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arXiv:2401.10022 · Journal of Mathematical Physics

Entropy production of quantum reset models

Géraldine Haack, Alain Joye

Published Oct 1, 2024• 2 citations
arXivHTMLPDF

Abstract

We analyze the entropy production of Quantum Reset Models (QRMs) corresponding to quantum dynamical semigroups driven by Lindbladians motivated by a probabilistic description of dissipation in an external environment. We investigate the strict positivity of entropy production for Lindbladians given as sums of QRMs, when the Hamiltonian of the total Lindbladian is split as an affine combination of Hamiltonians of the individual QRMs. In this setup, we derive conditions on the coefficients of the combination and on the reset states ensuring either positive or zero entropy production. Second, we deal with a tri-partite system subject at its ends to two independent QRMs and a weak coupling Hamiltonian. The latter is split as an affine combination of individual Hamiltonians, and we provide necessary and sufficient conditions ensuring strict positivity of the entropy production to leading order, with the possible exception of one affine combination. We apply these results to a physically motivated model and exhibit explicit expressions for the leading orders steady-state solution, entropy production and entropy fluxes. Moreover, these approximations are numerically shown to hold beyond the expected regimes.

DOI
10.1063/5.0199007

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We analyze the entropy production of Quantum Reset Models (QRMs) corresponding to quantum dynamical semigroups driven by Lindbladians motivated by a probabilistic description of dissipation in an external environment. We investigate the strict positivity of entropy production for Lindbladians given as sums of QRMs, when the Hamiltonian of the total Lindbladian is split as an affine combination of Hamiltonians of the individual QRMs. In this setup, we derive conditions on the coefficients of the combination and on the reset states ensuring either positive or zero entropy production. Second, we deal with a tri-partite system subject at its ends to two independent QRMs and a weak coupling Hamiltonian. The latter is split as an affine combination of individual Hamiltonians, and we provide necessary and sufficient conditions ensuring strict positivity of the entropy production to leading order, with the possible exception of one affine combination. We apply these results to a physically motivated model and exhibit explicit expressions for the leading orders steady-state solution, entropy production and entropy fluxes. Moreover, these approximations are numerically shown to hold beyond the expected regimes.
This paper is devoted to the analysis of Lindblad operators of Quantum Reset Models, describing the effective dynamics of tri-partite quantum systems subject to stochastic resets. We consider a chain of three independent subsystems, coupled by a Hamiltonian term. The two subsystems at each end of the chain are driven, independently from each other, by a reset Lindbladian, while the center system is driven by a Hamiltonian. Under generic assumptions on the coupling term, we prove the existence of a unique steady state for the perturbed reset Lindbladian, analytic in the coupling constant. We further analyze the large times dynamics of the corresponding CPTP Markov semigroup that describes the approach to the steady state. We illustrate these results with concrete examples corresponding to realistic open quantum systems.
The dissipative dynamics of a quantum system weakly coupled to one or several reservoirs is usually described in terms of a Lindblad generator. The popularity of this approach is certainly due to the linear character of the latter. However, while such linearity finds justification from an underlying Hamiltonian evolution in some scaling limit, it does not rely on solid physical motivations at small but finite values of the coupling constants, where the generator is typically used for applications. The Markovian quantum master equations we propose are instead supported by very natural thermodynamic arguments. They themselves arise from Markovian master equations for the system and the environment which preserve factorized states and mean energy and generate entropy at a non-negative rate. The dissipative structure is driven by an entropic map, called modular, which introduces nonlinearity. The generated modular dynamical semigroup (MDS) guarantees for the positivity of the time evolved state the correct steady state properties, the positivity of the entropy production, and a positive Onsager matrix with symmetry relations arising from Green-Kubo formulas. We show that the celebrated Davies Lindblad generator, obtained through the Born and the secular approximations, generates a MDS. In doing so we also provide a nonlinear MDS which is supported by a weak coupling argument and is free from the limitations of the Davies generator.
In the weak-coupling limit approach to open quantum systems, the presence of the bath is eliminated and accounted for by a master equation that introduces dissipative contributions to the system reduced dynamics: within this framework, there are no bath entropy contributions to the entropy balance. We show that, as a consequence, the entropy production fails to be positive for a class of physically legitimate, that is completely positive and trace preserving, non-Markovian dynamical maps. Moreover, in absence of the semigroup property, if the reduced dynamics has a thermal asymptotic state, this need not be stationary. Then even the integrated entropy production becomes negative. These observations imply that, when the conditions leading to reduced dynamics of semigroup type are relaxed, a consistent formulation of the second law of thermodynamics requires that the environment contribution to the entropy balance be explicitly taken into account.
An invariant state of a quantum Markov semigroup is an equilibrium state if it satisfies a quantum detailed balance condition. In this paper, we introduce a notion of entropy production for faithful normal invariant states of a quantum Markov semigroup on B(h) as a numerical index measuring "how much far" they are from equilibrium. The entropy production is defined as the derivative of the relative entropy of the one-step forward and backward evolution in analogy with the classical probabilistic concept. We prove an explicit trace formula expressing the entropy production in terms of the completely positive part of the generator of a norm continuous quantum Markov semigroup showing that it turns out to be zero if and only if a standard quantum detailed balance condition holds.
We demonstrate that, for a quantum Markovian semigroup on a finite-dimensional Hilbert space, if it satisfies the standard quantum detailed balance condition, its generator admits a special representation that yields a vanishing entropy production rate. Conversely, if the generator admits a special representation adhering to the condition of thermodynamic consistency and leading to a vanishing entropy production rate, then the corresponding quantum Markovian semigroup must satisfy the standard quantum detailed balance condition. In this context, we adopt the definition of entropy production rate that is motivated by the physics literature and standard for thermodynamically consistent Lindbladians.
We give an explicit entropy production formula for a class of quantum Markov semigroups, arising in the weak coupling limit of a system coupled with reservoirs, whose generators [Formula: see text] are sums of other generators [Formula: see text] associated with positive Bohr frequencies [Formula: see text] of the system. As a consequence, we show that any such semigroup satisfies the quantum detailed balance condition with respect to an invariant state if and only if all semigroups generated by each [Formula: see text] do so with respect to the same invariant state.