Abstract We study a four-stroke Otto engine whose working fluid is a quantum Ising chain. The thermodynamic cycle consists in sweeps of the transverse magnetic field occurring in thermal isolation, alternated by thermalisation strokes with reservoirs at different temperatures. The system–environment coupling is modelled in a thermodynamically consistent way by means of a nonlocal Lindblad master equation. We show that the engine may operate in four different operation modes, depending on the various parameters, in particular it can act as a heat engine and as a refrigerator. We detect an enhancement of the thermodynamic performance as the critical point is crossed, and investigate it in detail.
Abstract We study a four-stroke Otto engine whose working fluid is a quantum Ising chain. The thermodynamic cycle consists in sweeps of the transverse magnetic field occurring in thermal isolation, alternated by thermalisation strokes with reservoirs at different temperatures. The system–environment coupling is modelled in a thermodynamically consistent way by means of a nonlocal Lindblad master equation. We show that the engine may operate in four different operation modes, depending on the various parameters, in particular it can act as a heat engine and as a refrigerator. We detect an enhancement of the thermodynamic performance as the critical point is crossed, and investigate it in detail.
Abstract This paper proposes a theoretical model for a heat engine operating on the Otto cycle, employing a two-qubit Heisenberg chain as its working substance. This system is subjected to an external, time-dependent homogeneous magnetic field and a symmetric cross-spin interaction. The interaction is configured to occur along two distinct orientations, contingent upon the direction of Zeeman energy and symmetric interaction: either exclusively along the X -direction or exclusively along the Z -direction. Furthermore, the thermal reservoirs integral to the Otto engine are considered to engage with the working substance via two discrete modes: a localized interaction or a collective interaction. The two qubits exhibit weak coupling to a non-equilibrium thermal environment during the isochoric heating and cooling strokes, thereby validating the application of a Markovian model as a suitable approximation for describing the time evolution of the working substance. This study investigates the influence of various system parameters on the thermodynamic quantities and the resultant power output. A principal finding is that refrigeration functionality is the predominant operational characteristic when the system engages in collective interaction with the reservoirs. Conversely, localized interactions facilitate dual operational modes, with the sign of the Zeeman energy determining the function as either a refrigerator or a heat engine. Significantly, positive power output is achieved in the engine regime, and we find that the choice of interaction axis acts as a powerful amplification mechanism for the thermodynamic output, while the system-environment coupling scheme proves to be the most decisive factor in determining the machine’s fundamental purpose.
We investigate a quantum Otto engine with a quantum Ising spin glass as the working medium to explore the scaling behavior of work output and thermodynamic performance concerning system size, particularly near the critical point. Specifically, we explore the two operating modes of the Otto engine, namely the heat engine and refrigerator modes. We observe a double-peaked structure in the heat engine regime, leading to superlinear scaling in both work output and thermodynamic performance near the critical point. Additionally, in the refrigerator regime, superlinear scaling in refrigerator efficiency can be achieved at high and low temperatures, significantly outperforming models with uniform Ising interactions. These findings suggest that disorder and frustration in quantum Ising spin-glass systems could significantly impact thermodynamic performance in quantum heat engines and refrigerators, potentially opening up new avenues for improvement.
Abstract We undertake a theoretical study of a finite-time quantum Otto engine cycle driven by inter-particle interactions in a weakly interacting one-dimensional (1D) Bose gas in the quasicondensate regime. Utilizing ac-field approach, we simulate the entire Otto cycle, i.e. the two work strokes and the two equilibration strokes. More specifically, the interaction-induced work strokes are modelled by treating the working fluid as an isolated quantum many-body system undergoing unitary evolution. The equilibration strokes, on the other hand, are modelled by treating the working fluid as an open quantum system tunnel-coupled to another quasicondensate which acts as either the hot or cold reservoir, albeit of finite size. We find that, unlike a uniform 1D Bose gas, a harmonically trapped quasicondensate cannot operate purely as aheatengine; instead, the engine operation is enabled by additionalchemicalwork performed on the working fluid, facilitated by the inflow of particles from the hot reservoir. The microscopic treatment of dynamics during equilibration strokes enables us to evaluate the characteristic operational time scales of this Ottothermochemicalengine, crucial for characterizing its power output, without any ad hoc assumptions about typical thermalization timescales. We analyse the performance and quantify the figures of merit of the proposed Otto thermochemical engine, finding that it offers a favourable trade-off between efficiency and power output, particularly when the interaction-induced work strokes are implemented via a sudden quench. We further demonstrate that in the sudden quench regime, the engine operates with an efficiency close to the near-adiabatic (near maximum efficiency) limit, while concurrently achieving maximum power output.
We discuss the limit cycle regime of a finite-time quantum Otto cycle with a frictionless two-dimensional anisotropic Ising model as the working fluid. From Onsager's exact equilibrium solution, we first find optimal parameters for the operational modes of work extraction and cooling for infinitely slow cycles. The equilibrium points in these optimal cycles correspond to different phases of the model, such that the nonequilibrium dynamics during the cycle bypasses the phase transition. Finite-time cycles allow for finite power extraction or cooling currents, but for such cycles, we point out that-already within the regime of weak system-reservoir coupling-energetic changes of the system during dissipative strokes may contain a significant portion of coupling and decoupling control work and should thus not be directly identified with heat. For ultrafast cycles, the required control work spoils performance, such that to maximize work extraction or cooling heat per cycle time, there is an optimal cycle duration. We also find that net-zero-energy transitions may lead to undesired reservoir heating.
Although the idea of combining thermodynamics with quantum mechanics is more than a century old, quantum thermodynamics has seen significant development over the past few decades. Understanding work, heat, and entropy in the quantum regime has become increasingly important, particularly in light of advances in quantum technologies. This thesis investigates work processes in quantum spin chains. Quantum work processes can involve genuinely quantum features such as entanglement, coherence, and measurement back-action, which are absent in classical thermodynamic descriptions, making their characterization an area of ongoing interest in quantum thermodynamics. Focusing first on a single work step, we show that the frictional work due to finite-time driving for a non-integrable quantum spin chain can be well quantified by the diagonal entropy production. We further demonstrate that integrability breaking enhances work extraction in the adiabatic limit, while suppressing it in the non-adiabatic regime. We then study a quantum Otto cycle using the transverse-field Ising model as the working substance. We determine how different types of operation (engine, refrigerator, accelerator, heater) can emerge for different parameter regimes. We show that with infinitesimal work strokes, a thermal machine behaves either as an engine or an accelerator, and that these regimes can be characterized by equilibrium transverse magnetization. At low temperatures, these regimes are governed by low-energy excitations, while at high temperatures they follow from a free-energy expansion in inverse temperature. Frictional effects can emerge and suppress the engine performance during non-adiabatic driving. We show that these effects can be mitigated using an optimised drive protocol based on a geometric formulation of the path of the system through parameter space. Overall, this thesis provides a comprehensive understanding of how integrability, coherence, finite-time driving, and non-adiabatic transitions govern work extraction and thermal machine operation in quantum spin chains, and paves the way for understanding these processes in other quantum many-body systems.