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arXiv:2105.12617 · The European Physical Journal H

E. Schrödinger’s 1931 paper “On the Reversal of the Laws of Nature” [“Über die Umkehrung der Naturgesetze”, Sitzungsberichte der preussischen Akademie der Wissenschaften, physikalisch-mathematische Klasse, 8 N9 144–153]

Raphaël Chétrite, Paolo Muratore-Ginanneschi, Kay Schwieger

Published Nov 22, 2021• 26 citations
arXivHTMLPDF

Abstract

Abstract We present an English translation of Erwin Schrödinger’s paper on “On the Reversal of the Laws of Nature‘’. In this paper, Schrödinger analyses the idea of time reversal of a diffusion process. Schrödinger’s paper acted as a prominent source of inspiration for the works of Bernstein on reciprocal processes and of Kolmogorov on time reversal properties of Markov processes and detailed balance. The ideas outlined by Schrödinger also inspired the development of probabilistic interpretations of quantum mechanics by Fényes, Nelson and others as well as the notion of “Euclidean Quantum Mechanics” as probabilistic analogue of quantization. In the second part of the paper, Schrödinger discusses the relation between time reversal and statistical laws of physics. We emphasize in our commentary the relevance of Schrödinger’s intuitions for contemporary developments in statistical nano-physics.

DOI
10.1140/epjh/s13129-021-00032-7

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Proceedings of the Aristotelian Society (Hardback)•Jun 1, 2000•42 citations
Abstract We present an English translation of Erwin Schrödinger’s paper on “On the Reversal of the Laws of Nature‘’. In this paper, Schrödinger analyses the idea of time reversal of a diffusion process. Schrödinger’s paper acted as a prominent source of inspiration for the works of Bernstein on reciprocal processes and of Kolmogorov on time reversal properties of Markov processes and detailed balance. The ideas outlined by Schrödinger also inspired the development of probabilistic interpretations of quantum mechanics by Fényes, Nelson and others as well as the notion of “Euclidean Quantum Mechanics” as probabilistic analogue of quantization. In the second part of the paper, Schrödinger discusses the relation between time reversal and statistical laws of physics. We emphasize in our commentary the relevance of Schrödinger’s intuitions for contemporary developments in statistical nano-physics.
Abstract A decade before his 1926 paperb reporting his discovery of wave mechanics, a derivation of the time-independent wave equation, and its solutions for hydrogen-like atoms, Erwin Schrödinger had carried out several studies dealing with Brownian motion. It is clear from several of the papers he wrote that he was completely familiar with diffusion equations, the Fokker-Planck equation in many forms, their connections with Green’s functions, and with behavior of systems of particles undergoing random walks including those in force fields.c Thus, it is not surprising that Schrödinger was aware of the relation of the Schrödinger equation in imaginary time, to the diffusion equation governing particles undergoing diffusion, In this paper, with the title “On the Reversal of Natural Laws,” Schrödinger pointed out the remarkable formal analogy of diffusion with quantum mechanics and the discrepancies introduced by the factor J=T. In his discussion Schrödinger made the statement, “I am unable to foresee whether this analogy will prove itself useful in the clarification of quantum mechanical concepts,” but he finished the paper with the hope it would. There is no indication that Schrödinger was aware of the possibilities of a next step into quantum Monte Carlo - the use of random walks to provide solutions to the wave equation. This was left for others to discover later.
This is an exploration with today’s tools of probability theory into the mystery of ‘Über die Umkehrung der Naturgesetze’ (On time-reversal of natural laws) written by Erwin Schrödinger in 1931. He propagates the idea that diffusions given their marginal distributions at finite initial and final time are time-reversible. We are going to meet clouds of identical and independent particles considering them as realizations of diffusions. The particle dynamics is assumed to be known. Given the observation of such a cloud in terms of distribution densities at finite initial and final time, the intention is to find the ‘most probable’ distribution density of the cloud at intermediate times.
This paper proposes an interpretation of quantum mechanics, relying on the time-symmetric stochastic dynamics of quantum particles and on non-classical probability theory. Our main purpose is to demonstrate that the wave function and its complex conjugate can be interpreted as complex probability distributions in two complex diffusion equations related to non-real forward and backward in time stochastic motions respectively. We say non-real because Schroedinger forward and backward diffusions describe both reversible (real trajectories) and irreversible trajectories (non-real trajectories). The reversible trajectories are the only real trajectories and are given by the intersection of those forward and backward processes. It turns out that if we translate this intersection using set-theoretic language, we are led to a reversible diffusion described by Born rule probabilities. This proposal is useful also for explaining more about the role of complex numbers in quantum mechanics that produces this so-called "wave-like" nature of quantum reality. Our perspective also challenges the notion of physical superposition and aims at a derivation of superposition principle not based on the linearity of Schroedinger's equation but relying on pure probability theory. Moreover, it is suggested that, embracing the idea of stochastic processes in quantum theory, explains the reasons for the appearance of classical behavior in large objects, in contrast to the quantum behavior of small ones. In other words, we claim that a combination of a probabilistic and no-ontic view (neither epistemic though) of the wave function with a stochastic hidden-variables approach, may provide some insight into the quantum physical reality and potentially establish the groundwork for a novel interpretation of quantum mechanics.
The discussion on time-reversal in quantum mechanics exists at least since Wigner's ``Uber die Operation der Zeitumkehr in der Quantenmechanik'' paper in 1932. If and how the dynamics of the quantum world is time-reversible has been the subject of many controversies. Some have seen quantum mechanics as fundamentally time-irreversible, see for example von Neumann, and some have seen in that the ultimate cause of time's arrow and second law behavior. In his best-selling book ``The Emperor's New Mind'', Roger Penrose argues similarly and concludes that ``our sought-for quantum gravity must be a time-asymmetric theory'' [p.351]. Not so long ago, we read yet about another project in Physicalia 26: to extend quantum mechanics into new fundamentally irreversible equations, thus proposing a new theory giving ``... une description fondamentale irreversible de tout systeme physique''.
Introduction. There exists a very comprehensive theory concerning the time development of probabilistic systems. This is the Theory of Stochastic processes (1). Quantum mechanics as described by the Schrödinger equation rests very heavily on probabilistic interpretation, and yet, after forty years of remarkably rapid advances and successes, it is not clear how it is related to stochastic theory. The formal similarity of certain aspects of, and equations used in these two theories are well known. The diffusion equation corresponds to the Schrödinger equation, a correspondence only marred by a square root of minus unity appearing with the time derivative in the latter equation. The Kolmogoroff–Chapman relation for probabilities in Brownian motion has an analogue (2) in quantum mechanics, not for probabilities though, but for the complex probability amplitudes. The uncertainty relation also has a stochastic analogue (3). Some of these analogous characteristics are actually symptomatic of the gulf which separates these two theories. There are solutions to the diffusion equation which have a very clear physical probabilistic meaning. This is not the case with the corresponding and formally similar solutions to the Schrödinger equation and is partly due to the √ − 1 mentioned earlier. The probabilistic interpretation of the solutions to the diffusion equation is direct and immediate. On the other hand, the probabilistic interpretation of the solutions, ψ of the Schrödinger equation involve the introduction of the probability density, p = ψ*ψ. One great difference between these two theories lies in their each having distinct principles of linear superposition. In Stochastic Theory probabilities are superposed and in quantum mechanics amplitudes or wave functions are superposed.
In a classical mechanical world, the fundamental laws of nature are reversible. The laws of nature treat the past and future as mirror images of each other. Temporally asymmetric phenomena are ultimately said to arise from initial conditions. But are the laws of nature also reversible in a quantum world? This paper argues that they are not, that time in a quantum world prefers a particular ‘hand’ or ordering. I argue, first, that the probabilistic algorithm used in the theory picks out a preferred direction of time for almost all interpretations of the theory, and second, that contrary to the received wisdom the Schrödinger evolution is also irreversible. The status of Wigner reversal invariance is then discussed. I conclude that the quantum world is fundamentally irreversible, but manages to appear (thanks to Wigner reversal invariance) reversible at the classical level.