Recent developments in experimental methods allow for the study of thermodynamic properties of quantum systems. In quantum integrated circuits, quantum systems are elements in an electric circuit that can straightforwardly be coupled to other elements. This manipulability allows one to construct quantum heat engines, Maxwell demons etc. Quantum integrated circuits also are one of the main potential settings to realise a working quantum computer. Calorimetric measurements in integrated circuits serve as a promising technique to probe thermodynamic laws of the quantum regime and to study the inner workings of quantum devices. Due to this experimental accessibility, the theoretical study of open quantum systems in the context of quantum integrated circuits is highly relevant. Open quantum systems are typically small systems, e.g. qubits or oscillators, in contact with one or more reservoirs. The research on which this thesis is based can roughly be divided into two parts. The first part is concerned with the thermodynamics of a driven qubit in contact with a thermal bath. This system is the archetype of a quantum out-ofequilibrium system. In one case the qubit is strongly driven by a semiclassical driving field. Building on earlier works, the thermodynamic relations of the system are found by proving the equivalence with an easier to study qubit-oscillator system. In the other, case the qubit is driven by being in contact with two baths with a temperature gradient. The full generating function is derived in a proper approximative scheme and a fluctuation-dissipation relation is found. The second part focusses on a specific experimental scheme to perform calorimetric measurements. The scheme relies on coupling a quantum system to a finite reservoir and performing fast temperature measurements on the reservoir. Doing so allows one to infer energy changes in the reservoir and therefore to obtain the heat exchanged with the system. The dynamics of this system are modelled for weak system-reservoir coupling and concrete experimental predictions are made. In new work, the dynamics for a toy model of a system interacting with a finite reservoir are derived from first principles for a specific model. The first principle derivation matches with the earlier modelled dynamics in the weak coupling and allows to consider strong system-reservoir coupling as well.
Recent developments in experimental methods allow for the study of thermodynamic properties of quantum systems. In quantum integrated circuits, quantum systems are elements in an electric circuit that can straightforwardly be coupled to other elements. This manipulability allows one to construct quantum heat engines, Maxwell demons etc. Quantum integrated circuits also are one of the main potential settings to realise a working quantum computer. Calorimetric measurements in integrated circuits serve as a promising technique to probe thermodynamic laws of the quantum regime and to study the inner workings of quantum devices. Due to this experimental accessibility, the theoretical study of open quantum systems in the context of quantum integrated circuits is highly relevant. Open quantum systems are typically small systems, e.g. qubits or oscillators, in contact with one or more reservoirs. The research on which this thesis is based can roughly be divided into two parts. The first part is concerned with the thermodynamics of a driven qubit in contact with a thermal bath. This system is the archetype of a quantum out-ofequilibrium system. In one case the qubit is strongly driven by a semiclassical driving field. Building on earlier works, the thermodynamic relations of the system are found by proving the equivalence with an easier to study qubit-oscillator system. In the other, case the qubit is driven by being in contact with two baths with a temperature gradient. The full generating function is derived in a proper approximative scheme and a fluctuation-dissipation relation is found. The second part focusses on a specific experimental scheme to perform calorimetric measurements. The scheme relies on coupling a quantum system to a finite reservoir and performing fast temperature measurements on the reservoir. Doing so allows one to infer energy changes in the reservoir and therefore to obtain the heat exchanged with the system. The dynamics of this system are modelled for weak system-reservoir coupling and concrete experimental predictions are made. In new work, the dynamics for a toy model of a system interacting with a finite reservoir are derived from first principles for a specific model. The first principle derivation matches with the earlier modelled dynamics in the weak coupling and allows to consider strong system-reservoir coupling as well.
Ongoing experimental activity aims at calorimetric measurements of thermodynamic indicators of quantum integrated systems. We study a model of a driven qubit in contact with a finite-size thermal electron reservoir. The temperature of the reservoir changes due to energy exchanges with the qubit and an infinite-size phonon bath. Under the assumption of weak coupling and weak driving, we model the evolution of the qubit-electron temperature as a hybrid master equation for the density matrix of the qubit at different temperatures of the calorimeter. We compare the temperature evolution with an earlier treatment of the qubit-electron model, where the dynamics were modeled by a Floquet master equation under the assumption of drive intensity much larger than the qubit-electron coupling squared. We numerically and analytically investigate the predictions of the two mathematical models of dynamics in the weak-drive parametric region. We numerically determine the parametric regions where the two models of dynamics give distinct temperature predictions and those where their predictions match.
We investigate the experimental setup proposed in New J. Phys. 15, 115006 (2013) for calorimetric measurements of thermodynamic indicators in an open quantum system. As a theoretical model we consider a periodically driven qubit coupled with a large yet finite electron reservoir, the calorimeter. The calorimeter is initially at equilibrium with an infinite phonon bath. As time elapses, the temperature of the calorimeter varies in consequence of energy exchanges with the qubit and the phonon bath. We show how under weak-coupling assumptions, the evolution of the qubit-calorimeter system can be described by a generalized quantum jump process including as dynamical variable the temperature of the calorimeter. We study the jump process by numeric and analytic methods. Asymptotically with the duration of the drive, the qubit-calorimeter attains a steady state. In this same limit, we use multiscale perturbation theory to derive a Fokker-Planck equation governing the calorimeter temperature distribution. We inquire the properties of the temperature probability distribution close and at the steady state. In particular, we predict the behavior of measurable statistical indicators versus the qubit-calorimeter coupling constant.
Superconducting circuits provide a controllable and versatile platform for studying quantum phenomena and advancing quantum technologies. Josephson junctions and resonators are the central circuit elements, as they enable the realization of macroscopic quantum systems—such as qubits—that can be conveniently controlled, probed, and integrated with non-superconducting components. The implementation of a thermal reservoir through the integration of a dissipative element, such as a normal-metal resistor, offers an experimental platform for investigating quantum thermodynamics, heat management in circuits, on-chip thermal detectors, and the realization of quantum thermal machines. In this thesis, we integrate a mesoscopic normal metal and its associated thermometers as an on-chip bolometer within circuit quantum electrodynamics devices for thermal detection and quantum thermodynamics experiments. The on-chip bolometer is utilized as a sensitive and broadband thermal spectrometer to characterize the properties of a superconducting resonator and to investigate its dominant loss channels. We demonstrate the capability of our thermal detector to resolve the resonator modes over a wide frequency range extending above 20 GHz. When two thermal baths are connected through a qubit–resonator system, a quantum heat valve can be realized. This device has been demonstrated using both transmon and flux qubits. Photonic heat transport between the two baths is controlled by tuning the qubit energy via an applied static magnetic field. To model these experiments, we propose an approach based on electromagnetic simulation and microwave circuit theory, restricted to the linear-response regime. Despite this limitation, the method successfully captures the experimental observations and provides a practical tool for analysing and designing circuits for future experiments. A periodically driven qubit coupled to two unequal resonators, each terminated by a heat reservoir, enables the realization of a quantum Otto refrigerator. The use of a transmon qubit for this purpose is limited by its weak anharmonicity. We therefore explore alternative platforms for the experimental implementation of a quantum refrigerator based on charge and flux qubits, which exhibit strong anharmonicity. As an important step, we perform experiments on a driven flux qubit galvanically coupled to a resonator that is, in turn, weakly capacitively coupled to a heat reservoir. We observe interference patterns in the heat current arising from driving-induced coherence. In particular, resonance peaks in the heat transferred to the bath appear at driving frequencies that are integer fractions of the resonator frequency. These quantum features are governed by the relative phase accumulated by the qubit states under driving.
Technological advances over the past few decades have made it possible to address quantum systems down to individual quanta of energy. Artificial atoms are now routinely fabricated and manipulated using solid-state technology. Exciting new applications are now within grasp, such as quantum heat engines, which have been theorised to achieve energy efficiencies not possible for their classical counterparts. Energy fluctuations are an inherent part of these devices and a detailed understanding of them is required. However, the proper theoretical framework under which such fluctuations are to be understood is still debated. In this thesis, we study energy fluctuations in open quantum systems at the level of individual runs of an experimental protocol. This work has been carried out in two parts. In the first part, we focus on calorimetric measurements – a promising new experimental protocol to continuously measure energy fluctuations of a qubit interacting with a thermal environment. Applying the protocol to more complex systems is not straightforward. Using a simple two-level approximation, we show that for some experimental parameters this protocol can be extended to a driven harmonic oscillator. Another aspect of the calorimetric protocol is that it can induce non-Markovian effects which affect how work and heat are defined. We quantify the degree of non-Markovianity induced by this measurement protocol, when applied to a qubit, based on a previously developed theoretical model. Importantly, we show that non-Markovianity does not necessarily decrease monotonically with the environment size. The attempt to extend the calorimetric protocol to general systems has led to the second part of this thesis. The calorimetric detection is a particular case of a continuously monitored system. However, other schemes exist that lead to different definitions of work and heat. Reconciling these approaches is not straightforward, as evidenced by the many work definitions present in the literature. The difficulty is centred at the fact that, in the orthodox interpretation of quantum mechanics, energy is not always a well-defined quantity. Here, based on the Bohmian interpretation of quantum mechanics, we put forward a general framework to remove this problem in a clear conceptual manner. In particular, we show that the classical definition of work for closed systems can be straightforwardly generalised to the quantum case. For an open system, we used the Bohmian conditional wave function which provides a stochastic state evolution for the open system. We show that this approach can lead to new insights regarding the role of entanglement in energy fluctuations and has the potential to provide a general and observer-independent framework of energy fluctuations in open quantum systems. The results presented in this thesis give a small contribution to the developing field of quantum thermodynamics.
The study of nanoscopic thermal devices attracts an increasing attention, not only because of their key role in understanding the emergence of thermodynamics from quantum theory, but also for the potential use of quantum-mechanical thermal cycles, especially refrigerators, in quantum technologies. This thesis, is devoted to the performance optimization of autonomous (heat-driven) refrigerators. For a quantum refrigerator, one has a full microscopic description of the simple system serving as a working medium, and of its interaction with the external heat baths. This enables a consistent `finite-time? thermodynamic analysis, not relying on any phenomenological assumptions about the leading sources of irreversibility, and allows to establish arguably general performance bounds, essential to benchmark the operation of realistic devices. In particular, tight and model-independent upper bounds for the coefficient of performance at maximum power, are derived here for a class of strongly coupled refrigerators, and seen to hold more generally for other types of heat and power-driven cycles. Remarkably, these ultimate limitations only depend on the particulars of the system-baths interaction at the interface with the object to be cooled. Strategies might be then defined so as to saturate those limits: It is shown how the working medium of the refrigerator may be, for instance, scaled up into a parallel multi-stage configuration, resembling that of macroscopic multi-effect absorption chillers, as a means to increase its cooling power. Similarly, by applying reservoir engineering techniques on selected transitions between the energy states of the working medium, one can mimic exploitable non-equilibrium fluctuations in the baths, capable of boosting the overall power and COP beyond what would be otherwise allowed by the second law of thermodynamics. In this way, heat-driven chillers could be set to compete on a equal footing with the best power-driven refrigerators.
Quantum thermodynamics seeks to address the emergence of thermodynamic laws, which govern how energy is exchanged between physical systems, from a quantum mechanical description of light and matter. As such, the workhorse model for an underlying description of such energy exchange processes is the open quantum system: a quantum system which may interact with an external environment. Open quantum systems are well-understood in regimes where the interaction between the system and the environment is weak enough that perturbative methods may be employed to arrive at dynamical equations of motion for the evolution of the system. How to tackle the strong coupling regime is an open question and much research is still being devoted in this area. In this project we employ a technique developed for studying an open quantum system in regimes of strong reservoir coupling in problems in thermodynamics which have so far been restricted to the weak coupling regime. We spend some time developing our strong coupling framework and then use it to analyse a quantum heat engine to find that strong coupling leads to a particular set of operational costs which are not present in more well-understood weak coupling versions. We also identify effects purely quantum in nature, present in the engine cycle only at strong coupling, which lead to a degradation in the engine's performance. Finally we address the issue of quantum coherence more generally in archetypal open quantum system models beyond weak coupling, and identify a thermodynamic cost to its erasure.