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arXiv:2504.07200 · Physical Review A

Ergotropy-based quantum thermodynamics

J. M. Z. Choquehuanca, P. A. C. Obando, M. S. Sarandy, F. M. de Paula

Published Oct 2, 2025• 2 citations
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Abstract

We introduce an ergotropy-based formulation of quantum thermodynamics, which provides a strong connection between average heat and von Neumann entropy. By adopting this formulation, we can reinterpret the infinitesimal average heat in terms of the infinitesimal change of the passive state associated with the density operator behind the quantum dynamics. Like entropy, this leads to a heat concept that is invariant under passive state transformations. As an application, the average heat can be used as a general non-Markovianity measure for unital maps. Moreover, a positive-semidefinite temperature naturally emerges in an out-of-equilibrium ergotropy-based scenario. Concerning the infinitesimal average work, it arises as an infinitesimal variation of ergotropy, as well as an extra passive work contribution in the case of a time-dependent Hamiltonian. As illustrations, we consider the thermodynamics of a single-qubit open system in the cases of generalized amplitude-damping and phase-damping channels.

DOI
10.1103/3vt1-m8z2

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We introduce an ergotropy-based formulation of quantum thermodynamics, which provides a strong connection between average heat and von Neumann entropy. By adopting this formulation, we can reinterpret the infinitesimal average heat in terms of the infinitesimal change of the passive state associated with the density operator behind the quantum dynamics. Like entropy, this leads to a heat concept that is invariant under passive state transformations. As an application, the average heat can be used as a general non-Markovianity measure for unital maps. Moreover, a positive-semidefinite temperature naturally emerges in an out-of-equilibrium ergotropy-based scenario. Concerning the infinitesimal average work, it arises as an infinitesimal variation of ergotropy, as well as an extra passive work contribution in the case of a time-dependent Hamiltonian. As illustrations, we consider the thermodynamics of a single-qubit open system in the cases of generalized amplitude-damping and phase-damping channels.
Quantum thermodynamics has emerged as a central field for understanding how energy conversion processes occur in microscopic systems. In these systems, effects such as coherence, entanglement, and non-Markovianity play key roles. In this thesis, we explore different ways to describe quantum thermodynamics, using two main approaches: one based on entropy and the other on ergotropy. First, we introduce a generalized approach to quantify non-Markovianity through the breakdown of monotonicity in thermodynamic functions. In this context, the entropy-based heat flow serves as a practical tool to witness and measure quantum memory in unital maps that do not reverse the sign of the internal energy. Next, we analyze the dynamics of ergotropy in open qubits under both Markovian and non-Markovian evolutions. We identify phenomena such as freezing and sudden death of ergotropy, and we establish an analytical relation between the change in ergotropy and the environment-induced work . This provides a clear physical interpretation for the additional term in the first law in the entropy-based formulation. Finally, we propose an ergotropy-based thermodynamic formulation, in which heat is reinterpreted in terms of the change of the passive state associated with the density operator governing the quantum dynamics. This approach allows one to measure non-Markovianity of unital maps more generally and accurately than the entropy-based heat flow. This advantage comes from the direct link between heat and von Neumann entropy, a property ensured by invariance under passive transformations. Moreover, the out-of-equilibrium temperature naturally remains non-negative, similarly to equilibrium thermodynamics.
We investigate the dynamics of ergotropy in open systems under Markovian and non-Markovian evolutions. In this scenario, we begin by formulating the ergotropy of an arbitrary qubit state in terms of energy and coherence. Thus we determine the conditions for ergotropy freezing and ergotropy sudden death as a consequence of the system-bath interaction. In order to use ergotropy as a resource for energy extraction in the form of work in an open-system scenario, we adopt the entropy-based formulation of quantum thermodynamics. In this approach, the work gains an additional environment-induced component, which may be present even for constant Hamiltonians. We then establish an analytical relationship between the environment-induced work and ergotropy, providing an interpretation of environment-induced work in terms of variation of ergotropy. In particular, energy transfer by environment-induced work can be performed up to a limit, which is governed by the energy cost to transit between the initial and final passive states of the quantum dynamics. We illustrate these results for qubit states evolving under nondissipative and dissipative quantum processes.
We introduce a generalized approach to characterize the non-Markovianity of quantum dynamical maps via breakdown of monotonicity of thermodynamic functions. By adopting an entropy-based formulation of quantum thermodynamics, we use the relationship between heat and entropy to propose a measure of non-Markovianity based on the heat flow for single-qubit quantum evolutions. This measure can be applied for unital dynamical maps that do not invert the sign of the internal energy. Under certain conditions, it can also be extended for other thermodynamic functions, such as internal energy and work flows. In this context, a natural connection between heat and quantum coherence can be identified for dynamical maps that are both unital and incoherent. As applications, we explore dissipative and nondissipative quantum dynamical processes, illustrating the compatibility between our thermodynamic quantifiers and the well-establish measure defined via quantum coherence.
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This paper explores quantum heat engines based on qubit and qutrit working media interacting with thermal environments through generalized amplitude damping (GAD) channels. We investigate how quantum channels can be employed to model heat absorption, dissipation, and work extraction in open quantum thermal machines, and derive the conditions required for positive work extraction. The effects of quantum correlations, emission probability, population redistribution, and system--environment interactions on the thermodynamic performance of the engine are systematically analyzed across different operational regimes. In addition, we examine the ergotropy of qubit and qutrit systems under dissipative dynamics to understand how environmental effects influence the maximum extractable work. Our results demonstrate that multilevel quantum systems exhibit enhanced work extraction capability and improved robustness against decoherence compared to two-level systems, providing further insight into the role of dissipative dynamics and quantum resources in realistic quantum thermodynamic devices.
In this work, we introduce and characterize a broad class of quantum operations with a unique fixed point, termed quantum ergodic channels. We derive Lindblad-type master equations for these channels in arbitrary finite dimensions and analyze their non-Markovian dynamics using established measures. When the fixed point is a passive state, the channels exhibit ergotropy dynamics with notable thermodynamic implications. Specifically, under Markovian processes, ergotropy (a measure of the extractable work from a system under unitary evolution) monotonically decreases. However, in non-Markovian dynamics, ergotropy fluctuates, leading to a backflow effect that highlights memory-induced resource recovery. Our findings suggest that this ergotropy backflow could serve as an operationally meaningful indicator of non-Markovianity, offering new perspectives on the interplay between memory effects and thermodynamic behavior in open quantum systems. This study enhances the theoretical framework for understanding energy dynamics under ergodic channels and highlights new avenues for exploring the implications of memory effects in quantum batteries.