground state in various regions of the anisotropy parameter are presented in Sect. 13. The magnetic properties of the ground state are explained in Sect. 14. Sect. 15 concerns excited states and the zero-temperature thermodynamics of the XXZ model. The thermodynamics of the XXZ Heisenberg chain is derived on the basis of the string hypothesis in Sect. 16; the thermodynamic Bethe ansatz equations are analyzed in high-temperature and low-temperature limits. An alternative derivation of the thermodynamics without using strings, leading to a non-linear integral equation determining the free energy, is the subject of Sect. 17. A nontrivial application of the Quantum Inverse Scattering method to the fully anisotropic XYZ Heisenberg chain is described in Sect. 18. Sect. 19 deals with integrable cases of isotropic spin chains with an arbitrary spin.
This chapter reviews the various techniques developed for the study of the thermodynamics of integrable systems at the example of the simplest one, namely the spin-12 Heisenberg chain. As a matter of fact, the strict ground state is inaccessible due to the very fundamentals of thermodynamics. The minimization of the free energy functional yields what is known as the thermodynamical Bethe ansatz. Application of thermodynamical data of quantum spin chains is the microscopic modelling of magnetic systems such as spin-Peierls compounds and ladder systems. The microscopic interactions of a given substance are determined by a comparative analysis of the experimental results for the susceptibility and the theoretical data obtained for a model. Lowering the temperature, the systems enter a large regime with non-universal correlations and finally approach the quantum critical point at exactly zero temperature showing again universal yet nontrivial properties with divergent correlation lengths governed by conformal field theory.