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arXiv:2511.14552

Experimental observation and application of the genuine Quantum Mpemba Effect

Bruno P. Schnepper, Jefferson L. D. de Oliveira, Carlos H. S. Vieira, Krissia Zawadzki, Roberto M. Serra

quant-phSubmitted Nov 18, 2025• Announced Nov 19, 2025• 0 citations
v1 · Nov 18, 2025v2 · Aug 17, 2026
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Abstract

Coherence is an inherently quantum property that deeply affects microscopic processes, including thermalization phenomena. A striking example is the quantum Mpemba effect (QME), in which a system can exhibit anomalous relaxation, thermalizing faster from a state initially farther from equilibrium than from one closer. Here, we experimentally investigate the genuine QME and observe how the dynamics of a spin-1/2 system interacting with a heat sink can be sped-up to equilibrium. Furthermore, we apply the QME in a quantum Otto refrigerator, thereby increasing its cooling power. This proof-of-concept experiment unveils new practical paths for improving quantum thermal tasks.

Comments
8 pages, 6 figures

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Coherence is an inherently quantum property that deeply affects microscopic processes, including thermalization phenomena. A striking example is the quantum Mpemba effect (QME), in which a system can exhibit anomalous relaxation, thermalizing faster from a state initially farther from equilibrium than from one closer. Here, we experimentally investigate the genuine QME and observe how the dynamics of a spin-1/2 system interacting with a heat sink can be sped-up to equilibrium. Furthermore, we apply the QME in a quantum Otto refrigerator, thereby increasing its cooling power. This proof-of-concept experiment unveils new practical paths for improving quantum thermal tasks.
The quantum Mpemba effect refers to the phenomenon of a quantum system in an initial state, far away from equilibrium, relaxing much faster than a state comparatively nearer to equilibrium. We experimentally demonstrate that this highly counterintuitive effect can occur naturally during the thermalization of quantum systems. Considering dipolar relaxation as the dominant decoherence process, we theoretically derive the conditions that can lead to the Mpemba effect in nuclear spins. After experimentally preparing nuclear spin states dictated by those conditions, we observe the occurrence of the Mpemba effect when they are left to thermalize without any external control. We also experimentally observe the genuine quantum Mpemba effect during thermalization of nuclear spins. Our results establish that both these effects are natural in thermalization of quantum systems, and may show up without the need for any bath engineering.
The Mpemba effect, where a state farther from equilibrium relaxes faster than one closer to it, is a striking phenomenon in both classical and quantum systems. In open quantum systems, however, the quantum Mpemba effect (QME) typically occurs only for specifically chosen initial states, which limits its universality. Here we present a general and experimentally feasible strategy to realize both QME and anti-QME. By applying a temporary bond-dissipation quench, we selectively suppresses or enhances slow relaxation modes, thereby reshaping relaxation pathways independently of both the system and the initial state. We demonstrate this mechanism in systems with dephasing and boundary dissipation, and outline feasible cold-atom implementations. Our results establish controllable dissipation as a versatile tool for quantum control, accelerated relaxation, and efficient nonequilibrium protocols.
The Mpemba effect, where a hotter system cools faster than a colder one under otherwise identical conditions, has been extensively studied in classical systems. In this work, we present the quantum analogue of the Mpemba effect using a dissipative qubit, which is referred to as the canonical quantum Mpemba effect. We demonstrate that, under the identical conditions, the relaxation dynamics of a qubit initialized in a thermal state with a higher temperature can be exponentially faster than those of a colder thermal state. Strikingly, this acceleration is determined solely by the initial temperature of the system, independent of other parameters. The relaxation is confirmed to be a genuine cooling process via the effective steady state temperature, mirroring its classical counterpart. Last, we propose a practical classical quantum hybrid algorithmic quantum circuit to realize this effect using superconducting qubits experimentally.
In recent years, the quantum Mpemba effect (QME) which occurs when an out-of-equilibrium system reaches equilibrium faster than another that is closer to equilibrium has attracted significant attention from the scientific community as an intriguing and counterintuitive phenomenon. It generalizes its classical counterpart, extending the concept beyond thermal equilibration. This paper approaches the QME for Markovian open quantum systems from different perspectives. Firstly, we propose a physical mechanism based on decoherence-free subspaces. Secondly, we show that a macroscopic enhancement of the decay rate that scales linearly with system size can be obtained, leading to an extreme version of the phenomenon on Markovian open quantum systems. Thirdly, we study the Mpemba effect through the unravelings of Davies maps, revealing subtleties in the figures of merit which are chosen for obtaining the QME. Lastly, we propose a microscopic model for a better understanding of thermal bath dynamics in this context.
The quantum Mpemba effect (QMpE) describes an anomalous thermalization phenomenon in which quantum states initially far from equilibrium can approach thermal equilibrium faster than states that begin closer to it. While this effect has been extensively studied in various frameworks, its practical implications for quantum information processing remain largely unexplored. We investigate the relationship between QMpE and quantum thermometry, focusing on non-equilibrium scenarios where measurements are performed during early-stage thermalization. In a Markovian model, we rigorously prove that the initial states that are optimal for thermometry exhibit QMpE with high probability and thermalize faster than most initial states. Our results reveal a fundamental connection between quantum thermodynamics and thermometry, suggesting that QMpE can be harnessed to enhance temperature estimation with quantum probes.
The Mpemba effect refers to the anomalous relaxation of a quantum state that, despite being initially farther from equilibrium, relaxes faster than a closer counterpart. Detecting such a quantum Mpemba effect typically requires full knowledge of the quantum state during its time evolution, which is an experimentally challenging task since state tomography becomes exponentially difficult as system size increases. This poses a significant obstacle in studying Mpemba effect in complex many-body systems. In this work, we demonstrate that this limitation can be overcome by identifying suitable observables that signal rapid relaxation. Moreover, as long as the system equilibrates to a known unique steady-state, it is possible to fully detect the occurrence of quantum Mpemba effect just by measuring the observable for known state preparations. Our approach thus significantly reduces experimental complexity and offers a practical route for observing the quantum Mpemba effect in complex and extended multi-qubit setups.