We systematically derive the quantum generalized nonlinear Langevin equation using Morozov's projection operator method. This approach extends the linear Mori-Zwanzig projection operator technique, allowing for the inclusion of nonlinear interactions among macroscopic modes. Additionally, we obtain the quantum generalized Fokker-Planck equation within the Heisenberg picture, which is consistent with Morozov's original formulation. These equations are fundamentally significant in nonequilibrium statistical physics, particularly in scenarios characterized by enhanced fluctuations, such as anomalous transport phenomena near critical points. The quantum nature of the derived generalized Langevin and Fokker-Planck equations is anticipated to provide a more detailed description than their classical equivalents. Specifically, the noise kernel in the quantum generalized Langevin equation is multiplicative, which broadens the applicability beyond Gaussian approximations. Given specific interactions, these equations are expected to be instrumental in investigating critical transport phenomena.
The structure of the projection-operator theory of Mori for quantum Brownian motion is reconsidered, emphasizing the nature of underlying quantum processes. Quantum-mechanical assumptions of the theory are extracted to sets of axioms. The Hilbert space scrV formed with relevant observables for quantum generalized Langevin equations (QGLE's) includes, in general, elements that cannot be operators on state vectors of the original system. The definition of Liouville operator L, as a mapping from one operator to another, thus requires its reconstruction in scrV. The work shows that the mentioned axioms not only ensure a unified reconstruction of L (hence of QGLE's) in systems in stationary states that may be nonequilibrium as well as equilibrium, but also extend intrinsically the domain of applicability of QGLE's. Illustrations of the setting for these extended QGLE's are presented by concrete examples of Hilbert spaces formed with quantum-mechanical Gaussian and non-Gaussian random variables, showing specifically the significance of a response-function-type inner product that assigns \ensuremath{\delta} correlation to the quantized Gaussian white noise which is an operator-valued distributional process with Kubo-Martin-Schwinger property.
We first point out that nonrelativistic quantum mechanics formulated at imaginary time s = it can formally be recognized as the Fokker-Planck description of a classical Brownian motion, which occurs (in general) in a medium where particles are absorbed and emitted. We next offer a new formulation of quantum dynamics, which is basically the Langevin treatment of that Brownian motion. More explicitly, we derive a noise average representation of the transition probability W ( X", s"|X', s' ) in terms of the solutions to a Langevin equation with a Gaussian white noise. Upon analytic continuation back to real time W ( X", s"|X', s' ) becomes the propagator of the original Schrödinger equation, namely we have ⟨ X", t"|X', t' ⟩ = W ( X", it"|X', it' ). The main advantage of this approach is to permit a systematic application to quantum-dynamical problems of the mathematical techniques developed in the theory of classical stochastic processes, even when vector potentials and/or time-dependent potentials are present.
A quantum mechanical form of the Langevin equation is derived from an explicit consideration of the molecule-medium interaction, as advocated by Simons in 1978, and by using two identities in the interaction picture. This can be easily reduced to the classical regime, and further simplified to the macroscopic Langevin equation by considering the stochastic Langevin force autocorrelation function. One of the so-called Einstein relations appears as a byproduct. By following the methodology proposed by Simons, an exact expression for the momentum autocorrelation function is obtained. The latter can be used to calculate the zero-frequency macroscopic diffusion coefficient that is observed to satisfy the second Einstein relation. The formalism described above gives rise to the possibility of explicitly computing the transport characteristics such as friction constant and diffusion coefficient from the corresponding quantum statistical mechanical expressions. A discussion on the Langevin equation becomes complete only when the corresponding Fokker-Planck equation is obtained. Therefore, the probability of the evolution of states with a particular absolute magnitude of linear momentum from those of another momentum eigenvalue is quantum mechanically defined. This probability appears as a special average value of a projection operator and as a special projection operator correlation function. A classical identity is introduced that is shown to be valid also for the quantum mechanically defined probability function. By using this identity, the so-called Fokker-Planck equation for the evolution probability is easily established.
Building upon the work of Hu, Paz, and Zhang [1,2] on open quantum systems we consider the quantum Brownian motion (QBM) model with one oscillator (position variable
x) as the system, {\it nonlinearly} coupled to an environment of
N harmonic oscillators (with mass
mn, natural frequency
ωn, position
qn and momentum
pn variables) in the form
∑n(vn1(x)qnk+vn2(x)pnl) where
k,l are integers (the present work only considers the
k=l=2 cases). The vertex functions $v_{n1}, v_{n2} $ are of the form
vn1=λCn1f(x),vn2(x)=−λCn2mn−2ωn−2f(x) where
Cn1,2 are the coupling constants with the
nth oscillator,
f(x) is any arbitrary function of
x, and
λ is a dimensionless constant. Employing the closed-time-path formalism the influence action
SIF is calculated using a perturbative expansion in
λ. It is possible to identify the terms in
SIF quadratic or higher in
Δ(s)≡f(x+(s))−f(x−(s)) to constitute the noise kernel, while terms linear in
Δ to that of the dissipation kernel. The non-Gaussian noise kernel gives rise to non-zero three-point correlation function of the corresponding stochastic force. The pathway presented here should be useful for the exploration of \textit{non-Gaussian properties of systems nonlinearly coupled with their environments}; examples in early universe cosmology and in quantum optomechanics (QOM) are mentioned. A modified fluctuation-dissipation relation (FDR) is also established, which ensures the consistency of the model and the accuracy of results even at higher perturbative orders. Another result of significance is the derivation of a nonlinear Langevin equation which is expected to be useful for many open quantum system applications.
We apply the projection operator method (POM) to ϕ4 theory and derive both quantum and semiclassical equations of motion for the soft modes. These equations have no time-convolution integral term, in sharp contrast with other well-known results obtained using the influence functional method (IFM) and the closed time path method (CTP). However, except for the fluctuation force field terms, these equations are similar to the corresponding equations obtained using IFM with the linear harmonic approximation, which was introduced to remove the time-convolution integral. The quantum equation of motion in POM can be regarded as a kind of quantum Langevin equation in which the fluctuation force field is given in terms of the operators of the hard modes. These operators are then replaced with c-numbers using a certain procedure to obtain a semiclassical Langevin equation. It is pointed out that there are significant differences between the fluctuation force fields introduced in this paper and those introduced in IFM. The arbitrariness of the definition of the fluctuation force field in IFM is also discussed.