Nonlocality is a defining feature of quantum mechanics and has long served as a key indicator of quantum resources since the formulation of Bell's inequalities. Identifying the contribution of nonlocality to extractable work remains a central problem in quantum thermodynamics. We address this by introducing a quantifier of nonlocal contributions to extractable work in bipartite systems. It is shown that closed form expressions can be calculated for our quantity in terms of the Schmidt coefficients. Further for strictly non-interacting Hamiltonian, the direct relationship between ergotropy and correlations is established. Our results reveal that nonlocal resources invariably enhance extractable work under non-interacting Hamiltonians, while in the presence of interactions, their contribution can either increase or diminish depending on the structure of the state and the Hamiltonian.
Nonlocality is a defining feature of quantum mechanics and has long served as a key indicator of quantum resources since the formulation of Bell's inequalities. Identifying the contribution of nonlocality to extractable work remains a central problem in quantum thermodynamics. We address this by introducing a quantifier of nonlocal contributions to extractable work in bipartite systems. It is shown that closed form expressions can be calculated for our quantity in terms of the Schmidt coefficients. Further for strictly non-interacting Hamiltonian, the direct relationship between ergotropy and correlations is established. Our results reveal that nonlocal resources invariably enhance extractable work under non-interacting Hamiltonians, while in the presence of interactions, their contribution can either increase or diminish depending on the structure of the state and the Hamiltonian.
Understanding the role of classical and quantum correlations in work extraction is a problem of fundamental importance in thermodynamics. We approach this problem by considering that, in closed quantum systems, the maximum cyclic work extractable is equal to the ergotropy. Thus, we aim to identify and investigate the contributions to the ergotropy coming from different kinds of initial correlations (total, classical, discord, and entanglement correlations). By doing so, we have introduced and studied quantifiers of correlations which are based on ergotropy. In particular, our results suggest that only discord correlations always give a positive contribution to work extraction, whereas total, classical, and entanglement correlations can reduce the work extraction.
We investigate the dynamics of ergotropy in open systems under Markovian and non-Markovian evolutions. In this scenario, we begin by formulating the ergotropy of an arbitrary qubit state in terms of energy and coherence. Thus we determine the conditions for ergotropy freezing and ergotropy sudden death as a consequence of the system-bath interaction. In order to use ergotropy as a resource for energy extraction in the form of work in an open-system scenario, we adopt the entropy-based formulation of quantum thermodynamics. In this approach, the work gains an additional environment-induced component, which may be present even for constant Hamiltonians. We then establish an analytical relationship between the environment-induced work and ergotropy, providing an interpretation of environment-induced work in terms of variation of ergotropy. In particular, energy transfer by environment-induced work can be performed up to a limit, which is governed by the energy cost to transit between the initial and final passive states of the quantum dynamics. We illustrate these results for qubit states evolving under nondissipative and dissipative quantum processes.
A fundamental problem in quantum thermodynamics is to properly quantify the work extractable from out-of-equilibrium systems. While for closed systems, maximum quantum work extraction is defined in terms of the ergotropy functional, this question is unclear in open systems interacting with an environment. The concept of local ergotropy has been proposed, but it presents several problems, such as it is not guaranteed to be nonincreasing in time. Here, we introduce the concept of extended local ergotropy by exploiting the free evolution of the system-environment compound. At variance with the local ergotropy, the extended local ergotropy is greater, is nonincreasing in time, and activates the potential of work extraction in many cases. We then concentrate on specific schemes in which we alternate repeated local unitaries and free system-environment evolution. We provide examples based on the Jaynes-Cummings model, presenting practical protocols and analytic results that serve as proof of principle for the aforementioned advantages.
Quantum thermodynamics has emerged as a central field for understanding how energy conversion processes occur in microscopic systems. In these systems, effects such as coherence, entanglement, and non-Markovianity play key roles. In this thesis, we explore different ways to describe quantum thermodynamics, using two main approaches: one based on entropy and the other on ergotropy. First, we introduce a generalized approach to quantify non-Markovianity through the breakdown of monotonicity in thermodynamic functions. In this context, the entropy-based heat flow serves as a practical tool to witness and measure quantum memory in unital maps that do not reverse the sign of the internal energy. Next, we analyze the dynamics of ergotropy in open qubits under both Markovian and non-Markovian evolutions. We identify phenomena such as freezing and sudden death of ergotropy, and we establish an analytical relation between the change in ergotropy and the environment-induced work . This provides a clear physical interpretation for the additional term in the first law in the entropy-based formulation. Finally, we propose an ergotropy-based thermodynamic formulation, in which heat is reinterpreted in terms of the change of the passive state associated with the density operator governing the quantum dynamics. This approach allows one to measure non-Markovianity of unital maps more generally and accurately than the entropy-based heat flow. This advantage comes from the direct link between heat and von Neumann entropy, a property ensured by invariance under passive transformations. Moreover, the out-of-equilibrium temperature naturally remains non-negative, similarly to equilibrium thermodynamics.
The paradigm of extracting work from an isolated quantum system through a cyclic Hamiltonian process is a topic of immense research interest. The optimal work extracted under such a process is termed ergotropy [Europhys. Lett. 67, 565 (2004)]. Here, in a multiparty scenario, we consider only a class of such cyclic processes that can be implemented locally, giving rise to the concept of local ergotropy. Eventually, the presence of quantum correlations results in a nonvanishing thermodynamic quantity called an ergotropic gap, measured by the difference between global and local ergotropy. However, the converse does not hold in general, i.e., its nonzero value does not necessarily imply the presence of quantum correlations. For arbitrary multiparty states, we quantify this gap. We also evaluate the difference between maximum global and local extractable work for arbitrary states when the system is no longer isolated but put in contact with a bath of the same local temperature.
Abstract It is an established fact that quantum coherences have thermodynamic value. The natural question arises, whether other genuine quantum properties such as entanglement can also be exploited to extract thermodynamic work. In the present analysis, we show that the ergotropy can be expressed as a function of the quantum mutual information, which demonstrates the contributions to the extractable work from classical and quantum correlations. More specifically, we analyze bipartite quantum systems with locally thermal states, such that the only contribution to the ergotropy originates in the correlations. Our findings are illustrated for a two-qubit system collectively coupled to a thermal bath.