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arXiv:2505.17081 · Physical review. E

Lieb-Mattis ordering theorem of electronic energy levels in the thermodynamic limit

Manuel Calixto, Alberto Mayorgas, Julio Guerrero

Published Sep 1, 2025• 0 citations
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Abstract

The Lieb-Mattis theorem orders the lowest-energy states of total spin s of a system of P interacting fermions. We generalize these predictions to fermionic mixtures of P particles with more than N=2 spinor components or species in the thermodynamic limit P→∞. The lowest-energy state inside each permutation symmetry sector h, arising in the P-fold tensor product decomposition, is well approximated by a U(N) coherent (quasiclassical variational) state, especially in the limit P→∞. In particular, the ground state of the system belongs the most symmetric (dominant Young tableau h_{0}) configuration. We exemplify our construction with the N=3 level Lipkin-Meshkov-Glick model, with a previous motivation on pairing correlations and U(N)-invariant quantum Hall ferromagnets. In the limit P→∞, each lowest-energy state within each permutation symmetry sector h undergoes a quantum phase transition for a critical value λ_{c}(h) of the exchange coupling constant λ, depending on h. This generalizes standard quantum phase transitions and their phase diagrams corresponding to the ground state belonging to the most symmetric sector h_{0}.

DOI
10.1103/sdgd-lsfx

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The Lieb-Mattis theorem orders the lowest-energy states of total spin s of a system of P interacting fermions. We generalize these predictions to fermionic mixtures of P particles with more than N=2 spinor components or species in the thermodynamic limit P→∞. The lowest-energy state inside each permutation symmetry sector h, arising in the P-fold tensor product decomposition, is well approximated by a U(N) coherent (quasiclassical variational) state, especially in the limit P→∞. In particular, the ground state of the system belongs the most symmetric (dominant Young tableau h_{0}) configuration. We exemplify our construction with the N=3 level Lipkin-Meshkov-Glick model, with a previous motivation on pairing correlations and U(N)-invariant quantum Hall ferromagnets. In the limit P→∞, each lowest-energy state within each permutation symmetry sector h undergoes a quantum phase transition for a critical value λ_{c}(h) of the exchange coupling constant λ, depending on h. This generalizes standard quantum phase transitions and their phase diagrams corresponding to the ground state belonging to the most symmetric sector h_{0}.
Using the Lieb–Mattis ordering theorem of electronic energy levels, we identify the Hilbert space of the low energy sector of U(N) quantum Hall/Heisenberg ferromagnets at filling factor M for L Landau/lattice sites with the carrier space of irreducible representations of U(N) described by rectangular Young tableaux of M rows and L columns, and associated with Grassmannian phase spaces U(N)/U(M)×U(N−M). We embed this N-component fermion mixture in Fock space through a Schwinger–Jordan (boson and fermion) representation of U(N)-spin operators. We provide different realizations of basis vectors using Young diagrams, Gelfand–Tsetlin patterns and Fock states (for an electron/flux occupation number in the fermionic/bosonic representation). U(N)-spin operator matrix elements in the Gelfand–Tsetlin basis are explicitly given. Coherent state excitations above the ground state are computed and labeled by complex (N−M)×M matrix points Z on the Grassmannian phase space. They adopt the form of a U(N) displaced/rotated highest-weight vector, or a multinomial Bose–Einstein condensate in the flux occupation number representation. Replacing U(N)-spin operators by their expectation values in a Grassmannian coherent state allows for a semi-classical treatment of the low energy (long wavelength) U(N)-spin-wave coherent excitations (skyrmions) of U(N) quantum Hall ferromagnets in terms of Grasmannian nonlinear sigma models.
We introduce the notion of mixed symmetry quantum phase transition (MSQPT) as singularities in the transformation of the lowest-energy state properties of a system of identical particles inside each permutation symmetry sector μ, when some Hamiltonian control parameters λ are varied. We use a three-level Lipkin-Meshkov-Glick model, with U(3) dynamical symmetry, to exemplify our construction. After reviewing the construction of U(3) unitary irreducible representations using Young tableaux and the Gelfand basis, we first study the case of a finite number N of three-level atoms, showing that some precursors (fidelity susceptibility, level population, etc.) of MSQPTs appear in all permutation symmetry sectors. Using coherent (quasiclassical) states of U(3) as variational states, we compute the lowest-energy density for each sector μ in the thermodynamic N→∞ limit. Extending the control parameter space by μ, the phase diagram exhibits four distinct quantum phases in the λ-μ plane that coexist at a quadruple point. The ground state of the whole system belongs to the fully symmetric sector μ=1 and shows a fourfold degeneracy, due to the spontaneous breakdown of the parity symmetry of the Hamiltonian. The restoration of this discrete symmetry leads to the formation of four-component Schrödinger cat states.
Using the Lieb–Mattis ordering theorem of electronic energy levels, we identify and construct the Hilbert space of the low energy sector of U(N) quantum Hall/Heisenberg ferromagnets at filling factor M for L Landau/lattice sites. The carrier Hilbert space of irreducible representations of U(N) is described by rectangular Young tableaux of M rows and L columns, and associated with Grassmannian phase spaces U(N)/U(M)×U(N-M). Replacing U(N)-spin operators by their expectation values in a Grassmannian coherent state allows for a semi-classical treatment of the low energy U(N)-spin-wave coherent excitations (skyrmions) of U(N) quantum Hall ferromagnets in terms of Grasmannian nonlinear sigma models.
We prove the Lieb-Schultz-Mattis theorem on the energy spectrum of a general two- or three-dimensional quantum many-body system with the U(1) particle number conservation and translation symmetry. Especially, it is demonstrated that the theorem holds in a system with long-range interactions. To this end, we introduce approximate magnetic translation symmetry under the total magnetic flux Φ=2π instead of the exact translation symmetry, and explicitly construct low energy variational states. The energy spectrum at Φ=2π is shown to agree with that at Φ=0 in the thermodynamic limit, which concludes the Lieb-Schultz-Mattis theorem.
Based on the exact solution of one-dimensional Fermi gas systems with SUSUSU(N) symmetry in a hard wall, we demonstrate that we are able to sort the ordering of the lowest-energy eigenvalues of states with all allowed permutation symmetries, which can be solely marked by certain quantum numbers in the Bethe ansatz equations. Our results give examples beyond the scope of the generalized Lieb-Mattis theorem, which can only compare the ordering of energy levels of states belonging to different symmetry classes if they are comparable according to the pouring principle. In the strongly interacting regime, we show that the ordering of energy levels can be determined by an effective spin-exchange model, and we extend our results to a nonuniform system trapped in a harmonic potential.
The Lieb-Mattis theorem on the antiferromagnetic ordering of energy levels is generalized to SU (N ) extended Hubbard model with Heisenberg exchange and pair-hopping terms.It is proved that the minimum energy levels among the states from equivalent representations are nondegenerate and ordered according to the dominance order of corresponding Young diagrams.In particular, the ground states form a unique antisymmetric multiplet.The relation with the similar ordering among the spatial wavefunctions with different symmetry classes of ordinary quantum mechanics is discussed also.