In the design and investigation of superconducting qubits and related devices, a lumped-element circuit model is the standard theoretical approach. However, many important physical questions lie beyond its scope, such as the behavior of circuits with strong Josephson junctions carrying substantial currents and the properties of very small superconducting devices. By performing gauge transformations on self-consistent solutions of the Bogoliubov--de Gennes equations, we develop here a formalism that treats Josephson couplings nonperturbatively. We apply the formalism to (a) show that Fermi sea effects can contribute to the effective capacitance of small charge qubits; (b) demonstrate an asymmetry in clockwise and counterclockwise current states in small rf superconducting quantum interference device qubits; and (c) provide a microscopic wave function of superconducting Schr\"odinger cats suitable for computing the number of entangled electrons.
In the design and investigation of superconducting qubits and related devices, a lumped-element circuit model is the standard theoretical approach. However, many important physical questions lie beyond its scope, such as the behavior of circuits with strong Josephson junctions carrying substantial currents and the properties of very small superconducting devices. By performing gauge transformations on self-consistent solutions of the Bogoliubov--de Gennes equations, we develop here a formalism that treats Josephson couplings nonperturbatively. We apply the formalism to (a) show that Fermi sea effects can contribute to the effective capacitance of small charge qubits; (b) demonstrate an asymmetry in clockwise and counterclockwise current states in small rf superconducting quantum interference device qubits; and (c) provide a microscopic wave function of superconducting Schr"odinger cats suitable for computing the number of entangled electrons.
Superconducting circuits are one of the leading candidates for scalable quantum computation, owing to their long coherence time and compatibility with fabrication techniques. Despite their experimental success, the conventional theoretical framework for superconducting circuit quantisation relies on a semiclassical procedure that requantises the phenomenological Ginzburg-Landau order parameter, introducing the postulated canonical relations and leaving the microscopic origins of circuit parameters hidden. In the present thesis, we develop a rigorous and first-principles approach for the quantisation of superconducting circuits, directly grounded in Bardeen-Cooper-Schrieffer (BCS) theory for superconductivity, and extend this framework to investigate the dynamics of the superconducting Higgs amplitude mode. The central methodological contribution of this work is a projective approach, in which the full many-body electronic Hamiltonian of a superconducting system is projected onto a carefully constructed low-energy BCS Hilbert space, HBCS, spanned by phase parameterised BCS ground states. We systematically characterise the kinematic properties of this subspace, quantify the orthogonality and completeness of the phase basis via the BCS overlap and the projection error, and show that the effective dimensionality of the space is scaled as the square root of the number of single electronic modes. This approach does not impose a spontaneously broken symmetry so that it consistently describes quantised circuits that support superpositions of phases, and the canonical commutation relations between phase and number are derived from the underlying fermionic commutation properties, rather than imposed. This establishes the fully quantum mechanical foundation upon which the standard circuit quantisation approach implicitly rests. The projective formalism is subsequently applied to derive the effective Hamiltonian for superconducting circuit elements. For point-like elements, \eg, capacitive islands and Josephson junctions, projection of the fermionic Hamiltonian onto HBCS yields analytical expressions for the charging energy and the Josephson energy in terms of microscopic material parameters. The resulting Hamiltonian reproduces the standard Cooper-pair-box and transmon Hamiltonians, but now on an unambiguous microscopic footing. We further extend the approach to spatially distributed elements. Inductance is derived from the constitutive response to spatially varying phase torsion in a superconducting wire, yielding the lumped-element inductive energy from first principles. This analysis also identifies the emergent low-energy Hilbert space of the inductor. Combining the results, a complete microscopic derivation of the standard superconducting inductance-capacitance-junction (LCJ) circuit Hamiltonian is recovered. The final part of this thesis extends the projective methodology to the superconducting Higgs mode associated to the amplitude dynamics of the superconducting order parameter. A general BCS space parameterised by phase and gap amplitude is constructed, onto which we project the microscopic Hamiltonian. This yields a generalised eigenvalue problem governing the dynamics of the gap amplitude. The Higgs mode of a superconducting island is thereby shown to behave as a quantum harmonic oscillator. We derive the analytical expressions for the superconducting Higgs mass, spring constant, and oscillation frequency of the gap dynamics. While our results reveal a logarithmic correction to the Higgs frequency reported in previous literature, we numerically validate these results, and compute quantum anharmonic corrections to the Higgs frequency for higher excitations. This thesis proposes a novel, formal and quantitative circuit quantisation theory for superconducting circuits, based on which we explore the Higgs amplitude mode dynamics. The approach is capable of resolving the fundamental question about the compactness of superconducting phase and is extendable to cover quasiparticle contributions. This microscopic circuit theory equips us with a new tool to understand superconducting devices at a level of microscopic detail inaccessible to the standard semiclassical framework, paving the way for a principled treatment of quasiparticle losses and the exploration of exotic superconducting circuit elements.
The theory of superconducting phase qubits---also known as current-biased Josephson junctions---is presented. In the first part of this thesis, I introduce quantum computation, quantum simulation, and their deep connection with symplectic integration. I then consider the fundamental many-body theory of superconductivity and Josephson junctions and show how the quantum dynamics of a single macroscopic degree of freedom, the gauge invariant phase difference, emerges. A complete study of the Hilbert space structure of such a variable is performed for the current-biased junction. The resulting resonance structure is studied in detail, using various formalisms including the WKB approximation, instanton methods, the complex scaling transformation, basis set stabilization, numerical integration, and dynamical simulation using Lie algebraic wave-packet propagation. The second part of this thesis explores how the current-biased junction can be used as an element of a quantum computer---a quantum bit (qubit). Single qubit operations are studied, followed by the presentation of the theory of coupled qubit devices. My key result is the design and optimization of quantum logic gates with high fidelity (F ~ 0.9999) for capacitively coupled phase qubits with short gate times (~ 10 ns). Finally, I examine an advanced qubit-coupling scheme, a resonant coupling method utilizing a harmonic oscillator as the auxiliary degree of freedom. The models and methods presented here have been developed in direct collaboration with an experimental program. These experiments are the first to show spectroscopic evidence for entanglement between two and three macroscopic degrees of freedom in a superconducting circuit.
We derive a mesoscopic theory of the Josephson junction from nonrelativistic scalar electrodynamics. Our theory reproduces the Josephson relations with the canonical current phase relation acquiring a weak second harmonic term, and it improves the standard lumped-element descriptions employed in circuit quantum electrodynamics by providing spatial resolution of the superconducting order parameter and electromagnetic field. By providing an ab initio derivation of the charge qubit Hamiltonian that relates traditionally free qubit parameters to geometric and material properties, we progress toward the quantum engineering of superconducting circuits at the subnanometer scale.
The strong-coupling version of the BCS theory for superconductors is used to derive microscopic models for all types of small Josephson junctions--charge qubit, flux qubit and phase qubit. Applied to Josephson qubits it yields a more complicated structure of the lowest-lying energy levels than that obtained from phenomenological models based on quantization of the Kirchhoff equations. In particular, highly degenerate levels emerge, which act as probability sinks for the qubit. The alternative formulae concerning spectra of superconducting qubits are presented and compared with the experimental data. In contrast to the existing theories those formulae contain microscopic parameters of the model. In particular, for the first time, the density of Cooper pairs at zero temperature is estimated for an Al-based flux qubit. Finally, the question whether small Josephson junctions can be treated as macroscopic quantum systems is briefly discussed.
Superconducting circuits consisting of a few low-anharmonic transmons coupled to readout and bus resonators can perform basic quantum computations. Since the number of qubits in such circuits is limited to not more than a few tens, the qubits can be designed to operate within the dispersive regime where frequency detunings are much stronger than coupling strengths. However, scaling up the number of qubits will bring the circuit out of the regime, and this invalidates current theories. We develop a formalism that allows to consistently diagonalize the superconducting circuit Hamiltonian beyond the dispersive regime. This will allow to study qubit-qubit interaction unperturbatively, therefore, our formalism remains valid and accurate at small or even negligible frequency detuning; thus, our formalism serves as a theoretical ground for designing qubit characteristics for scaling up the number of qubits in superconducting circuits. We study the most important circuits with single- and two-qubit gates, i.e., a single transmon coupled to a resonator and two transmons sharing a bus resonator. Surprisingly, our formalism allows to determine the circuit characteristics, such as dressed frequencies and Kerr couplings, in closed-form formulas that not only reproduce perturbative results, but also extrapolate beyond the dispersive regime and can ultimately reproduce (and even modify) the Jaynes-Cumming results at resonant frequencies.
Josephson junctions are the central nonlinear element of superconducting qubits, yet their standard description is reached through a chain of approximations. We propose a purely quantum-mechanical model of the junction, formulated directly in Hilbert space: a charged particle moves on a one-dimensional loop, and the junction is a point at which the wave function obeys self-adjoint boundary conditions, labelled by a coupling strength λ, which controls the transparency of the junction, and a phase jump δ, which plays the role of the superconducting phase difference. For a loop with a single junction we solve the spectral problem and show that the ground-state momentum expectation, identified with the supercurrent, factorises exactly as ⟨p^0⟩=Ic(δ,λ)sinδ. For opaque junctions Ic becomes independent of δ and the first Josephson relation I=Icsinδ is recovered; for strongly attractive coupling, where the ground state is bound to the junction, the sinδ law is also recovered, but with an exponentially suppressed amplitude. For more transparent junctions, however, the model \emph{predicts} deviations from the pure sinδ law: Ic acquires a dependence on δ already at order λ−2, compatible with the higher Josephson harmonics recently found necessary to describe superconducting qubit spectra, and a fully transparent contact yields a current linear in δ. When the phase varies in time, a gauge transformation shows that the voltage drop across the junction is proportional to δ˙, so that the second Josephson relation emerges without being imposed. The boundary-condition approach thus reproduces both Josephson relations from first principles and predicts corrections to them, offering a route towards higher-fidelity models of superconducting qubits.