With the approaching second quantum revolution, the study of quantum thermodynamics, particularly heat flow, has become even more relevant for two main reasons. First, understanding heat and other types of noise is essential for protecting quantum information and preventing decoherence. Second, the ability to manufacture and control quantum systems developed for the quantum computer allows for experimental study of quantum thermodynamics in entirely new settings. In this thesis, several systems involving quantum systems in contact with baths are studied theoretically in experimentally available settings. First, two rectification or diode setups for heat currents are proposed using a dark-state mechanism. In one system, the dark-state mechanism is imperfect but very robust. In the other system, the dark-state mechanism relies on quantum entanglement and is much better but more fragile towards decoherence. Next, a quantum version of the Wheatstone bridge is built using the same entanglement-powered dark state mechanism. After having studied several boundary-driven quantum systems, the lessons learned are generalized into resonance conditions using a general linear chain of weakly interacting chains of strongly interacting spins. The final two chapters focus on the ability to study statistical physics in realizable quantum systems. First, a Maxwell's demon setup is proposed. A demon-controlled qutrit is coupled to two non-Markovian baths. The information back-flow from the non-Markovian baths allows the demon to more effectively transfer heat from the cold bath to the hot bath. Second, the Mott insulator to superfluid phase transition in a lattice of transmons is examined. The ground state has a variable particle number and is prepared using adiabatic state preparation. This allows for the exploration of the entire phase diagram.
With the approaching second quantum revolution, the study of quantum thermodynamics, particularly heat flow, has become even more relevant for two main reasons. First, understanding heat and other types of noise is essential for protecting quantum information and preventing decoherence. Second, the ability to manufacture and control quantum systems developed for the quantum computer allows for experimental study of quantum thermodynamics in entirely new settings. In this thesis, several systems involving quantum systems in contact with baths are studied theoretically in experimentally available settings. First, two rectification or diode setups for heat currents are proposed using a dark-state mechanism. In one system, the dark-state mechanism is imperfect but very robust. In the other system, the dark-state mechanism relies on quantum entanglement and is much better but more fragile towards decoherence. Next, a quantum version of the Wheatstone bridge is built using the same entanglement-powered dark state mechanism. After having studied several boundary-driven quantum systems, the lessons learned are generalized into resonance conditions using a general linear chain of weakly interacting chains of strongly interacting spins. The final two chapters focus on the ability to study statistical physics in realizable quantum systems. First, a Maxwell's demon setup is proposed. A demon-controlled qutrit is coupled to two non-Markovian baths. The information back-flow from the non-Markovian baths allows the demon to more effectively transfer heat from the cold bath to the hot bath. Second, the Mott insulator to superfluid phase transition in a lattice of transmons is examined. The ground state has a variable particle number and is prepared using adiabatic state preparation. This allows for the exploration of the entire phase diagram.
We now turn to the subject of thermodynamics, and to describing the process of thermalization of quantum systems. A quantum system that interacts with another system large enough to obey the usual rules of thermodynamics, is referred to as an open system. The thermal system with which it interacts is often referred to as a thermal bath , or simply as the environment. We will use these terms interchangeably. Modeling the behavior of open quantum systems has many applications. One of these is to model the noise that they are subjected to by their surroundings, noise that we will wish to control using measurement and feedback loops in Chapter 5. There are also two important connections between quantum measurements, information theory, and thermodynamics. The first of these is that the thermodynamic entropy of a macroscopic system can be identified with the information-theoretic entropy that characterizes the lack of knowledge of an observer about the microstates of the system. In turn, if an observer is allowed to make microscopic measurements on the system, then this modifies the thermodynamic rules regarding the conversion of heat to work. Such is the subject of Maxwell’s demon. Curiously it took more than a century to understand how Maxwell’s demon, essentially a microscopic measurement and feedback process, fits within the second law of thermodynamics. In another twist, it turns out that the process of erasing information requires an increase in the thermodynamic entropy of the environment, and this increase is directly related to the amount of information erased.
To understand in detail the relation between unitary quantum theory that describes our world at the microscopic scale and thermodynamics, which was long believed only to apply to macroscopic objects, is one of the most interesting and long-standing problems in physics. Recently, this problem has received renewed attention, in particular from the community of quantum information theory, but also from the field of statistical mechanics, inspired from stochastic thermodynamics. These results suggest that thermodynamics is also relevant for individual quantum systems, provided that they can be brought into contact with thermal baths. In this thesis, I use recently developed tools to provide new results both on fundamental questions, but also on questions which are of practical relevance for potential miniaturized thermal machines. In terms of fundamental questions, the results in this thesis contribute to understanding how the basic laws of thermodynamics and statistical mechanics can be understood directly from unitary quantum mechanics. In particular, I discuss and answer the following questions: i) How can we quantify the third law of thermodynamics using information theoretic methods? ii) How can we quantify the "thermodynamic value" of a state-transition in quantum systems? iii) How can we axiomatically characterize the non-equilibrium free energy and relative entropy? iv) How can we justify statistical ensembles from an operational perspective, without having to introduce either some probability measures or an information theoretic entropy measure? v) How can we understand the equilibration of closed quantum systems, how long does it take and how difficult is it to avoid? In the second part of the thesis I discuss in detail how experimental restrictions, which become important at the quantum scale, influence the ultimate thermodynamic bounds for thermal machines. In particular, the results in this thesis provide thermodynamic bounds on work-extraction and efficiencies of thermal machines in situations where 1.) an experimenter only has limited field strengths available, 2.) an experimenter cannot control the interactions between particles, but external fields arbitrarily well, and 3.) situations in which a small quantum system can only be strongly coupled to heat baths. These bounds are tight and I provide explicit examples illustrating the different behaviours. Finally, I come back to a classic problem in statistical physics: The emergence of spontaneous symmetry breaking. Here, I provide general and rigorous new results that show how symmetry-breaking stationary states emerge from fluctuations in order parameters in dissipative lattice models.
Recent developments in experimental methods allow for the study of thermodynamic properties of quantum systems. In quantum integrated circuits, quantum systems are elements in an electric circuit that can straightforwardly be coupled to other elements. This manipulability allows one to construct quantum heat engines, Maxwell demons etc. Quantum integrated circuits also are one of the main potential settings to realise a working quantum computer. Calorimetric measurements in integrated circuits serve as a promising technique to probe thermodynamic laws of the quantum regime and to study the inner workings of quantum devices. Due to this experimental accessibility, the theoretical study of open quantum systems in the context of quantum integrated circuits is highly relevant. Open quantum systems are typically small systems, e.g. qubits or oscillators, in contact with one or more reservoirs. The research on which this thesis is based can roughly be divided into two parts. The first part is concerned with the thermodynamics of a driven qubit in contact with a thermal bath. This system is the archetype of a quantum out-ofequilibrium system. In one case the qubit is strongly driven by a semiclassical driving field. Building on earlier works, the thermodynamic relations of the system are found by proving the equivalence with an easier to study qubit-oscillator system. In the other, case the qubit is driven by being in contact with two baths with a temperature gradient. The full generating function is derived in a proper approximative scheme and a fluctuation-dissipation relation is found. The second part focusses on a specific experimental scheme to perform calorimetric measurements. The scheme relies on coupling a quantum system to a finite reservoir and performing fast temperature measurements on the reservoir. Doing so allows one to infer energy changes in the reservoir and therefore to obtain the heat exchanged with the system. The dynamics of this system are modelled for weak system-reservoir coupling and concrete experimental predictions are made. In new work, the dynamics for a toy model of a system interacting with a finite reservoir are derived from first principles for a specific model. The first principle derivation matches with the earlier modelled dynamics in the weak coupling and allows to consider strong system-reservoir coupling as well.
Quantum dissipation has been the object of study within the physics and chemistry communities for many years. Despite this, the field is in constant evolution, largely due to the fact that novel systems where the understanding of dissipation and dephasing processes is of crucial importance have become experimentally accessible in recent years. Among the ongoing research themes, we mention the defeat of decoherence in solid state-based quantum bits (qubits) (e.g. superconducting qubits or quantum dot based qubits), or dissipation due to non-equilibrium Fermi reservoirs, as is the case for quantum transport through meso- and nanoscale structures. A close inspection of dissipation in such systems reveals that one has to deal with 'unconventional' environments, where common assumptions of, for example, linearity of the bath and/or equilibrium reservoir have to be abandoned. Even for linear baths at equilibrium it might occur that the bath presents some internal structure, due, for example, to the presence of localized bath modes. A large part of this focus issue is devoted to topics related to the rapidly developing fields of quantum computation and information with solid state nanodevices. In these implementations, single and two-qubit gates as well as quantum information transmission takes place in the presence of broadband noise that is typically non-Markovian and nonlinear. On both the experimental and theory side, understanding and defeating such noise sources has become a crucial step towards the implementation of efficient nanodevices. On a more fundamental level, electron and spin transport through quantum dot nanostructures may suffer from 'unconventional' dissipation mechanisms such as the simultaneous presence of spin relaxation and fermionic dissipation, or may represent themselves out of equilibrium baths for nearby mesoscopic systems. Finally, although not expected from the outset, the present collection of articles has revealed that different 'unconventional' questions were still open on the standard harmonic oscillator and spin baths. This includes both fundamental issues, such as the possibility of estimating the specific heat for a free particle in the presence of dissipation, and the development of methods suitable to dealing with long range correlations at zero temperature and with quantum chaotic environments. We believe that the present focus issue on Quantum Dissipation in Unconventional Environments , although certainly not exhaustive, provides an important open-access resource that presents the latest state of the art of research in this field along its different lines. Focus on Quantum Dissipation in Unconventional Environments Contents Coherent control of an effective two-level system in a non-Markovian biomolecular environment J Eckel, J H Reina and M Thorwart Charge transfer dynamics in driven molecular ratchets: quantum Monte Carlo results and rate models L Mühlbacher and J Ankerhold Decoherence in qubits due to low-frequency noise J Bergli, Y M Galperin and B L Altshuler Dephasing by electron–electron interactions in a ballistic Mach–Zehnder interferometer Clemens Neuenhahn and Florian Marquardt Quantum frustration of dissipation by a spin bath D D Bhaktavatsala Rao, Heiner Kohler and Fernando Sols A random matrix theory of decoherence T Gorin, C Pineda, H Kohler and T H Seligman Dissipative dynamics of a biased qubit coupled to a harmonic oscillator: analytical results beyond the rotating wave approximation Johannes Hausinger and Milena Grifoni Dissipative dynamics of a two-level system resonantly coupled to a harmonic mode Frederico Brito and Amir O Caldeira Spin correlations in spin blockade Rafael Sánchez, Sigmund Kohler and Gloria Platero Landau–Zener tunnelling in dissipative circuit QED David Zueco, Peter Hänggi and Sigmund Kohler Quantum oscillations in the spin-boson model: reduced visibility from non-Markovian effects and initial entanglement F K Wilhelm Dynamics of dissipative coupled spins: decoherence, relaxation and effects of a spin-boson bath P Nägele, G Campagnano and U Weiss Spin chain model for correlated quantum channels Davide Rossini, Vittorio Giovannetti and Simone Montangero Finite quantum dissipation: the challenge of obtaining specific heat Peter Hänggi, Gert-Ludwig Ingold and Peter Talkner Dynamics of large anisotropic spin in a sub-ohmic dissipative environment close to a quantum-phase transition Frithjof B Anders Effects of low-frequency noise cross-correlations in coupled superconducting qubits A D'Arrigo, A Mastellone, E Paladino and G Falci From coherent motion to localization: dynamics of the spin-boson model at zero temperature Haobin Wang and Michael Thoss Phonon distributions of a single-bath mode coupled to a quantum dot F Cavaliere, G Piovano, E Paladino and M Sassetti
Maxwell's demon is the quintessential example of information control, which is necessary for designing quantum devices. In thermodynamics, the demon is an intelligent being who utilizes the entropic nature of information to sort excitations between reservoirs thus lowering the total entropy. So far, implementations of Maxwell's demon have largely been limited to Markovian baths. In our work, we study the degree to which such a demon may be assisted by non-Markovian effects using a superconducting circuit platform. The setup is two baths connected by a demon controlled qutrit interface, allowing the transfer of excitations only if the overall entropy of the two baths is lowered. Importantly, we show that non-Markovian effects yield the largest entropy reduction through appropriate timing of the demon operation. Our results demonstrate that non-Markovian effects can be exploited to boost the information transfer rate in quantum Maxwell demons.
Maxwell's demon is the quintessential example of information control, which is necessary for designing quantum devices. In thermodynamics, the demon is an intelligent being who utilizes the entropic nature of information to sort excitations between reservoirs, thus lowering the total entropy. So far, implementations of Maxwell's demon have largely been limited to Markovian baths. In our work, we study the degree to which such a demon may be assisted by non-Markovian effects using a superconducting circuit platform. The setup is two baths connected by a demon-controlled qutrit interface, allowing the transfer of excitations only if the overall entropy of the two baths is lowered. The largest entropy reduction is achieved in a non-Markovian regime and, importantly, due to non-Markovian effects, the demon performance can be optimized through proper timing. Our results demonstrate that non-Markovian effects can be exploited to boost the information transfer rate in quantum Maxwell demons.