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arXiv:2503.02928 · Physical Review Letters

Finite-Temperature Quantum Topological Order in Three Dimensions

Shu-Tong Zhou, Meng Cheng, Tibor Rakovszky, Curt W. von Keyserlingk, Tyler D. Ellison

Published Jul 1, 2025• 8 citations

Abstract

We identify a three-dimensional system that exhibits long-range entanglement at sufficiently small but nonzero temperature-it therefore constitutes a quantum topological order at finite temperature. The model of interest is known as the fermionic toric code, a variant of the usual 3D toric code, which admits emergent fermionic pointlike excitations. The fermionic toric code, importantly, possesses an anomalous two-form symmetry, associated with the spacelike Wilson loops of the fermionic excitations. We argue that it is this symmetry that imbues low-temperature thermal states with a novel topological order and long-range entanglement. Based on the current classification of three-dimensional topological orders, we expect that the low-temperature thermal states of the fermionic toric code belong to a phase of matter that, in the context of equilibrium phases of matter, only exists at nonzero temperatures. We conjecture that further examples of topological orders at nonzero temperatures are given by discrete gauge theories with anomalous two-form symmetries. Our Letter therefore opens the door to studying quantum topological order at nonzero temperature in physically realistic dimensions.

DOI: 10.1103/n9sq-8cxw

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We identify a three-dimensional system that exhibits long-range entanglement at sufficiently small but nonzero temperature-it therefore constitutes a quantum topological order at finite temperature. The model of interest is known as the fermionic toric code, a variant of the usual 3D toric code, which admits emergent fermionic pointlike excitations. The fermionic toric code, importantly, possesses an anomalous two-form symmetry, associated with the spacelike Wilson loops of the fermionic excitations. We argue that it is this symmetry that imbues low-temperature thermal states with a novel topological order and long-range entanglement. Based on the current classification of three-dimensional topological orders, we expect that the low-temperature thermal states of the fermionic toric code belong to a phase of matter that, in the context of equilibrium phases of matter, only exists at nonzero temperatures. We conjecture that further examples of topological orders at nonzero temperatures are given by discrete gauge theories with anomalous two-form symmetries. Our Letter therefore opens the door to studying quantum topological order at nonzero temperature in physically realistic dimensions.

We introduce two-dimensional toric code models with additional long-range loop interactions. Our models preserve the topologically ordered ground states of the ordinary toric code, while confining anyons at zero temperature. For sufficiently long-ranged interactions, we argue that this confinement persists at finite temperatures, strongly constraining anyon mobility and giving rise to finite-temperature topological order. This topological phase acts as a self-correcting quantum memory and exhibits long-range entanglement. For shorter-ranged interactions, signatures of topological order survive only up to an exponentially large length scale at finite temperature, yielding a partially self-correcting quantum memory.

We propose a diagnostic for finite temperature topological order using "topological entanglement negativity," the long-range component of a mixed-state entanglement measure. As a demonstration, we study the toric code model in d spatial dimensions for d=2,3,4, and find that when topological order survives thermal fluctuations, it possesses a nonzero topological entanglement negativity, whose value is equal to the topological entanglement entropy at zero temperature. Furthermore, we show that the Gibbs state of 2D and 3D toric code at any nonzero temperature, and that of 4D toric code above a certain critical temperature, can be expressed as a convex combination of short-range entangled pure states, consistent with the absence of topological order.

We construct a tensor network representation of the three-dimensional (3D) toric code ground state that is stable to a generating set of uniform local tensor perturbations, including those that do not map to local operators on the physical Hilbert space. The stability is established by mapping the phase diagram of the perturbed tensor network to that of the 3D Ising gauge theory, which has a nonzero finite temperature transition. More generally, we find that the stability of a topological tensor network state is determined by the form of its virtual symmetries and the topological excitations created by virtual operators that break those symmetries. In particular, a dual representation of the 3D toric code ground state, as well as representations of the

X

-cube and cubic code ground states, for which pointlike excitations are created by such operators, are found to be unstable.

We address the question of whether symmetry-protected topological (SPT) order can persist at nonzero temperature, with a focus on understanding the thermal stability of several models studied in the theory of quantum computation. We present three results in this direction. First, we prove that nontrivial SPT order protected by a global onsite symmetry cannot persist at nonzero temperature, demonstrating that several quantum computational structures protected by such onsite symmetries are not thermally stable. Second, we prove that the three-dimensional (3D) cluster-state model used in the formulation of topological measurement-based quantum computation possesses a nontrivial SPT-ordered thermal phase when protected by a generalized (1-form) symmetry. The SPT order in this model is detected by long-range localizable entanglement in the thermal state, which compares with related results characterizing SPT order at zero temperature in spin chains using localizable entanglement as an order parameter. Our third result is to demonstrate that the high-error tolerance of this 3D cluster-state model for quantum computation, even without a protecting symmetry, can be understood as an application of quantum error correction to effectively enforce a 1-form symmetry.

We demonstrate that multipartite entanglement, witnessed by the quantum Fisher information, can characterize topological quantum phase transitions in the spin-

\frac{1}{2}

toric code model (TCM) on a square lattice with external fields. We show that the quantum Fisher information density of the ground state can be written in terms of the expectation values of gauge-invariant Wilson loops for different sizes of square regions and identify

{\mathbb{Z}}_{2}

topological order by its scaling behavior. Furthermore, we use this multipartite entanglement witness to investigate thermalization and disorder-assisted stabilization of topological order after a quantum quench. Moreover, with an upper bound of the quantum Fisher information, we demonstrate the absence of finite-temperature topological order in the two-dimensional TCM in the thermodynamic limit. Our results provide insights to topological phases, which are robust against external disturbances and are candidates for topologically protected quantum computation.

Symmetry Fractionalization in Three-Dimensional

\mathbb{Z}_2

Topological Order and Fermionic Symmetry-Protected Phases

In two-dimensional topological phases, quasiparticle excitations can carry fractional symmetry quantum numbers. We generalize this notion of symmetry fractionalization to three-dimensional topological phases, in particular to loop excitations, and propose a partial classification for symmetry-enriched

\mathbb{Z}_2

toric code phase. We apply the results to the classification of fermionic symmetry-protected topological phases in three dimensions.