A repeated interaction process assisted by auxiliary thermal systems charges a quantum battery. The charging energy is supplied by switching on and off the interaction between the battery and the thermal systems. The charged state is an equilibrium state for the repeated interaction process, and the ergotropy characterizes its charge. The working cycle consists in extracting the ergotropy and charging the battery again. We discuss the fluctuating efficiency of the process, among other fluctuating properties. These fluctuations are dominated by the equilibrium distribution and depend weakly on other process properties.
A repeated interaction process assisted by auxiliary thermal systems charges a quantum battery. The charging energy is supplied by switching on and off the interaction between the battery and the thermal systems. The charged state is an equilibrium state for the repeated interaction process, and the ergotropy characterizes its charge. The working cycle consists in extracting the ergotropy and charging the battery again. We discuss the fluctuating efficiency of the process, among other fluctuating properties. These fluctuations are dominated by the equilibrium distribution and depend weakly on other process properties.
Abstract The reduced state of a small system strongly coupled to a charger in thermal equilibrium may be athermal and used as a small battery once disconnected. By harnessing the battery-charger correlations, the battery’s extractable energy can increase above the ergotropy. We introduce a protocol that uses a quantum system as a memory that measures the charger and leaves the battery intact in its charged state. Using the information gained from the measurement, the daemonic ergotropy of the battery is extracted. Then the battery is reconnected to the charger, thermalizing and charging it. However, the memory should return to its initial standard state to close the thermodynamic cycle. Thus, on the one hand, the work cost of the cycle is the sum of the disconnecting and reconnecting battery-charger work plus the measurement and erasure work. On the other hand, the extracted energy is the daemonic ergotropy of the battery plus the ergotropy of the memory. The ratio of these quantities defines the efficiency of the cycle. The protocol is exemplified by a modified transverse spin 1/2 Ising chain, one spin functioning as the battery and the others as the charger. The memory is another auxiliary spin 1/2. We found pairs of measurement schemes from which we extract the same daemonic ergotropy from the battery, they dissipate the same amount of energy, and one leaves the memory in an active state, the other in a passive state. We study the memory’s ergotropy and the daemonic ergotropy of the battery. We find that with measurements, the efficiency can surpass that of the unmeasured protocol, given conditions on temperature, coupling, and choice of the measurement operators.
We show that a cyclic unitary process can extract work from the thermodynamic equilibrium state of an engineered quantum dissipative process. Systems in the equilibrium states of these processes serve as batteries, storing energy. The dissipative process that brings the battery to the active equilibrium state is driven by an agent that couples the battery to thermal systems. The second law of thermodynamics imposes a work cost for the process; however, no work is needed to keep the battery in that charged state. We consider simple examples of these batteries and discuss situations in which the charged state has full population inversion, in which case the extractable work is maximal, and circumstances in which the efficiency of the process is maximal.
We study the ergotropy and the thermodynamic potentials of a qubit battery charged by repeated interactions with clusters of thermal ancillas, qubits or oscillators, through a composite system-bath coupling that generates steady-state coherence in the energy basis. A single parameter encoding the bath quantum statistics yields the coherence and ergotropy in closed form for any cluster size. For large clusters, the ergotropy becomes independent of the bath statistics and, at optimal couplings, reaches a universal fraction of the equilibrium internal energy of the qubit at the bath temperature. Since the charged state has no population inversion, all extractable work comes from coherence. The ergotropy is flat at low temperatures. We trace this plateau to the third law, and show that the ergotropy is proportional to the equilibrium enthalpy of the qubit, whose slope vanishes with the heat capacity. For a battery composed of multiple qubits, the coherence grows exponentially with the number of qubits while the ergotropy grows linearly, both remaining a nearly constant fraction of their respective maxima. The charged state is a non-equilibrium steady state with finite entropy at zero temperature, sustained by the work of switching the collisional interaction on and off. The cost is nonzero whenever the parallel coupling is nonzero, and, unlike the ergotropy, it depends on the bath statistics.
In one of its versions, the Second Law states: "It is impossible to construct an engine which will work in a complete cycle, and produces no effect except the raising of a weight and cooling of a heat reservoir." While the Second Law is considered as one of the most robust laws of Nature, it is still challenging how to interpret it in a fully quantum domain. Here we unpack the true meaning of the "cyclicity" and formulate the Second Law for a generic quantum battery via its asymptotic properties of a charging process rather than in terms of a single cycle. As a paradigm, we propose a machine consisting of a battery that repeatedly interacts with identically prepared systems. We then propose the Second Law in the form: The ergotropy of the battery may increase indefinitely if and only if systems are in a non-passive state. One of the most interesting features of this new formulation is the appearance of the passive states that naturally generalize the notion of the heat bath. In this paper, we provide a handful of results that supports this formulation for diagonal systems. Interestingly, our methodology meets a well-known theory of Markov chains, according to which we classify the general charging processes based on the passivity/non-passivity of charging systems. In particular, the adopted mathematics allows us to distinguish a subtle asymptotic difference between the indefinite increase of the battery's energy (induced by the maximally mixed states) and of ergotropy (induced by the non-passive states) in terms of the so-called null-recurrent versus transient Markov chains.
Thermally charged quantum batteries provide a stable and easy-to-have energy resource, but remain passive and therefore do not allow useful energy extraction on demand via unitary operations. We introduce a time-dependent stirring protocol that activates a thermally charged quantum battery through a time-dependent coupling to an auxiliary activator, thereby generating correlations that drive the battery into an active state. Accounting explicitly for the energetic cost of the stirring process, the entropic cost of correlation generation and the activation time, we derive bounds on the maximal net extractable energy. Incorporating projective measurement on the activator and exploiting the information gained through the measurement further enhances the extractable energy. As an experimentally relevant example, we analyze a waveguide-QED setup where a harmonic-oscillator battery (waveguide) is stirred and monitored by a two-level system. We characterize the performance of the protocol in terms of net extractable energy (net ergotropy) and power output.
A quantum battery is a temporary energy-storage system. We construct a quantum battery model of an N-spin chain with nearest-neighbor hopping interaction and investigate the quantum battery's charging process. We obtain the maximum energy in the quantum battery charged by a coherent cavity driving field or a thermal heat bath. We confirm that for a finite-length spin chain, thermal charging results in a nonzero ergotropy, contradicting a previous result: An incoherent heat source cannot charge a single-spin quantum battery. The nearest-neighbor hopping interaction induces energy-band splitting, enhancing the energy storage and the ergotropy of the quantum battery. We find a critical point in the energy and ergotropy resulting from the ground-state quantum phase transition after which the energy significantly enhances. Finally, we also find that disorder increases the energy of the quantum battery.