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arXiv:2202.05264 · Quantum

Periodically refreshed quantum thermal machines

Archak Purkayastha, Giacomo Guarnieri, Steve Campbell, Javier Prior, John Goold

Published Sep 8, 2022• 12 citations
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Abstract

We introduce unique class of cyclic quantum thermal machines (QTMs) which can maximize their performance at the finite value of cycle duration τ where they are most irreversible. These QTMs are based on single-stroke thermodynamic cycles realized by the non-equilibrium steady state (NESS) of the so-called Periodically Refreshed Baths (PReB) process. We find that such QTMs can interpolate between standard collisional QTMs, which consider repeated interactions with single-site environments, and autonomous QTMs operated by simultaneous coupling to multiple macroscopic baths. We discuss the physical realization of such processes and show that their implementation requires a finite number of copies of the baths. Interestingly, maximizing performance by operating in the most irreversible point as a function of τ comes at the cost of increasing the complexity of realizing such a regime, the latter quantified by the increase in the number of copies of baths required. We demonstrate this physics considering a simple example. We also introduce an elegant description of the PReB process for Gaussian systems in terms of a discrete-time Lyapunov equation. Further, our analysis also reveals interesting connections with Zeno and anti-Zeno effects.

DOI
10.22331/q-2022-09-08-801

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We introduce unique class of cyclic quantum thermal machines (QTMs) which can maximize their performance at the finite value of cycle duration τ where they are most irreversible. These QTMs are based on single-stroke thermodynamic cycles realized by the non-equilibrium steady state (NESS) of the so-called Periodically Refreshed Baths (PReB) process. We find that such QTMs can interpolate between standard collisional QTMs, which consider repeated interactions with single-site environments, and autonomous QTMs operated by simultaneous coupling to multiple macroscopic baths. We discuss the physical realization of such processes and show that their implementation requires a finite number of copies of the baths. Interestingly, maximizing performance by operating in the most irreversible point as a function of τ comes at the cost of increasing the complexity of realizing such a regime, the latter quantified by the increase in the number of copies of baths required. We demonstrate this physics considering a simple example. We also introduce an elegant description of the PReB process for Gaussian systems in terms of a discrete-time Lyapunov equation. Further, our analysis also reveals interesting connections with Zeno and anti-Zeno effects.
A procedure to find optimal regimes for quantum thermal engines (QTMs) is described and demonstrated. The QTMs are modelled as the periodically-driven non-equilibrium steady states of open quantum systems, whose dynamics is approximated in this work with Markovian master equations. The action of the external agent and the couplings to the heat reservoirs can be modulated with control functions, and it is the time-dependent shape of these control functions the object of optimisation. Those functions can be freely parameterised, which permits to constrain the solutions according to experimental or physical requirements. • Description of a procedure to find optimal regimes for quantum thermal engines. • The engines are modelled as the periodically-driven non-equilibrium steady states of open quantum systems. • The action of the external agent and the couplings to the heat reservoirs can be modulated with control functions. • Those functions can be freely parameterised to constrain the solutions according to experimental requirements.
We use fast periodic control to realize finite-time Otto cycles exhibiting quantum advantage.Such periodic modulation of the working medium-bath interaction Hamiltonian during the thermalization strokes can give rise to non-Markovian anti-Zeno dynamics and corresponding reduction in the thermalization times.Faster thermalization can in turn significantly enhance the power output in engines or, equivalently, the rate of refrigeration in refrigerators.This improvement in performance of dynamically controlled Otto thermal machines arises due to the time-energy uncertainty relation of quantum mechanics.
We investigate the operation of a qubit as a quantum thermal device within the repeated interaction framework, allowing for strong system-bath coupling and finite interaction times. We analyze two minimal models: an alternating-coupling setup, in which the qubit sequentially interacts with hot and cold baths, and a simultaneous-coupling setup, where both baths interact with the qubit during each collision. For the alternating model, we obtain an exact analytical solution for the limit-cycle state, valid for arbitrary coupling strengths and collision durations. Using this solution, we rigorously prove a no-go theorem for quantum refrigeration. We further demonstrate that, although work can be generated locally at individual system-bath contacts, the total work over a cycle is always nonpositive, precluding engine operation. In the absence of work, the model describes pure heat conduction, for which we derive a closed-form expression for the heat current and show that it exhibits a nonmonotonic turnover behavior. The simultaneous-coupling model is analyzed perturbatively. In the short-collision-time limit, it reproduces the same steady-state behavior as the alternating model, reinforcing the generality of the constraints identified. Our results establish fundamental limitations on qubit-based quantum thermal machines operating under Markovian repeated interactions and highlight the need for enriched models to realize functional quantum thermal devices.
The study of quantum thermodynamics is key to the development of quantum thermal machines. In contrast to most of the previous proposals based on discrete strokes, here we consider a working substance that is permanently coupled to two or more baths at different temperatures and continuously driven. To this end, we investigate parametrically driven quantum harmonic oscillators coupled to heat baths via a collision model. Using a thermodynamically consistent local master equation, we derive the heat flows and power of the working device, which can operate as an engine, refrigerator, or accelerator, and analyze the instantaneous and average efficiencies and coefficients of performance. Studying the regimes of both slow and fast driving of the system, we find that an increased driving frequency can lead to a change of functioning to a dissipator. Finally, we investigate the effect of squeezing one of the thermal baths: it leads to an apparent higher efficiency compared to the corresponding Carnot value of an equilibrium bath with the same temperature and to sustained entanglement between the working substance oscillators in the limit cycle.
We present a detailed study of quantum thermal machines employing quantum systems as working substances. In particular, we study two different types of two-stroke cycles where two collections of identical quantum systems with evenly spaced energy levels are initially prepared at thermal equilibrium by putting them in contact with a cold and a hot thermal bath, respectively. The two cycles differ in the absence or the presence of a mediator system, while, in both cases, nonresonant exchange Hamiltonians are exploited as particle interactions. We show that the efficiencies of these machines depend only on the energy gaps of the systems composing the collections and are equal to the efficiency of ``equivalent'' Otto cycles. Focusing on the cases of qubits or harmonic oscillators for both models, we maximize the engine power and analyze, in the model without the mediator, the role of the waiting time between subsequent interactions. It turns out that the case with the mediator can bring performance advantages when the interaction times are comparable with the waiting time of the correspondent cycle without the mediator. We find that in both cycles, the power peaks of qubit systems can surpass the Curzon-Ahlborn efficiency. Finally, we compare our cycle without the mediator with previous schemes of the quantum Otto cycle showing that high coupling is not required to achieve the same maximum power.
We investigate the operation of a qubit as a quantum thermal device within the repeated interaction framework, allowing for strong system-bath coupling and finite interaction times. We analyze two minimal models: an alternating-coupling setup, in which the qubit sequentially interacts with hot and cold baths, and a simultaneous-coupling setup, where both baths interact with the qubit during each collision. For the alternating model, we obtain an exact analytical solution for the limit-cycle state, valid for arbitrary coupling strengths and collision durations. Using this solution, we rigorously prove a no-go theorem for quantum refrigeration. We further demonstrate that although work can be generated locally at individual system-bath contacts, the total work over a cycle is always nonpositive, precluding engine operation. In the absence of work, the model describes pure heat conduction, for which we derive a closed-form expression for the heat current and show that it exhibits a nonmonotonic turnover behavior. The simultaneous-coupling model is analyzed perturbatively. In the short-collision-time limit, it reproduces the same steady-state behavior as the alternating model, reinforcing the generality of the constraints identified. Our results establish fundamental limitations on qubit-based quantum thermal machines operating under Markovian repeated interactions and highlight the need for enriched models to realize functional quantum thermal devices.