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arXiv:2212.09151 · Physical Review A

Exact entanglement dynamics of two spins in finite baths

Mei Yu, Otfried Gühne, Stefan Nimmrichter

Published Aug 17, 2023• 2 citations
arXivHTMLPDF

Abstract

We consider the buildup and decay of two-spin entanglement through phase interactions in a finite environment of surrounding spins, as realized in quantum computing platforms based on arrays of atoms, molecules, or nitrogen vacancy centers. The non-Markovian dephasing caused by the spin environment through Ising-type phase interactions can be solved exactly and compared to an effective Markovian treatment based on collision models. In a first case study on a dynamic lattice of randomly hopping spins, we find that non-Markovianity boosts the dephasing rate caused by nearest-neighbor interactions with the surroundings, degrading the maximum achievable entanglement. However, we also demonstrate that additional three-body interactions can mitigate this degradation, and that randomly timed reset operations performed on the two-spin system can help sustain a finite average amount of steady-state entanglement. In a second case study based on a model nuclear magnetic resonance system, we elucidate the role of bath correlations at finite temperature on non-Markovian dephasing. They speed up the dephasing at low temperatures while slowing it down at high temperatures, compared to an uncorrelated bath, which is related to the number of thermally accessible spin configurations with and without interactions.

DOI
10.1103/physreva.108.022415

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We consider the buildup and decay of two-spin entanglement through phase interactions in a finite environment of surrounding spins, as realized in quantum computing platforms based on arrays of atoms, molecules, or nitrogen vacancy centers. The non-Markovian dephasing caused by the spin environment through Ising-type phase interactions can be solved exactly and compared to an effective Markovian treatment based on collision models. In a first case study on a dynamic lattice of randomly hopping spins, we find that non-Markovianity boosts the dephasing rate caused by nearest-neighbor interactions with the surroundings, degrading the maximum achievable entanglement. However, we also demonstrate that additional three-body interactions can mitigate this degradation, and that randomly timed reset operations performed on the two-spin system can help sustain a finite average amount of steady-state entanglement. In a second case study based on a model nuclear magnetic resonance system, we elucidate the role of bath correlations at finite temperature on non-Markovian dephasing. They speed up the dephasing at low temperatures while slowing it down at high temperatures, compared to an uncorrelated bath, which is related to the number of thermally accessible spin configurations with and without interactions.
Molecular spins are promising candidates for quantum information science, leveraging coherent electronic spin states for quantum sensing and computation. However, the practical application of these systems is hindered by electronic spin decoherence, driven by interactions with nuclear spins in the molecule and the surrounding environment at low temperatures. Predicting dephasing dynamics remains a formidable challenge due to the complexity of the spin bath. In this work, we develop a non-Markovian time-convolutionless master equation to treat an electronic spin coupled to a nuclear-spin bath. By relating ab initio electronic structure parameters directly to the decoherence dynamics, we provide a framework that accounts for pure dephasing in the low-temperature limit. We apply this method to a series of molecular qubit candidates and demonstrate good agreement with experimental relaxation trends. This approach offers a computationally efficient path for the prediction of low-temperature decoherence trends in molecular spin systems.
We consider pure dephasing of Bell states of electron spin qubits interacting with a sparse bath of nuclear spins. Using the newly developed two-qubit generalization of cluster-correlation expansion method, we calculate the spin-echo decay of $|\mathrm{\ensuremath{\Psi}}\ensuremath{\rangle}$ and $|\mathrm{\ensuremath{\Phi}}\ensuremath{\rangle}$ states for various interqubit distances. Comparing the results with calculations in which dephasing of each qubit is treated independently, we identify signatures of influence of common part of the bath on the two qubits. At large interqubit distances, this common part consists of many nuclei weakly coupled to both qubits, so that decoherence caused by it can be modeled by considering multiple uncorrelated sources of noise (clusters of nuclei), each of them weakly affecting the qubits. Consequently, the resulting genuinely two-qubit contribution to decoherence can be described as being caused by classical Gaussian noise. On the other hand, for small interqubit distances the common part of the environment contains clusters of spins that are strongly coupled to both qubits, and their contribution to two-qubit dephasing has visibly non-Gaussian character. We show that one can easily obtain information about non-Gaussianity of environmental noise affecting the qubits from the comparison of dephasing of $|\mathrm{\ensuremath{\Psi}}\ensuremath{\rangle}$ and $|\mathrm{\ensuremath{\Phi}}\ensuremath{\rangle}$ Bell states. Numerical results are obtained for two nitrogen vacancy centers interacting with a bath of 13C^{13}\mathrm{C}13C nuclei of natural concentration, for which we obtain that Gaussian description of a correlated part of environmental noise starts to hold for centers separated by about 3 nm.
In the first part of this thesis, we investigate the dynamics of open quantum systems coupled in a purely dephasing way to their environment, which is a paradigmatic example of decoherent dynamics. We focus more specifically on the emergence of non-Markovian effects in the dynamics of such open systems. After reviewing different measures of non-Markovianity, we obtain an analytical expression for the reduced density operator of a finite-dimensional open system coupled with its environment through time-dependent purely dephasing interactions. When the system is initially uncorrelated with its environment, we obtain the time-local master equation that describes its dynamics. In this case, we also derive an exact expression for the witness of non-Markovianity based on the volume of accessible states of the open system. These results are then applied to spin systems coupled to either a spin or a bosonic environment. For spin environments, we study non-Markovianity for different ranges of interaction and in different thermodynamical limits. Moreover, the generation of entanglement between the open system and its environment as well as between spins within the open system is investigated. For bosonic environments, we study the effect of the initial state of the environment on non-Markovianity. We also show that time-dependent modulations of the system-environment coupling can dramatically alter the non-Markovian behavior of the open system. Finally, we consider the case of an open quantum system simultaneously coupled to spin and bosonic baths. In that case, we study how the coupling between the different baths and of the presence of initial correlations in the environment affect the non-Markovianity displayed by the open quantum system. The second part of this thesis is a contribution to the investigation of how quantum systems can be used to process information. More precisely, we focus on the implementation of gate-based quantum computing using neutral atoms trapped in optical or magnetic lattices and interacting through dipole-dipole interactions when excited to Rydberg states. In this context, we present protocols implementing two-qubit quantum gates between atoms far apart in the lattice. To this end, we propose to use a chain of non-coding ancilla atoms to transfer the state of the control qubit to an atom near the target qubit. Before discussing entangling gates between distant qubits, we present two protocols that implement state transfer along a chain of two-level atoms relying respectively on single- and two-atom laser pulses combined with dipole blockade. After reviewing protocols implementing CZ and CNOT gates between nearby qubits using dipole-dipole interactions, we show how the state-transfer protocols previously presented can be used to perform entangling gates between distant qubits. The performance of the state-transfer and gate protocols are assessed using the process fidelity. Moreover, we provide a theoretical explanation for the behavior of the process fidelity with respect to dissipation and imperfect blockade.
The dynamics of a central spin-1/2 in presence of a local magnetic field and a bath of N spin-1/2 particles is studied in the thermodynamic limit. The interaction between the spins is Heisenberg XY type and the bath is considered to be a perfect thermal reservoir. In this case, the evolution of the populations of the reduced density matrix is obtained for different temperatures. A Born approximation is made but not a Markov approximation resulting a non-Markovian dynamics. The measure of the entanglement between the spin and the bath is obtained by means of the von Neumann entropy. For low temperatures, results show that there are oscillations of populations and of the von Neumann entropy as measure of entanglement, indicating that the central spin becomes disentangled of the spins of the bath with characteristic time periods in which it is possible to extract or recuperate information. In the regime of high temperatures, the evolution shows a final maximum entangled state with entropy S = ln 2 as it is expected for a two level system. I
We have studied an early stage disentanglement by solving an exactly solvable spin bath model in the Markovian and non-Markovian regimes. In the Markovian regime, the central two qubit spins are non-interacting in which entanglement strongly depends on mean number of photon. In the non-Markovian regime, we solved by considering and ignoring the interaction between central two spins and observe that the entanglement strongly depends on the spin bath interaction, qubit spin interaction, bath spin interaction, thermal temperature and the initial state. Further, the concurrence of an initially unentangled state mixed with an entangled state also depends on the initial state.
Applications of quantum devices and simulators require an accurate understanding of their dynamics as well as the effects of environmental noise. While some sources of noise can be modeled as Markovian dissipation, coupling to resonators or vibrational modes often produces non-Markovian dynamics as well, making it difficult to characterize the system, particularly for interacting many-body systems. Here, we identify a broad class of exactly solvable many-body quantum systems with both non-Markovian dynamics and Markovian dissipation. We consider a prototypical model of spins coupled to lossy bosonic modes that mediate Ising-type interactions. We exclude a transverse field but allow local spin dissipation that need not commute with the interactions, including dephasing, relaxation, pumping, and even processes that generate coherences. Using an exact stochastic representation, we decouple the many-body dynamics into the evolution of individual spins, yielding exact spin observables and correlations without adiabatically eliminating the bosons. In the Markovian limit, our solutions describe Ising models with correlated dephasing and nonreciprocal interactions. An example of spin squeezing shows that both the achievable squeezing and its optimal preparation time depend strongly on the interplay between non-Markovian dynamics and Markovian dissipation.