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arXiv:2510.12599 · Physical review. E

Quantum thermodynamics of Gross-Pitaevskii qubits

Sebastian Deffner

Published Mar 12, 2026• 2 citations
arXivHTMLPDF

Abstract

What are the resources that can be leveraged for a thermodynamic device to exhibit genuine quantum advantage? Typically, the answer to this question is sought in quantum correlations. In the present work, we show that quantum Otto engines that operate with nonlinear qubits significantly outperform linear engines. To this end, we develop a comprehensive thermodynamic description of nonlinear qubits, starting with identifying the proper thermodynamic equilibrium state. We then show that for ideal cycles as well as at maximum power the efficiency of the nonlinear engine is significantly higher. Interestingly, nonlinear dynamics can be thought of as an effective description of a correlated, complex quantum many-body system. Hence, our findings corroborate common wisdom, while at the same time propose a design of more efficient quantum engines.

DOI
10.1103/6lhx-byxy

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What are the resources that can be leveraged for a thermodynamic device to exhibit genuine quantum advantage? Typically, the answer to this question is sought in quantum correlations. In the present work, we show that quantum Otto engines that operate with nonlinear qubits significantly outperform linear engines. To this end, we develop a comprehensive thermodynamic description of nonlinear qubits, starting with identifying the proper thermodynamic equilibrium state. We then show that for ideal cycles as well as at maximum power the efficiency of the nonlinear engine is significantly higher. Interestingly, nonlinear dynamics can be thought of as an effective description of a correlated, complex quantum many-body system. Hence, our findings corroborate common wisdom, while at the same time propose a design of more efficient quantum engines.
Abstract This paper presents an analysis of quantum Otto heat engines operating in non-equilibrium. It explores the fundamental thermodynamic principles that govern these engines, focusing on efficiency, work output, and the impact of environmental factors such as thermal gradients, external fields, noise, and decoherence. The study investigates the effects of non-equilibrium conditions on engine performance, highlighting challenges and opportunities in practical realizations. Through numerical simulations, the article examines the power, efficiency, and performance coefficients, revealing trade-offs between these metrics and the influence of temperature differences and internal coupling strength. The results demonstrate that non-equilibrium effects can significantly reduce efficiency compared to ideal scenarios, emphasizing the importance of considering both quantum effects and real-world limitations in the design and optimization of quantum heat engines. This work contributes to the growing body of knowledge in quantum thermodynamics, offering insights for quantum computing, sustainable energy technologies, and thermodynamic cycles at the quantum scale.
This paper presents an analysis of quantum Otto heat engines operating out of equilibrium. It explores the fundamental thermodynamic principles governing these engines, focusing on efficiency, work output, and the impact of environmental factors, including thermal gradients, external fields, noise, and decoherence. The study investigates the effects of non-equilibrium conditions on engine performance, highlighting challenges and opportunities in practical realizations. Through numerical simulations, the article examines the power, efficiency, and performance coefficients, revealing trade-offs between these metrics and the influence of temperature differences and internal coupling strength. The results demonstrate that non-equilibrium effects can significantly reduce efficiency compared to idealized scenarios, underscoring the importance of accounting for both quantum effects and real-world constraints in the design and optimization of quantum heat engines. This work contributes to the growing body of knowledge in quantum thermodynamics, offering insights for quantum computing, sustainable energy technologies, and thermodynamic cycles at the quantum scale.
The quantum heat engines have drawn much attention due to miniaturization of devices recently. We study the dynamics of the quantum Otto heat engine using the driven-dissipative Schrödinger equation. Starting from different initial states, we simulate the time evolutions of the internal energy, power and heat-work conversion efficiency. The initial state impacts on these thermodynamic quantities before the Otto cycle reaches stable. In the transition period, the efficiency and power may be higher or lower than the corresponding values in the cyclostationary state. Remarkably, the efficiency could surpass the Otto limit and even the Carnot limit and the power could be much higher than the rated power. The efficiency anomaly is due to the energy in the initial state. Thus, we suggest that periodically pumping could take the similar role of a hot bath but could be manipulated flexibly. Furthermore, we propose a new quantum engine working in a single reservoir to convert the pump energy into mechanical work. This manipulative engine could potentially be applied to working in the microenvironments without a large temperature difference, such as the biological tissues in vivo. Our protocol is expected to model a new quantum engine with the advantage of applicability and controllability.
Abstract A key focus of designing quantum thermal devices is the potential advantage that can be gleaned from genuine quantum effects when compared to classical devices. The recent experimental realization of the Pauli engine (Koch et al 2023 Nature 621 723)—where energy is extracted via changes in particle statistics as an alternative to conventional heat sources—has opened new avenues of research where quantum statistics can be considered as a thermodynamic resource. In this work we propose hybrid quantum heat engines which can utilize additional strokes that change the single particle statistics between bosonic and fermionic descriptions during the cycle. To accomplish this we consider the 1D Lieb–Liniger gas, in which the s-wave interactions can be tuned between the non-interacting and the hard-core limit, which are described by bosonic and fermionic statistics respectively. We show that by suitably choosing where to implement these statistical strokes during an Otto-like cycle in the quasi-static limit, the efficiency and work output can be significantly enhanced when compared to fully bosonic or fully fermionic engines. Furthermore, in the degenerate regime our engine can operate at the Carnot efficiency, due to the interplay between the different contributions of heat and work induced by the statistical strokes. Finally, we highlight how our thermodynamic cycles can realize other thermal operations, such as refrigerators, promising similar statistical enhancements for a wide range of temperatures.
While the emergent field of quantum thermodynamics has the potential to impact energy science, the performance of thermal machines is often classical. We ask whether quantum effects can boost the performance of a thermal machine to reach quantum supremacy, i.e., surpassing both the efficiency and power achieved in classical thermodynamics. To this end, we introduce a nonadiabatic quantum heat engine operating an Otto cycle with a many-particle working medium, consisting of an interacting Bose gas confined in a time-dependent harmonic trap. It is shown that thanks to the interplay of nonadiabatic and many-particle quantum effects, this thermal machine can outperform an ensemble of single-particle heat engines with same resources, demonstrating the quantum supremacy of many-particle thermal machines.
In this chapter, we examine how quantum coherence affects the effectiveness and performance of quantum Otto engines running in nonequilibrium conditions. Energy conversion on a quantum scale can be understood through the use of quantum Otto engines, which employ cyclic thermodynamic processes involving isochoric and adiabatic transformations. We examine how the ability to extract work from thermal reservoirs at different temperatures is impacted by preserving quantum coherence among the engine’s operating states. We investigate the dynamics of coherence under various nonequilibrium conditions and configurations, including changing temperatures and coupling strengths, using the Quantum Master Equation framework. According to our research, engines with improved quantum coherence perform noticeably better than their classical counterparts, allowing for higher efficiencies and more work extraction. We also explore optimization techniques and real-world applications for creating quantum heat engines that make use of coherence as a vital resource. The potential of coherent quantum states in powering next-generation energy systems is highlighted in this work, which connects theoretical developments in quantum thermodynamics with real-world applications.