In one of its versions, the Second Law states: "It is impossible to construct an engine which will work in a complete cycle, and produces no effect except the raising of a weight and cooling of a heat reservoir." While the Second Law is considered as one of the most robust laws of Nature, it is still challenging how to interpret it in a fully quantum domain. Here we unpack the true meaning of the "cyclicity" and formulate the Second Law for a generic quantum battery via its asymptotic properties of a charging process rather than in terms of a single cycle. As a paradigm, we propose a machine consisting of a battery that repeatedly interacts with identically prepared systems. We then propose the Second Law in the form: The ergotropy of the battery may increase indefinitely if and only if systems are in a non-passive state. One of the most interesting features of this new formulation is the appearance of the passive states that naturally generalize the notion of the heat bath. In this paper, we provide a handful of results that supports this formulation for diagonal systems. Interestingly, our methodology meets a well-known theory of Markov chains, according to which we classify the general charging processes based on the passivity/non-passivity of charging systems. In particular, the adopted mathematics allows us to distinguish a subtle asymptotic difference between the indefinite increase of the battery's energy (induced by the maximally mixed states) and of ergotropy (induced by the non-passive states) in terms of the so-called null-recurrent versus transient Markov chains.
In one of its versions, the Second Law states: "It is impossible to construct an engine which will work in a complete cycle, and produces no effect except the raising of a weight and cooling of a heat reservoir." While the Second Law is considered as one of the most robust laws of Nature, it is still challenging how to interpret it in a fully quantum domain. Here we unpack the true meaning of the "cyclicity" and formulate the Second Law for a generic quantum battery via its asymptotic properties of a charging process rather than in terms of a single cycle. As a paradigm, we propose a machine consisting of a battery that repeatedly interacts with identically prepared systems. We then propose the Second Law in the form: The ergotropy of the battery may increase indefinitely if and only if systems are in a non-passive state. One of the most interesting features of this new formulation is the appearance of the passive states that naturally generalize the notion of the heat bath. In this paper, we provide a handful of results that supports this formulation for diagonal systems. Interestingly, our methodology meets a well-known theory of Markov chains, according to which we classify the general charging processes based on the passivity/non-passivity of charging systems. In particular, the adopted mathematics allows us to distinguish a subtle asymptotic difference between the indefinite increase of the battery's energy (induced by the maximally mixed states) and of ergotropy (induced by the non-passive states) in terms of the so-called null-recurrent versus transient Markov chains.
The charging of a quantum battery by a four-stroke quantum machine that works either as an engine or a refrigerator is investigated. The presented analysis provides the energetic behavior of the combined system in terms of the heat- and workflows of the machine, the average, the variance of the battery's energy, as well as the coherent and incoherent parts of its ergotropy. To monitor the battery state, its energy is measured either after the completion of any cycle or after a prescribed number of cycles is carried out. The resulting battery performances greatly differ for those two cases. During the first charging epoch with an engine, the regular measurements speed up the charging, whereas the gain of ergotropy is more pronounced in the absence of measurements. In a later stage, the engine fails to work as such, while it still continues charging the battery that eventually reaches the maximally charged state in the absence of intermediate measurements and a suboptimally charged state for a periodically measured battery. For a refrigerator, the charging of the measured battery also proceeds faster during the first epoch. Only during the second stage, when the machine fails to extract heat from the cold bath, the influence of the measurements becomes less pronounced, leading to rather similar asymptotic states for the two measurement scenarios.
A repeated interaction process assisted by auxiliary thermal systems charges a quantum battery. The charging energy is supplied by switching on and off the interaction between the battery and the thermal systems. The charged state is an equilibrium state for the repeated interaction process, and the ergotropy characterizes its charge. The working cycle consists in extracting the ergotropy and charging the battery again. We discuss the fluctuating efficiency of the process, among other fluctuating properties. These fluctuations are dominated by the equilibrium distribution and depend weakly on other process properties.
One of the most fundamental tasks in quantum thermodynamics is extracting energy from one system and subsequently storing this energy in an appropriate battery. Both of these steps, work extraction and charging, can be viewed as cyclic Hamiltonian processes acting on individual quantum systems. Interestingly, so-called passive states exist, whose energy cannot be lowered by unitary operations, but it is safe to assume that the energy of any not fully charged battery may be increased unitarily. However, unitaries raising the average energy by the same amount may differ in qualities such as their precision, fluctuations, and charging power. Moreover, some unitaries may be extremely difficult to realize in practice. It is hence of crucial importance to understand the qualities that can be expected from practically implementable transformations. Here, we consider the limitations on charging batteries when restricting to the feasibly realizable family of Gaussian unitaries. We derive optimal protocols for general unitary operations as well as for the restriction to easier implementable Gaussian unitaries. We find that practical Gaussian battery charging, while performing significantly less well than is possible in principle, still offers asymptotically vanishing relative charge variances and fluctuations.
We study the ergotropy and the thermodynamic potentials of a qubit battery charged by repeated interactions with clusters of thermal ancillas, qubits or oscillators, through a composite system-bath coupling that generates steady-state coherence in the energy basis. A single parameter encoding the bath quantum statistics yields the coherence and ergotropy in closed form for any cluster size. For large clusters, the ergotropy becomes independent of the bath statistics and, at optimal couplings, reaches a universal fraction of the equilibrium internal energy of the qubit at the bath temperature. Since the charged state has no population inversion, all extractable work comes from coherence. The ergotropy is flat at low temperatures. We trace this plateau to the third law, and show that the ergotropy is proportional to the equilibrium enthalpy of the qubit, whose slope vanishes with the heat capacity. For a battery composed of multiple qubits, the coherence grows exponentially with the number of qubits while the ergotropy grows linearly, both remaining a nearly constant fraction of their respective maxima. The charged state is a non-equilibrium steady state with finite entropy at zero temperature, sustained by the work of switching the collisional interaction on and off. The cost is nonzero whenever the parallel coupling is nonzero, and, unlike the ergotropy, it depends on the bath statistics.
The minimal-coupling quantum heat engine is a thermal machine consisting of an explicit energy storage system, heat baths, and a working body, which alternatively couples to subsystems through discrete strokes --- energy-conserving two-body quantum operations. Within this paradigm, we present a general framework of quantum thermodynamics, where a work extraction process is fundamentally limited by a flow of non-passive energy (ergotropy), while energy dissipation is expressed through a flow of passive energy. It turns out that small dimensionality of the working body and a restriction only to two-body operations make the engine fundamentally irreversible. Our main result is finding the optimal efficiency and work production per cycle within the whole class of irreversible minimal-coupling engines composed of three strokes and with the two-level working body, where we take into account all possible quantum correlations between the working body and the battery. One of the key new tools is the introduced ``control-marginal state" --- one which acts only on a working body Hilbert space, but encapsulates all features regarding work extraction of the total working body-battery system. In addition, we propose a generalization of the many-stroke engine, and we analyze efficiency vs extracted work trade-offs, as well as work fluctuations after many cycles of the running of the engine.
Abstract We introduce a cyclic quantum battery QB model, based on an interacting bipartite system, weakly coupled to a thermal bath. The working cycle of the battery consists of four strokes: system thermalization, disconnection of subsystems, ergotropy extraction, and reconnection. The thermal bath acts as a charger in the thermalization stroke, while ergotropy extraction is possible because the ensuing thermal state is no longer passive after the disconnection stroke. Focusing on the case of two interacting qubits, we show that phase coherence, in the presence of non-trivial correlations between the qubits, can be exploited to reach working regimes with efficiency higher than 50% while providing finite ergotropy. Our protocol is illustrated through a simple and feasible circuit model of a cyclic superconducting QB. Furthermore, we simulate the considered cycle on superconducting IBM quantum machines. The good agreement between the theoretical and simulated results strongly suggests that our scheme for cyclic QBs can be successfully realized in superconducting quantum hardware.