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arXiv:2107.01932

Classical and Quantum Correlation Functions for a Ring Model

Brian H Buck, C V Sukumar

Published Jul 5, 2021• 0 citations
arXivHTMLPDF

Abstract

Classical and quantum correlation functions are derived for a system of non-interacting particles moving on a circle. It is shown that the decaying behaviour of the classical expression for the correlation function can be recovered from the strictly periodic quantum mechanical expression by taking the limit that the Planck's constant goes to zero, after an appropriate transformation.

DOI
10.48550/arxiv.2107.01932

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Classical and quantum correlation functions are derived for a system of non-interacting particles moving on a circle. It is shown that the decaying behaviour of the classical expression for the correlation function can be recovered from the strictly periodic quantum mechanical expression by taking the limit that the Planck's constant goes to zero, after an appropriate transformation.
A review of the journal entitled 'Classical And Quantum Correlation Functions For A Ring Model' has been carried out which discusses the solutions of classical and quantum correlation functions for the ring model. Classical and quantum correlation functions are derived for systems of non-interacting particles moving in a circle. demonstrated that the decay behavior of the classical expression for the correlation function can be recovered from a strictly periodic quantum mechanical expression by taking the limit ℏ→0, after the appropriate transformation. The aim of this study is to present clearly and in detail how the position correlation function for a system of particles moving in a circle having a certain average energy and written in a form which shows the nature of the transformation. Next, we examine the use of Poisson addition to represent F(z), and how the correlation function becomes identical to the form given by classical statistical mechanics, which exhibits Gaussian decay. The results of this study indicate that the positional correlation function for a system of particles moving in a circle, and having a certain average energy, can be written in a form which shows the nature of the transformation. Then using the Poisson addition formula to represent F(z), the expression is rewritten to enable the limit ℏ→0 to be taken. It was finally found that the correlation function became identical to the form given by classical statistical mechanics, which exhibits a Gaussian decay.
We derive a simple and general relation between the fidelity of quantum motion, characterizing the stability of quantum dynamics with respect to arbitrary static perturbation of the unitary evolution propagator, and the integrated time auto-correlation function of the generator of perturbation. Surprisingly, this relation predicts the slower decay of fidelity the faster the decay of correlations. In particular, for non-ergodic and non-mixing dynamics, where asymptotic decay of correlations is absent, a qualitatively different and faster decay of fidelity is predicted on a timescale ∝ 1/δ as opposed to mixing dynamics where the fidelity is found to decay exponentially on a timescale ∝ 1/δ 2 , where δ is the strength of perturbation. A detailed discussion of a semiclassical regime of small effective values of Planck constant is given where classical correlation functions can be used to predict quantum fidelity decay. Note that the correct and intuitively expected classical stability behaviour is recovered in the classical limit → 0, as the two limits δ → 0 and → 0 do not commute. In addition, we also discuss non-trivial dependence on the number of degrees of freedom. All the theoretical results are clearly demonstrated numerically on the celebrated example of a quantized kicked top.
The stability of quantum systems to perturbations of the Hamiltonian is studied. This stability is quantified by the fidelity. Dependence of fidelity on the initial state as well as on the dynamical properties of the system is considered. In particular, systems having a chaotic or regular classical limit are analysed. The fidelity decay rate is given by an integral of the correlation function of the perturbation and is thus smaller the faster correlation function decays. If the perturbation can be written as a time derivative of another operator, meaning that the time averaged perturbation vanishes, fidelity freezes at a constant value and starts to decay only after a long time inversely proportional to the perturbation strength. In composite systems stability of entanglement to perturbations of the Hamiltonian is analysed in terms of purity. For regular systems purity decay is shown to be independent of Planck's constant for coherent initial states in the semiclassical limit. The accelerated decoherence of macroscopic superpositions is also explained. The theory of fidelity decay is applied to the stability of quantum computation and an improved quantum Fourier transform algorithm is designed.
A fully classical limit of the recently published quantum-classical approximation [A. A. Neufeld, J. Chem. Phys. 119, 2488 (2003)] is obtained and analyzed. The resulting kinetic equations are capable of describing the evolution of an open system on the entire time axis, including the short-time non-Markovian stage, and are valid beyond linear response regime. We have shown, that proceeding to the classical mechanics limit we restrict the class of allowed correlations between an open system and a canonical bath, so that the initial conditions and the relaxation operator has to be appropriately modified (projected). Disregard of the projection may lead to unphysical behavior, since mechanism of the decay of some correlations is essentially of quantum-mechanical nature, and is not correctly described by classical mechanics. The projection (quantum correction to the kinetics) is particularly important for the non-Markovian regime of relaxation towards canonical equilibrium. The conformity of the developed method to the conventional approaches is demonstrated using a model of Brownian motion (heavy particle in the bath of light ones), for which the obtained non-Markovian equations are reduced to the standard Fokker-Planck equation in phase space.
We consider the time correlation function of observables pertaining to a (quantum subsystem +bath), where the bath is coupled to a reservoir with many degrees of freedom. Integrating over the coordinates of this reservoir and assuming no initial correlations between the (quantum subsystem+bath) and the reservoir, we obtain an expression for the time correlation function that contains an influence functional. We then take the semiclassical and Fokker–Planck limits while modeling the reservoir with an Ohmic continuum of harmonic oscillators coupled bilinearily to the coordinates of the bath. The semiclassical limit is taken using a variant of Pechukas’ stationary phase analysis of the reduced propagator that yields a time correlation function written in terms of connected “classical” paths. These paths are got by solving the concatenation of several short-time interval Pechukas equations; as a result, the determination of these paths is more feasible than the determination of the “classical” path associated with a single long-time interval Pechukas equation. This concatenation includes the dissipative and stochastic forces associated with a classical Brownian particle. We then use decoherence arguments derived from an inspection of the influence functional to eliminate the phase interference structure of the bath. This elimination yields a mixed quantum-classical time correlation function that can be evaluated using nonadiabatic mixed quantum-classical dynamics schemes similar to those proposed recently by Webster and Tully.
Planck formulated the correspondence principle between quantum and classical mechanics as the limit in which the Planck constant h goes to zero. Bohr formulated the correspondence principle to be the limit of large quantum numbers. For three common quantum mechanical systems it is shown that in order for eigenvalues of quantum mechanical observables to have meaningful classical limits, it is necessary to take the double limit as both the Planck constant goes to zero and the quantum number goes to infinity, subject to the constraint that their product is equal to an appropriate classical action. This synthesis of the Bohr and Planck formulations of the correspondence principle is also used to show that the quantum mechanical transition frequency between adjacent levels approaches the corresponding classical frequency. The features these systems have in common in their classical limit are explained by general considerations of the classical limit of the Schrödinger equation.