Quantum Markov models are employed ubiqui-tously in quantum physics and in quantum information theory due to their relative simplicity and analytical tractability. In particular, these models are known to give accurate approxi-mations for a wide range of quantum optical and meso scopic systems. However, in general, the validity of the Markov approximation entails assumptions regarding properties of the system of interest and its environment, which may not be satisfied or accurate in arbitrary physical systems. Therefore, developing useful modelling tools for general non-Markovian quantum systems for which the Markov approximation is inappropriate or deficient is an undertaking of significant importance. This work considers non-Markovian principal quantum systems that can be embedded in a larger Markovian quantum system with one or more compound baths consisting of an auxiliary quantum system and a quantum white noise field, and derives a set of coupled stochastic and quantum master equations for embedded non-Markovian quantum systems. The case of a purely Hamiltonian coupling between the principal and auxiliary systems as a closed system without coupling to white noises is included as a special case. The results are expected to be of interest for (open-loop and feedback) control of continuous-time non-Markovian systems and studying reduced models for numerical simulation of such systems. They may also shed more light on the general structure of continuous-time non-Markovian quantum systems.
Quantum Markov models are employed ubiqui-tously in quantum physics and in quantum information theory due to their relative simplicity and analytical tractability. In particular, these models are known to give accurate approxi-mations for a wide range of quantum optical and meso scopic systems. However, in general, the validity of the Markov approximation entails assumptions regarding properties of the system of interest and its environment, which may not be satisfied or accurate in arbitrary physical systems. Therefore, developing useful modelling tools for general non-Markovian quantum systems for which the Markov approximation is inappropriate or deficient is an undertaking of significant importance. This work considers non-Markovian principal quantum systems that can be embedded in a larger Markovian quantum system with one or more compound baths consisting of an auxiliary quantum system and a quantum white noise field, and derives a set of coupled stochastic and quantum master equations for embedded non-Markovian quantum systems. The case of a purely Hamiltonian coupling between the principal and auxiliary systems as a closed system without coupling to white noises is included as a special case. The results are expected to be of interest for (open-loop and feedback) control of continuous-time non-Markovian systems and studying reduced models for numerical simulation of such systems. They may also shed more light on the general structure of continuous-time non-Markovian quantum systems.
An effective approach to modeling non-Markovian quantum systems is to embed a principal (quantum) system of interest into a larger quantum system. A widely employed embedding is one that uses another quantum system, referred to as the auxiliary system, which is coupled to the principal system, and both the principal and auxiliary can be coupled to quantum white noise processes. The principal and auxiliary together form a quantum Markov system and the quantum white noises act as a bath (environment) for this system. Recently it was shown that the conditional evolution of the principal system in this embedding under continuous monitoring by a travelling quantum probe can be expressed as a system of coupled stochastic differential equations (SDEs) that involve only operators of the principal system. The reduced conditional state of the principal only (conditioned on the measurement outcomes) are determined by the “diagonal" blocks of this coupled systems of SDEs. It is shown here that the “off-diagonal" blocks can be exactly eliminated up to their initial conditions, leaving a reduced closed system of SDEs for the diagonal blocks only. Under additional conditions the off-diagonal initial conditions can be made to vanish. This new closed system of equations, which includes an integration term involving a two-time stochastic kernel, represents the non-Markovian stochastic dynamics of the principal system under continuous-measurement. The system of equations determine the reduced conditional state of the principal only and may be viewed as a stochastic Nakajima-Zwanzig type of equation for continuously monitored non-Markovian quantum systems.
Quantum Markov models have been successfully used to accurately model various physical quantum systems in fields such as quantum optics, optomechanics and superconducting circuits and they provide the basis for (measurement-based) quantum feedback control. However, the quantum Markov assumption is a strong one and it is not expected to hold for general quantum systems of interest. The projection operator approach is one approach that has been developed to model non-Markovian quantum systems by considering its embedding in a larger Markovian quantum system, but mainly in the context of quantum master equations for the dynamics of the unmonitored reduced quantum state of a quantum system. This approach was recently adapted for continuously measured non-Markovian quantum systems, which enables open-loop control but did not yet consider the presence of feedback of the stochastic measurement record, deriving non-Markovian SDEs for the evolution of the projected state of the Markovian embedding. This paper generalizes these stochastic equations to the setting of stochastic feedback based on the continuous-measurement record and shows that the equations take the same form but that previously deterministic terms become stochastic ones which depend on the measurement record, as would be intuitively expected. The stochastic equations are obtained for a generalized class of measurements that includes continuous (possibly adaptive) homodyne and photon counting measurements.
Positivity preservation is naturally guaranteed in exact non-Markovian master equations for open quantum system dynamics. However, in many approximated non-Markovian master equations, the positivity of the reduced density matrix is not guaranteed. In this paper we provide a general class of time-local, perturbative, and positivity-preserving non-Markovian master equations generated from stochastic Schr\"odinger equations, particularly quantum-state-diffusion equations. Our method has an expanded range of applicability for accommodating a variety of non-Markovian environments. We show the positivity-preserving master equation for a three-level system coupled to a dissipative bosonic environment as a particular example to exemplify our general approach. We illustrate the numerical simulations with an analysis explaining why the previous approximated non-Markovian master equations cannot guarantee positivity. Our work provides a consistent master equation for studying the non-Markovian dynamics in ultrafast quantum processes and strong-coupling systems.
Stochastic unravelings provide a useful way to represent open quantum system dynamics in terms of pure state realizations, and have been widely studied both from a fundamental and from a computational point of view. They were initially formulated for Markovian dynamics described by the Gorini-Kossakowski-Sudarshan-Lindblad master equation. However, due to recent technological and experimental development, most physical relevant dynamics present temporal correlations beyond the Markov approximation. Such correlations cause decay rates to turn temporarily negative, thus requiring the generalization of stochastic unravelings from Markovian to non-Markovian scenarios. Indeed, many unraveling techniques have been introduced in this regime, and a comprehensive review of the different jump methods is currently missing. In this work, we provide an overview of widely used quantum jump unraveling techniques for non-Markovian systems and also discuss them in terms of their numerical efficiency, divisibility requirements, Hilbert space extension, and measurement interpretation.
The paradigm of considering open quantum systems—i.e., focusing only on the system of interest, and treating the rest of the world as an effective environment—has proven to be a highly effective way to understand a range of quantum systems, across areas of study such as quantum optics, cold atoms, superconducting qubits, and impurities in solid-state systems. A common approach in many of these contexts has been to consider simplified approaches based on the Born and Markov approximations. While these approximations are indeed often appropriate in contexts such as quantum optics, the widespread application of these approximations has been driven more by simplicity than by accuracy. In particular, these Markovian treatments will fail in many cases, such as when coupling to the environment is not weak, when the environment is structured and has resonances, when the system couples to low-frequency modes of the environment, or when the questions of interest involve the propagation of information through the environment. Despite the fact that many real problems are non-Markovian, the Markov approximation is still widely used, as it is often assumed that a fully non-Markovian treatment is too complex to be practical. In this Perspective we discuss a recently developed set of techniques that address this challenge. Centering our discussion around the notion of the process tensor, we demonstrate that the generality of the process tensor concept, coupled with efficient tensor-network methods, opens the door to the description of a wide range of observable non-Markovian processes in a wide range of open quantum systems.
The theory of open quantum systems represents one of the major developments of quantum mechanics over the last 50 years. Its central object of study is constituted by quantum systems that cannot be regarded as fully isolated, but instead interact with additional degrees of freedom, giving rise to irreversible phenomena such as dissipation and decoherence. The tools provided by this framework are nowadays of paramount importance across many active areas of research, including quantum computation, thermodynamics, metrology and biology. In this thesis, we investigate three main topics within the field. The first contribution concerns the microscopic derivation of the evolution equations, socalled quantum master equations, for open systems which are also subject to external driving fields. Standard techniques developed for time-independent Hamiltonians encounter several difficulties in the time-dependent case, largely restricting their applicability to specific instances, such as periodic or adiabatic drivings. In contrast, a core result of the derivation presented in the thesis is that, when the environment is sufficiently Markovian (essentially, memoryless), the non-adiabatic contributions to the driving field can be neglected in a controlled fashion, yielding an accurate master equation with time-dependent generator, capable of correctly reproducing the open dynamics even for strong drivings. This result is further supported by benchmarks against numerically exact simulations. The second contribution addresses the long-time behavior of general types of (Markovian) quantum master equations, including those of the form introduced above. While this problem has been extensively analyzed in the time-independent setting, virtually no results are known for time-dependent generators. In particular, we establish the foundations of a general theory of relaxation, that is, convergence towards an asymptotic trajectory in the long-time limit, independently of the initial state. The main results include a theorem guaranteeing sufficient conditions for relaxation and the derivation of a rate function governing the convergence to the asymptotic trajectory. The analysis is further extended to a simple non-Markovian case. Moreover, we treat in detail the specific master equation derived in the first part, connecting the aforementioned relaxation property directly to the underlying microscopic dynamics. The third contribution investigates chirality-induced spin selectivity (CISS) effects from the perspective of open quantum systems. Although the majority of theoretical studies aiming to model CISS are based on a coherent description of the spin dynamics, such effects have been observed also for electrons subject to incoherent transport across molecular networks. In this regard, we provide a rigorous ab initio derivation of the microscopic Hamiltonian describing the electronic transport, incorporating electron spin effects and contributions stemming from the nuclear vibrations. Within this result, we critically revise a master equation approach aiming to explain the origin of CISS effects observed in photosynthetic complexes. Taken together, these contributions offer fresh insights and original results on the interplay between driving fields and dissipation, relaxation phenomena, and electronic spin transport in the presence of incoherent dynamics. More broadly, these results provide new theoretical tools with several potential applications in quantum technologies, from modeling of control pulses in noisy environments to quantum reservoir engineering, and contribute to a deeper understanding of the role of quantum effects in biological systems.