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arXiv:2401.10996 · Physical Review Letters

Extended Local Ergotropy

Riccardo Castellano, Donato Farina, Vittorio Giovannetti, Antonio Acín

Published Oct 10, 2024• 21 citations
arXivHTMLPDF

Abstract

A fundamental problem in quantum thermodynamics is to properly quantify the work extractable from out-of-equilibrium systems. While for closed systems, maximum quantum work extraction is defined in terms of the ergotropy functional, this question is unclear in open systems interacting with an environment. The concept of local ergotropy has been proposed, but it presents several problems, such as it is not guaranteed to be nonincreasing in time. Here, we introduce the concept of extended local ergotropy by exploiting the free evolution of the system-environment compound. At variance with the local ergotropy, the extended local ergotropy is greater, is nonincreasing in time, and activates the potential of work extraction in many cases. We then concentrate on specific schemes in which we alternate repeated local unitaries and free system-environment evolution. We provide examples based on the Jaynes-Cummings model, presenting practical protocols and analytic results that serve as proof of principle for the aforementioned advantages.

DOI
10.1103/physrevlett.133.150402

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A fundamental problem in quantum thermodynamics is to properly quantify the work extractable from out-of-equilibrium systems. While for closed systems, maximum quantum work extraction is defined in terms of the ergotropy functional, this question is unclear in open systems interacting with an environment. The concept of local ergotropy has been proposed, but it presents several problems, such as it is not guaranteed to be nonincreasing in time. Here, we introduce the concept of extended local ergotropy by exploiting the free evolution of the system-environment compound. At variance with the local ergotropy, the extended local ergotropy is greater, is nonincreasing in time, and activates the potential of work extraction in many cases. We then concentrate on specific schemes in which we alternate repeated local unitaries and free system-environment evolution. We provide examples based on the Jaynes-Cummings model, presenting practical protocols and analytic results that serve as proof of principle for the aforementioned advantages.
Maximum quantum work extraction is generally defined in terms of the ergotropy functional, no matter how experimentally complicated is the implementation of the optimal unitary allowing for it, especially in the case of multipartite systems. In this framework, we consider a quantum battery made up of many interacting subsystems and study the maximum extractable work via concurrent local unitary operations on each subsystem. We call the resulting functional parallel ergotropy. Focusing on the bipartite case, we first observe that parallel ergotropy outperforms work extraction via egoistic strategies, in which the first agent A extracts locally on its part the maximum available work and the second agent B, subsequently, extracts what is left on the other part. For the agents, this showcases the need of cooperating for an overall benefit. Second, from the informational point of view, we observe that the parallel capacity of a state can detect entanglement and compare it with the statistical entanglement witness that exploits fluctuations of stochastic work extraction. Additionally, we face the technical problem of computing parallel ergotropy. We derive analytical upper bounds for specific classes of states and Hamiltonians and provide recipes to obtain numerical upper bounds via semidefinite programming in the generic case. Finally, extending the concept of parallel ergotropy, we demonstrate that system's free-time evolution and application of local unitaries allow one to saturate the gap with the ergotropy of the whole system.
We investigate the problem of finding the local analog of the ergotropy, which is the maximum work that can be extracted from a system if we can only apply local unitary transformation acting on a given subsystem. In particular, we provide a closed formula for the local ergotropy in the special case in which the local system has only two levels, and we give analytic lower bounds and semidefinite programming upper bounds for the general case. As nontrivial examples of application, we compute the local ergotropy for an atom in an electromagnetic cavity with Jaynes-Cummings coupling and the local ergotropy for a spin site in an XXZ Heisenberg chain, showing that the amount of work that can be extracted with a unitary operation on the coupled system can be greater than the work obtainable by quenching off the coupling with the environment before the unitary transformation.
Ergotropy, which represents the maximum amount of work that can be extracted from a quantum system, has become a focal point of interest in the fields of quantum thermodynamics and information processing. In practical scenarios, the interaction of quantum systems with their surrounding environment is unavoidable. Recent studies have increasingly focused on analyzing open quantum systems affected by non-stationary environmental fluctuations due to their significant impact on various physical scenarios. While much research has concentrated on work extraction from these systems, it often assumes that the environmental degrees of freedom are substantial and that the environment is effectively in equilibrium. This has led us to explore work extraction from quantum systems under non-stationary environmental conditions. In this work, the dynamics of ergotropy will be investigated in a non-equilibrium environment for both Markovian and non-Markovian regime. In this study, both the coherent and incoherent parts of the ergotropy will be considered. It will be shown that for a non-equilibrium environment, the extraction of work is more efficient compared to when the environment is in equilibrium.
Abstract In this mini-review, we discuss work extraction under restricted control, where only the system is accessible while other degrees of freedom remain uncontrolled. In this setting, local ergotropy is the maximum work extractable by cyclic unitaries on the system, and it can differ strongly from “switch-off” extraction after quenching the system-environment coupling. We review two settings where correlations and many-body effects shape local work. First, in a two-qubit quantum Rabi model, dissipation induces a Berezinskii–Kosterlitz–Thouless quantum phase transition. A gate-based charge-store-extract protocol uses a decoherence-free state to stabilize storage and makes strong system-bath coupling a resource, yielding local ergotropy above switch-off extraction and making its dynamics transition-dependent, also in relative fluctuations. Second, in a disordered XXZ chain where the first two spins form a battery coupled to an interacting spin bath, local ergotropy shows distinct long-time behavior across Anderson, many-body localized, and ergodic regimes, linking extractable work to localization transitions. Overall, the examples reviewed here show that local ergotropic observables quantify quantum-battery performance under local control and probe collective phenomena.
Nonlocality is a defining feature of quantum mechanics and has long served as a key indicator of quantum resources since the formulation of Bell's inequalities. Identifying the contribution of nonlocality to extractable work remains a central problem in quantum thermodynamics. We address this by introducing a quantifier of nonlocal contributions to extractable work in bipartite systems. It is shown that closed form expressions can be calculated for our quantity in terms of the Schmidt coefficients. Further for strictly non-interacting Hamiltonian, the direct relationship between ergotropy and correlations is established. Our results reveal that nonlocal resources invariably enhance extractable work under non-interacting Hamiltonians, while in the presence of interactions, their contribution can either increase or diminish depending on the structure of the state and the Hamiltonian.
The paradigm of extracting work from an isolated quantum system through a cyclic Hamiltonian process is a topic of immense research interest. The optimal work extracted under such a process is termed ergotropy [Europhys. Lett. 67, 565 (2004)]. Here, in a multiparty scenario, we consider only a class of such cyclic processes that can be implemented locally, giving rise to the concept of local ergotropy. Eventually, the presence of quantum correlations results in a nonvanishing thermodynamic quantity called an ergotropic gap, measured by the difference between global and local ergotropy. However, the converse does not hold in general, i.e., its nonzero value does not necessarily imply the presence of quantum correlations. For arbitrary multiparty states, we quantify this gap. We also evaluate the difference between maximum global and local extractable work for arbitrary states when the system is no longer isolated but put in contact with a bath of the same local temperature.