We study an open quantum spin chain with non-reciprocal dissipation using a theoretical approach known as time-dependent generalized Gibbs ensemble. In the regime of weak dissipation the system is fully characterized by its rapidity distribution and we derive a closed set of coupled differential equations governing their time evolution. We check the accuracy of this theory by benchmarking the results against numerical simulations. Using this framework we are able to compute both the magnetization density and current dynamics, identifying some relations between the two. The problem of the anomalous power-law exponents identified in a previous work is discussed. Our work constitutes a theoretical approach that is able to describe the physics of non-reciprocal open quantum spin chains beyond analyses based on non-interacting fermions.
We study an open quantum spin chain with non-reciprocal dissipation using a theoretical approach known as time-dependent generalized Gibbs ensemble. In the regime of weak dissipation the system is fully characterized by its rapidity distribution and we derive a closed set of coupled differential equations governing their time evolution. We check the accuracy of this theory by benchmarking the results against numerical simulations. Using this framework we are able to compute both the magnetization density and current dynamics, identifying some relations between the two. The problem of the anomalous power-law exponents identified in a previous work is discussed. Our work constitutes a theoretical approach that is able to describe the physics of non-reciprocal open quantum spin chains beyond analyses based on non-interacting fermions.
Generalized Gibbs ensembles have been used as powerful tools to describe the steady state of integrable many-particle quantum systems after a sudden change of the Hamiltonian. Here, we demonstrate numerically that they can be used for a much broader class of problems. We consider integrable systems in the presence of weak perturbations which break both integrability and drive the system to a state far from equilibrium. Under these conditions, we show that the steady state and the time evolution on long timescales can be accurately described by a (truncated) generalized Gibbs ensemble with time-dependent Lagrange parameters, determined from simple rate equations. We compare the numerically exact time evolutions of density matrices for small systems with a theory based on block-diagonal density matrices (diagonal ensemble) and a time-dependent generalized Gibbs ensemble containing only a small number of approximately conserved quantities, using the one-dimensional Heisenberg model with perturbations described by Lindblad operators as an example.
The theory of open quantum systems represents one of the major developments of quantum mechanics over the last 50 years. Its central object of study is constituted by quantum systems that cannot be regarded as fully isolated, but instead interact with additional degrees of freedom, giving rise to irreversible phenomena such as dissipation and decoherence. The tools provided by this framework are nowadays of paramount importance across many active areas of research, including quantum computation, thermodynamics, metrology and biology. In this thesis, we investigate three main topics within the field. The first contribution concerns the microscopic derivation of the evolution equations, socalled quantum master equations, for open systems which are also subject to external driving fields. Standard techniques developed for time-independent Hamiltonians encounter several difficulties in the time-dependent case, largely restricting their applicability to specific instances, such as periodic or adiabatic drivings. In contrast, a core result of the derivation presented in the thesis is that, when the environment is sufficiently Markovian (essentially, memoryless), the non-adiabatic contributions to the driving field can be neglected in a controlled fashion, yielding an accurate master equation with time-dependent generator, capable of correctly reproducing the open dynamics even for strong drivings. This result is further supported by benchmarks against numerically exact simulations. The second contribution addresses the long-time behavior of general types of (Markovian) quantum master equations, including those of the form introduced above. While this problem has been extensively analyzed in the time-independent setting, virtually no results are known for time-dependent generators. In particular, we establish the foundations of a general theory of relaxation, that is, convergence towards an asymptotic trajectory in the long-time limit, independently of the initial state. The main results include a theorem guaranteeing sufficient conditions for relaxation and the derivation of a rate function governing the convergence to the asymptotic trajectory. The analysis is further extended to a simple non-Markovian case. Moreover, we treat in detail the specific master equation derived in the first part, connecting the aforementioned relaxation property directly to the underlying microscopic dynamics. The third contribution investigates chirality-induced spin selectivity (CISS) effects from the perspective of open quantum systems. Although the majority of theoretical studies aiming to model CISS are based on a coherent description of the spin dynamics, such effects have been observed also for electrons subject to incoherent transport across molecular networks. In this regard, we provide a rigorous ab initio derivation of the microscopic Hamiltonian describing the electronic transport, incorporating electron spin effects and contributions stemming from the nuclear vibrations. Within this result, we critically revise a master equation approach aiming to explain the origin of CISS effects observed in photosynthetic complexes. Taken together, these contributions offer fresh insights and original results on the interplay between driving fields and dissipation, relaxation phenomena, and electronic spin transport in the presence of incoherent dynamics. More broadly, these results provide new theoretical tools with several potential applications in quantum technologies, from modeling of control pulses in noisy environments to quantum reservoir engineering, and contribute to a deeper understanding of the role of quantum effects in biological systems.
Integrable quantum systems evolving from non-equilibrium initial states do not thermalize to conventional Gibbs ensembles (GE). Instead, at long times they relax to generalized Gibbs ensembles (GGEs), which incorporate the full set of local and quasi-local conserved quantities. While GGEs have been extensively studied in the literature, a quantitative analytic characterization of how different they are from ordinary GEs is still lacking. In this work, we address this question by employing the concept of athermality, which we define within quantum resource theory as the relative entropy between a given state and the closest thermal state. By means of integrability techniques we compute the athermality for several quantum quenches in paradigmatic integrable models, including the free XY spin chain, the interacting Lieb-Liniger model, the XXZ spin chain, and the harmonic chain. We find that often the athermality becomes anomalously small when the post-quench Hamiltonian is critical in its ground state, despite probing physics at a finite energy density. We also prove that it systematically develops a singularity at criticality, which is inherited from the entropy of the GGE.
We study an open quantum spin chain of arbitrary length with nearest neighbor XX interactions of strength g, immersed in an external constant magnetic field $\mathrm{\ensuremath{\Delta}}$ along the z direction, whose end spins are weakly coupled to two heat baths at different temperatures. In the so-called global approach, namely, without neglecting interspin interactions, using standard weak-coupling limit techniques, we first derive the open chain master equation written in terms of fermionic mode operators. Then, we focus on the study of the dependence of the resulting open dynamics from the ratio $r\ensuremath{\equiv}g/\mathrm{\ensuremath{\Delta}}$. By increasing r, some of the chain Bohr transition frequencies become negative; when this occurs, both the generator of the dissipative time evolution and its stationary states behave discontinuously. As a consequence, the asymptotic spin and heat flows also exhibit discontinuities, but in a different way: while source terms in the spin flow continuity equation show jumps, the heat flow instead is continuous but with discontinuous first derivatives with respect to r. These two behaviors might be experimentally accessible; in particular, they could discriminate between the global and the local approaches to open quantum spin chains. Indeed, the latter one, which neglects interspin interactions in the derivation of the master equation, does not show any kind of discontinuous behavior.
The problem of characterizing low-temperature spin dynamics in antiferromagnetic spin chains has so far remained elusive. Here we reinvestigate it by focusing on isotropic antiferromagnetic chains whose low-energy effective field theory is governed by the quantum nonlinear sigma model. Employing an exact nonperturbative theoretical approach, we analyze the low-temperature behavior in the vicinity of nonmagnetized states and obtain exact expressions for the spin diffusion constant and the NMR relaxation rate, which we compare with previous theoretical results in the literature. Surprisingly, in SU(2)-invariant spin chains in the vicinity of half filling we find a crossover from the semiclassical regime to a strongly interacting quantum regime characterized by zero spin Drude weight and diverging spin conductivity, indicating superdiffusive spin dynamics. The dynamical exponent of spin fluctuations is argued to belong to the Kardar-Parisi-Zhang universality class. Furthermore, by employing numerical time-dependent density matrix renormalization group simulations, we find robust evidence that the anomalous spin transport persists also at high temperatures, irrespective of the spectral gap and integrability of the model.
Unitary integrable models typically relax to a stationary Generalized Gibbs Ensemble (GGE), but in experimental realizations dissipation often breaks integrability. In this work, we use the recently introduced time-dependent GGE (t-GGE) approach to describe the open dynamics of a gas of bosons subject to atom losses and gains. We employ tensor network methods to provide numerical evidence of the exactness of the t-GGE in the limit of adiabatic dissipation, and of its accuracy in the regime of weak but finite dissipation. That accuracy is tested for two-point functions via the rapidity distribution, and for more complicated correlations through a non-Gaussianity measure. We combine this description with Generalized Hydrodynamics and we show that it correctly captures transport at the Euler scale. Our results demonstrate that the t-GGE approach is robust in both homogeneous and inhomogeneous settings.