We consider the qubit-qutrit model of self-contained quantum refrigerator and observe the quantum Mpemba effect in its cooling. In this system, the qutrit acts as the refrigerator while the qubit is to be cooled. The entire system is coupled to three bosonic heat baths, due to which the dynamics of the system is governed by a Gorini-Kossakowski-Sudarshan-Lindblad master equation. We investigate the Liouvillian that generates the dynamics of the system and find that it has a block diagonal form. The dynamics of each element of the system's density matrix can be determined by solving the dynamical equation of the corresponding block that contains it. We find that the steady state belongs to the block containing only the diagonal elements in the energy basis. We numerically solve for the steady state and investigate the steady-state cooling over a significant region of the parameter space. Moreover, we demonstrate the quantum Mpemba effect in the refrigerator: a Mpemba state obtained by applying a unitary on the equilibrium state of the system reaches the steady state faster than the equilibrium state, despite the Mpemba state being initially farther away from the steady state. The Mpemba state thus leads to an acceleration in cooling of the cold qubit. We also find that both local and global unitaries on the qubit-qutrit system can generate the Mpemba state. Finally, we study the effect of the system-bath couplings on the Mpemba effect.
We consider the qubit-qutrit model of self-contained quantum refrigerator and observe the quantum Mpemba effect in its cooling. In this system, the qutrit acts as the refrigerator while the qubit is to be cooled. The entire system is coupled to three bosonic heat baths, due to which the dynamics of the system is governed by a Gorini-Kossakowski-Sudarshan-Lindblad master equation. We investigate the Liouvillian that generates the dynamics of the system and find that it has a block diagonal form. The dynamics of each element of the system's density matrix can be determined by solving the dynamical equation of the corresponding block that contains it. We find that the steady state belongs to the block containing only the diagonal elements in the energy basis. We numerically solve for the steady state and investigate the steady-state cooling over a significant region of the parameter space. Moreover, we demonstrate the quantum Mpemba effect in the refrigerator: a Mpemba state obtained by applying a unitary on the equilibrium state of the system reaches the steady state faster than the equilibrium state, despite the Mpemba state being initially farther away from the steady state. The Mpemba state thus leads to an acceleration in cooling of the cold qubit. We also find that both local and global unitaries on the qubit-qutrit system can generate the Mpemba state. Finally, we study the effect of the system-bath couplings on the Mpemba effect.
The Mpemba effect, where a hotter system cools faster than a colder one under otherwise identical conditions, has been extensively studied in classical systems. In this work, we present the quantum analogue of the Mpemba effect using a dissipative qubit, which is referred to as the canonical quantum Mpemba effect. We demonstrate that, under the identical conditions, the relaxation dynamics of a qubit initialized in a thermal state with a higher temperature can be exponentially faster than those of a colder thermal state. Strikingly, this acceleration is determined solely by the initial temperature of the system, independent of other parameters. The relaxation is confirmed to be a genuine cooling process via the effective steady state temperature, mirroring its classical counterpart. Last, we propose a practical classical quantum hybrid algorithmic quantum circuit to realize this effect using superconducting qubits experimentally.
This thesis investigates the quantum Mpemba effect, where an initially hotter system cools down faster than an initially colder one. This was demonstrated in a qubit system coupled to two environments. A thermal state is chosen as the initial state and then left to freely equilibrate. It was shown that the initial thermal state can be chosen in a way to accelerate the resulting relaxation process. The Liouvillian dynamics were analyzed and, by eliminating the contribution of the slowest decaying eigenmode (SDM) corresponding to accelerated relaxation dynamics, the effect was demonstrated. All states with vanishing SDM contributions were considered and found to belong to a plane in the Bloch sphere corresponding to a reduced state space. A thermal state could be shown to exist in this subspace, which is the Mpemba state that relaxes the fastest. The numerical relaxation dynamics were computed and the accelerated behavior of the Mpemba state verified. The fidelity of the Mpemba state also exhibits a steeper decay, consistent with the faster-decaying modes. The results were found to only strongly affect the solution in regions close to the steady state.
Coherence is an inherently quantum property that deeply affects microscopic processes, including thermalization phenomena. A striking example is the quantum Mpemba effect (QME), in which a system can exhibit anomalous relaxation, thermalizing faster from a state initially farther from equilibrium than from one closer. Here, we experimentally investigate the genuine QME and observe how the dynamics of a spin-1/2 system interacting with a heat sink can be sped-up to equilibrium. The mechanism underlying this speed-up is uncovered through detailed analysis of the heat exchange process. Furthermore, we apply the QME in a quantum Otto refrigerator, thereby increasing its cooling power. This proof-of-concept experiment unveils new practical paths for improving quantum thermal tasks.
Quantum Mpemba effect occurs when a quantum system, residing far away from the steady state, relaxes faster than a relatively nearer state. We look for the presence of this highly counterintuitive effect in the relaxation dynamics of the operators within the open quantum system setting. Since the operators evolve under a non-trace preserving map, the trace distance of an operator is not a monotonically decaying function of time, unlike its quantum state counterpart. Consequently, the trace distance can not serve as a reliable measure for detecting the Mpemba effect in operator dynamics. We circumvent this problem by defining a \textit{dressed} distance between operators that decays monotonically with time, enabling a generalized framework to explore the Mpemba-like effect for operators. Applying the formalism to various open quantum system settings, we find that, interestingly, in the single qubit case, only accelerated relaxation of operators is possible, while genuine Mpemba-like effects emerge in higher-dimensional systems such as qutrits and beyond. Furthermore, we demonstrate the existence of Mpemba-like effects in nonlocal, non-equilibrium operators, such as current, in a double-quantum-dot setup. Our results, besides offering fundamental insight about the occurrence of the Mpemba-like effect under non-trace preserving dynamics, open avenues for new experimental studies where quicker relaxation of observables could be of significant interest.
We investigate the quantum Mpemba effect in the relaxation of open quantum systems whose effective dynamics is described by Davies maps. We introduce a class of unitary transformations constructed from permutation matrices that, when applied to an initial state, (i) suppress the slowest decaying modes of the nonunitary dynamics and (ii) maximize the state's distinguishability from the steady state. The first condition ensures exponentially faster convergence to equilibrium, while the second implies that a quantum system initially further from equilibrium can approach it more rapidly than one that starts closer. This protocol thus realizes a genuine Mpemba effect, and its simulation requires low computational effort. We prove that, for any initial state, there exists a permutation matrix that maximizes its distance from equilibrium with respect to a chosen information-theoretic distinguishability measure. We illustrate our findings for a two-level system, as well as for the nonunitary dynamics of the transverse-field Ising chain and the XXZ chain, each weakly coupled to a bosonic thermal bath. In these cases, the quantum Mpemba effect is demonstrated using the Hilbert-Schmidt distance, quantum relative entropy, and trace distance. Overall, our results provide a versatile framework for engineering a genuine quantum Mpemba effect in Markovian open quantum systems.
The quantum Mpemba effect concerns with anomalous relaxation of quantum states that evolves either under unitary or non-unitary dynamics. In the context of open quantum systems, while most studies focus on quantum states evolving under completely positive trace-presing dynamics described by the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) master equation, we demonstrate that an analogous effect can arise at the level of operators. In particular, we show that operators that evolves under the adjoint Liouvillian -- despite not being a trace-preserving map -- can still exhibit a genuine Mpemba effect. We derive general conditions under which this phenomenon can occur and validate our predictions for three different open quantum setups. Our results broaden the scope of the Mpemba effect in quantum systems and provide a framework for controlling the relaxation of physically relevant observables.