We investigate the dynamics of ergotropy in open systems under Markovian and non-Markovian evolutions. In this scenario, we begin by formulating the ergotropy of an arbitrary qubit state in terms of energy and coherence. Thus we determine the conditions for ergotropy freezing and ergotropy sudden death as a consequence of the system-bath interaction. In order to use ergotropy as a resource for energy extraction in the form of work in an open-system scenario, we adopt the entropy-based formulation of quantum thermodynamics. In this approach, the work gains an additional environment-induced component, which may be present even for constant Hamiltonians. We then establish an analytical relationship between the environment-induced work and ergotropy, providing an interpretation of environment-induced work in terms of variation of ergotropy. In particular, energy transfer by environment-induced work can be performed up to a limit, which is governed by the energy cost to transit between the initial and final passive states of the quantum dynamics. We illustrate these results for qubit states evolving under nondissipative and dissipative quantum processes.
We investigate the dynamics of ergotropy in open systems under Markovian and non-Markovian evolutions. In this scenario, we begin by formulating the ergotropy of an arbitrary qubit state in terms of energy and coherence. Thus we determine the conditions for ergotropy freezing and ergotropy sudden death as a consequence of the system-bath interaction. In order to use ergotropy as a resource for energy extraction in the form of work in an open-system scenario, we adopt the entropy-based formulation of quantum thermodynamics. In this approach, the work gains an additional environment-induced component, which may be present even for constant Hamiltonians. We then establish an analytical relationship between the environment-induced work and ergotropy, providing an interpretation of environment-induced work in terms of variation of ergotropy. In particular, energy transfer by environment-induced work can be performed up to a limit, which is governed by the energy cost to transit between the initial and final passive states of the quantum dynamics. We illustrate these results for qubit states evolving under nondissipative and dissipative quantum processes.
Quantum thermodynamics has emerged as a central field for understanding how energy conversion processes occur in microscopic systems. In these systems, effects such as coherence, entanglement, and non-Markovianity play key roles. In this thesis, we explore different ways to describe quantum thermodynamics, using two main approaches: one based on entropy and the other on ergotropy. First, we introduce a generalized approach to quantify non-Markovianity through the breakdown of monotonicity in thermodynamic functions. In this context, the entropy-based heat flow serves as a practical tool to witness and measure quantum memory in unital maps that do not reverse the sign of the internal energy. Next, we analyze the dynamics of ergotropy in open qubits under both Markovian and non-Markovian evolutions. We identify phenomena such as freezing and sudden death of ergotropy, and we establish an analytical relation between the change in ergotropy and the environment-induced work . This provides a clear physical interpretation for the additional term in the first law in the entropy-based formulation. Finally, we propose an ergotropy-based thermodynamic formulation, in which heat is reinterpreted in terms of the change of the passive state associated with the density operator governing the quantum dynamics. This approach allows one to measure non-Markovianity of unital maps more generally and accurately than the entropy-based heat flow. This advantage comes from the direct link between heat and von Neumann entropy, a property ensured by invariance under passive transformations. Moreover, the out-of-equilibrium temperature naturally remains non-negative, similarly to equilibrium thermodynamics.
We introduce an ergotropy-based formulation of quantum thermodynamics, which provides a strong connection between average heat and von Neumann entropy. By adopting this formulation, we can reinterpret the infinitesimal average heat in terms of the infinitesimal change of the passive state associated with the density operator behind the quantum dynamics. Like entropy, this leads to a heat concept that is invariant under passive state transformations. As an application, the average heat can be used as a general non-Markovianity measure for unital maps. Moreover, a positive-semidefinite temperature naturally emerges in an out-of-equilibrium ergotropy-based scenario. Concerning the infinitesimal average work, it arises as an infinitesimal variation of ergotropy, as well as an extra passive work contribution in the case of a time-dependent Hamiltonian. As illustrations, we consider the thermodynamics of a single-qubit open system in the cases of generalized amplitude-damping and phase-damping channels.
Abstract In many standard analyses of quantum thermodynamics, the system and its environment are assumed to be initially independent and free of any correlations. However, in many physical scenarios, initial system-environment correlations are unavoidable. In this work, we investigate the role of initial system-environment correlations in work extraction from open quantum systems. Furthermore, we examine the effects of these correlations and the nature of environmental dynamics on the evolution of coherence, coherence-based ergotropy, and total ergotropy. In both Markovian and non-Markovian regimes, we show that initial correlations directly influence the amount of ergotropy. We also demonstrate that in the non-Markovian regime, reducing the initial correlation enables optimal utilization of memory effects and maintains work extraction efficiency over longer time intervals. In contrast, in the Markovian regime, such correlations only accelerate the decay process without producing a revival of quantum resources; therefore, work extraction must be carried out within very short time intervals.
Ergotropy, which represents the maximum amount of work that can be extracted from a quantum system, has become a focal point of interest in the fields of quantum thermodynamics and information processing. In practical scenarios, the interaction of quantum systems with their surrounding environment is unavoidable. Recent studies have increasingly focused on analyzing open quantum systems affected by non-stationary environmental fluctuations due to their significant impact on various physical scenarios. While much research has concentrated on work extraction from these systems, it often assumes that the environmental degrees of freedom are substantial and that the environment is effectively in equilibrium. This has led us to explore work extraction from quantum systems under non-stationary environmental conditions. In this work, the dynamics of ergotropy will be investigated in a non-equilibrium environment for both Markovian and non-Markovian regime. In this study, both the coherent and incoherent parts of the ergotropy will be considered. It will be shown that for a non-equilibrium environment, the extraction of work is more efficient compared to when the environment is in equilibrium.
We study the ergotropy and the thermodynamic potentials of a qubit battery charged by repeated interactions with clusters of thermal ancillas, qubits or oscillators, through a composite system-bath coupling that generates steady-state coherence in the energy basis. A single parameter encoding the bath quantum statistics yields the coherence and ergotropy in closed form for any cluster size. For large clusters, the ergotropy becomes independent of the bath statistics and, at optimal couplings, reaches a universal fraction of the equilibrium internal energy of the qubit at the bath temperature. Since the charged state has no population inversion, all extractable work comes from coherence. The ergotropy is flat at low temperatures. We trace this plateau to the third law, and show that the ergotropy is proportional to the equilibrium enthalpy of the qubit, whose slope vanishes with the heat capacity. For a battery composed of multiple qubits, the coherence grows exponentially with the number of qubits while the ergotropy grows linearly, both remaining a nearly constant fraction of their respective maxima. The charged state is a non-equilibrium steady state with finite entropy at zero temperature, sustained by the work of switching the collisional interaction on and off. The cost is nonzero whenever the parallel coupling is nonzero, and, unlike the ergotropy, it depends on the bath statistics.
Interactions between a quantum system and its environment can inject ergotropy into the system, raising the question of the minimal dimensionality and physical resources required for such injection. We first show that ergotropy injection is impossible under thermal operations when both the system and environment are qubits, whereas it becomes possible when the environment is enlarged to a qutrit. We further show that already in the qubit-qubit setting, relaxing environmental thermality and allowing interactions between system and environment allows ergotropy increment under energy-conserving unitaries. To elucidate the role of interactions, we consider a two-qubit isotropic XY interaction Hamiltonian and identify its distinct degeneracy regimes. We show that, in the central-block regime, when both the initial system and environmental states are incoherent, no ergotropic gain is possible when the environment is initially thermal, irrespective of the interaction strength. In contrast, environmental athermality in the form of population inversion, while retaining incoherence, enables ergotropic injection. We derive the optimal ergotropic gain and show that environmental coherence can enhance it, while system coherence alone need not be beneficial and can even reduce the gain. We further consider the double-degenerate regime, characterized by a finite interaction strength, and demonstrate positive ergotropic gain even for a thermal environment.